451 research outputs found

    L’enfant et le langage

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    Psychologie du langage

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    The Optimal Gravitational Lens Telescope

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    Given an observed gravitational lens mirage produced by a foreground deflector (cf. galaxy, quasar, cluster,...), it is possible via numerical lens inversion to retrieve the real source image, taking full advantage of the magnifying power of the cosmic lens. This has been achieved in the past for several remarkable gravitational lens systems. Instead, we propose here to invert an observed multiply imaged source directly at the telescope using an ad-hoc optical instrument which is described in the present paper. Compared to the previous method, this should allow one to detect fainter source features as well as to use such an optimal gravitational lens telescope to explore even fainter objects located behind and near the lens. Laboratory and numerical experiments illustrate this new approach

    To robotize chemistry laboratories. An example of organic synthesis: 2-Boc-amino-N-hydroxy-3-phenyl-propionamide

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    The paper describes the development of periodic modules used for the peptide synthesis of hydroxamic acid. A powder conveyor using the principle of positive weighing distribution is described. Purification is provided using automatic filtration and a liquid— liquid extraction module separation device. Device quality is improved using failure mode and effects analysis

    Modulating between 2e<sup>-</sup> and 4e<sup>-</sup> pathway in the oxygen reduction reaction with laser-synthesized iron oxide-grafted nitrogen-doped carbon

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    In this study, we demonstrate the tuning of the oxygen reduction reaction (ORR) by iron/iron oxide nanoparticle grafted laser-patterned nitrogen-doped carbon (LP-NC) electrodes. Depending on the preparation route, i.e. addition of a molecular Fe(NO3)2 precursor before (route 1) or after pre-carbonization (route 2) of the citric acid / urea precursors, either the 4e- or the 2e- pathway in the ORR is facilitated leading to either H2O or H2O2 as a reaction product, respectively. The kinetic reaction conditions afford mixed valence metal oxide nanoparticles embedded in LP-NC in the form of either Fe2O3/Fe or Fe2O3/FeO/Fe, respectively, facilitated by an in situ carbothermal reduction during the laser-induced carbonization. In HR(S)TEM analysis we found evidence for the occurrence of Fe2O3 in the η- or α- phase, depending on the preparation route. Reciprocally, the graphitization is also affected by the preparation route leading to either homogeneous graphitization or locally a graphitized shell structures around the nanoparticles. In the 4e- mediated ORR facilitated by η-Fe2O3/Fe@LP-NC onset potentials as low as 0.70 V (vs. RHE) with a H2O2 production efficiency 4% and 10 % in alkaline and neutral electrolyte, respectively, were determined. On the other hand, α-Fe2O3/FeO/Fe@LP-NC present onset potentials for the 2e- mediated ORR is as low as 0.77 with a H2O2 production efficiency of nearly 80%

    Trained laser-patterned carbon as high-performance mechanical sensors

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    We describe the mechanical properties of turbostratically graphitized carbon films obtained by carbon laser-patterning (CLaP) and their application as bending or mechanical pressure sensors. Stable conductive carbonized films were imprinted on a flexible polyethylene terephthalate (PET) substrate by laser-induced carbonization. After initial gentle bending, i.e. training, these sponge-like porous films show a quantitative and reversible change in resistance upon bending or application of pressure in normal loading direction. Maximum response values of ΔR/R0 = 388% upon positive bending (tensile stress) and −22.9% upon negative bending (compression) are implicit for their high sensitivity towards mechanical deformation. Normal mechanical loading in a range between 0 and 500 kPa causes a response between ΔR/R0 = 0 and −15%. The reversible increase or decrease in resistance is attributed to compression or tension of the turbostratically graphitized domains, respectively. This mechanism is supported by a detailed microstructural and chemical high-resolution transmission electron microscopic analysis of the cross-section of the laser-patterned carbon

    Dynamic multilateral markets

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    We study dynamic multilateral markets, in which players' payoffs result from intra-coalitional bargaining. The latter is modeled as the ultimatum game with exogenous (time-invariant) recognition probabilities and unanimity acceptance rule. Players in agreeing coalitions leave the market and are replaced by their replicas, which keeps the pool of market participants constant over time. In this infinite game, we establish payoff uniqueness of stationary equilibria and the emergence of endogenous cooperation structures when traders experience some degree of (heterogeneous) bargaining frictions. When we focus on market games with different player types, we derive, under mild conditions, an explicit formula for each type's equilibrium payoff as the market frictions vanish

    Gattini 2010: Cutting Edge Science at the Bottom of the World

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    The high altitude Antarctic sites of Dome A and the South Pole offer intriguing locations for future large scale optical astronomical Observatories. The Gattini project was created to measure the optical sky brightness, large area cloud cover and aurora of the winter-time sky above such high altitude Antarctic sites. The Gattini-DomeA camera was installed on the PLATO instrument module as part of the Chinese-led traverse to the highest point on the Antarctic plateau in January 2008. This single automated wide field camera contains a suite of Bessel photometric filters (B, V, R) and a long-pass red filter for the detection and monitoring of OH emission. We have in hand one complete winter-time dataset (2009) from the camera that was recently returned in April 2010. The Gattini-South Pole UV camera is a wide-field optical camera that in 2011 will measure for the first time the UV properties of the winter-time sky above the South Pole dark sector. This unique dataset will consist of frequent images taken in both broadband U and B filters in addition to high resolution (R similar to 5000) long slit spectroscopy over a narrow bandwidth of the central field. The camera is a proof of concept for the 2m-class Antarctic Cosmic Web Imager telescope, a dedicated experiment to directly detect and map the redshifted lyman alpha fluorescence or Cosmic Web emission we believe possible due to the unique geographical qualities of the site. We present the current status of both projects
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