17,468 research outputs found
Development of large, horizontal-axis wind turbines
A program to develop large, horizontal-axis wind turbines is discussed. The program is directed toward developing the technology for safe, reliable, environmentally acceptable large wind turbines that can generate a significant amount of electricity at costs competitive with those of conventional electricity-generating systems. In addition, these large wind turbines must be fully compatible with electric utility operations and interface requirements. Several ongoing projects in large-wind-turbine development are directed toward meeting the technology requirements for utility applications. The machines based on first-generation technology (Mod-OA and Mod-1) successfully completed their planned periods of experimental operation in June, 1982. The second-generation machines (Mod-2) are in operation at selected utility sites. A third-generation machine (Mod-5) is under contract. Erection and initial operation of the Mod-5 in Hawaii should take place in 1986. Each successive generation of technology increased reliability and energy capture while reducing the cost of electricity. These advances are being made by gaining a better understanding of the system-design drivers, improving the analytical design tools, verifying design methods with operating field data, and incorporating new technology and innovative designs. Information is given on the results from the first- and second-generation machines (Mod-OA, - 1, and -2), the status of the Department of Interior, and the status of the third-generation wind turbine (Mod-5)
Telemetry link for an automatic salmon migration monitor
The antenna and transmitter described in this report were designed for integration into the remote acoustic assessment system for detection of sockeye salmon in the Bristol Bay region of the Bering Sea. The assessment system configuration consists of an upward directed sonar buoy anchored 150 ft below the surface and attached by cable to a spar buoy tethered some 300 ft laterally. The spar buoy contains a telemetry transmitter, power supply, data processing electronics, an antenna and a beacon light
The NASA Lewis large wind turbine program
The program is directed toward development of the technology for safe, reliable, environmentally acceptable large wind turbines that have the potential to generate a significant amount of electricity at costs competitive with conventional electric generation systems. In addition, these large wind turbines must be fully compatible with electric utility operations and interface requirements. Advances are made by gaining a better understanding of the system design drivers, improvements in the analytical design tools, verification of design methods with operating field data, and the incorporation of new technology and innovative designs. An overview of the program activities is presented and includes results from the first and second generation field machines (Mod-OA, -1, and -2), the design phase of the third generation wind turbine (Mod-5) and the advanced technology projects. Also included is the status of the Department of Interior WTS-4 machine
Mutations in the Arabidopsis Peroxisomal ABC Transporter COMATOSE Allow Differentiation between Multiple Functions In Planta: Insights from an Allelic Series
COMATOSE (CTS), the Arabidopsis homologue of human Adrenoleukodystrophy protein (ALDP), is required for import of substrates for peroxisomal β-oxidation. A new allelic series and a homology model based on the bacterial ABC transporter, Sav1866, provide novel insights into structure-function relations of ABC subfamily D proteins. In contrast to ALDP, where the majority of mutations result in protein absence from the peroxisomal membrane, all CTS mutants produced stable protein. Mutation of conserved residues in the Walker A and B motifs in CTS nucleotide-binding domain (NBD) 1 resulted in a null phenotype but had little effect in NBD2, indicating that the NBDs are functionally distinct in vivo. Two alleles containing mutations in NBD1 outside the Walker motifs (E617K and C631Y) exhibited resistance to auxin precursors 2,4-dichlorophenoxybutyric acid (2,4-DB) and indole butyric acid (IBA) but were wild type in all other tests. The homology model predicted that the transmission interfaces are domain-swapped in CTS, and the differential effects of mutations in the conserved "EAA motif" of coupling helix 2 supported this prediction, consistent with distinct roles for each NBD. Our findings demonstrate that CTS functions can be separated by mutagenesis and the structural model provides a framework for interpretation of phenotypic data
Cationic Alkylaluminum-Complexed Zirconocene Hydrides as Participants in Olefin Polymerization Catalysis
The alkylaluminum-complexed zirconocene trihydride
cation [(SBI)Zr(μ-H)_3(AliBu_2)_2]^+, which is obtained by reaction of (SBI)ZrCl_2 with [Ph_3C][B(C_6F_5)_4] and excess HAl^iBu_2 in toluene solution, catalyzes the formation of isotactic polypropene when exposed to propene at -30 °C. This cation remains the sole observable species in catalyst systems free of AlMe compounds. In the presence of AlMe_3, however, exposure to propene causes the trihydride cation to be completely converted, under concurrent consumption of all hydride species by propene hydroalumination, to the doubly Me-bridged cation [(SBI)Zr(μ-Me)_2AlMe_2]^+. The latter then becomes the resting state for further propene polymerization, which produces, by chain transfer to Al, mainly AlMe_2-capped isotactic polypropene
Large wind turbines: A utility option for the generation of electricity
The wind resource is such that wind energy generation has the potential to save 6-7 quads of energy nationally. Thus, the Federal Government is sponsoring and encouraging the development of cost effective and reliable wind turbines. One element of the Federal Wind Energy Programs, Large Horizontal Axis Wind Turbine Development, is managed by the NASA Lewis Research Center for the Department of Energy. There are several ongoing wind system development projects oriented primarily toward utility application within this program element. In addition, a comprehensive technology program supporting the wind turbine development projects is being conducted. An overview is presented of the NASA activities with emphasis on application of large wind turbines for generation of electricity by utility systems
Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy
Reactions of unbridged zirconocene dichlorides, (R_nC_5H_5−n)_2ZrCl_2 (n = 0, 1, or 2), with diisobutylaluminum hydride (HAl^iBu_2) result in the formation of tetranuclear trihydride clusters of the type (R_nC_5H_5−n)_2Zr(μ-H)_3(Al^iBu_2)_3(μ-Cl)_2, which contain three [Al^iBu_2] units. Ring-bridged ansa-zirconocene dichlorides, Me_2E(R_nC_5H_4−n)_2ZrCl_2 with E = C or Si, on the other hand, are found to form binuclear dihydride complexes of the type Me_2E(R_nC_5H_4−n)_2Zr(Cl)(μ-H)_2Al^iBu_2 with only one [Al^iBu_2] unit. The dichotomy between unbridged and bridged zirconocene derivatives with regard to tetranuclear versus binuclear product formation is proposed to be connected to different degrees of rotational freedom of their C_5-ring ligands. Alkylaluminum-complexed zirconocene dihydrides, previously observed in zirconocene-based precatalyst systems activated by methylalumoxane (MAO) upon addition of HAl^iBu_2 or Al^iBu_3, are proposed to be species of the type Me_2Si(ind)_2Zr(Me)(μ-H)_2Al^iBu_2, stabilized by interaction of their terminal Me group with a Lewis acidic site of MAO
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