Theory of antiferroelectric phase transitions

At variance with structural ferroic phase transitions which give rise to macroscopic tensors coupled to macroscopic fields, criteria defining antiferroelectric (AFE) phase transitions are still under discussion due to the absence of specific symmetry properties characterizing their existence. They are recognized by the proximity of a ferroelectric (FE) phase induced under applied electric field, with a double hysteresis loop relating the induced polarization to the electric field and a typical anomaly of the dielectric permittivity. Here, we show that there exist indeed symmetry criteria defining AFE transitions. They relate the local symmetry of the polar crystallographic sites emerging at an AFE phase transition with the macroscopic symmetry of the AFE phase. The dielectric properties of AFE transitions are deduced from a Landau theoretical model in which ferroelectric and ferrielectric phases are shown to stabilize as the result of specific symmetry-allowed couplings of the AFE order- parameter with the field-induced polarization.Comment: 7 pages, 5 figures, 1 tabl

Order-Parameter Symmetries of Domain Walls in Ferroelectrics and Ferroelastics

The symmetry of boundaries between ferroelectric, ferroelastic and antiphase domains is a key element for a theoretical understanding of their properties. Here, we derive this symmetry from their organic relation to the symmetry of the primary transition order parameters. The domain wall symmetries are shown to coincide with directions of the order-parameter n-dimensional vector space, corresponding to sum of the vectors associated with adjacent domain states. This property is illustrated by the determination of the domain wall maximal symmetries in BaTiO3, LaAlO3, SrTiO3 and Gd2(MoO4)3. Besides, the domain pattern in YMnO3 is interpreted as resulting from an annihilation-creation process, the annihilation of the antiphase domain walls creating six ferroelectric domain walls merging at a single point.Comment: 5 pages, 3 figure

Relative Abundance Measurements in Plumes and Interplumes

We present measurements of relative elemental abundances in plumes and interplumes. Plumes are bright, narrow structures in coronal holes that extend along open magnetic field lines far out into the corona. Previous work has found that in some coronal structures the abundances of elements with a low first ionization potential (FIP) < 10 eV are enhanced relative to their photospheric abundances. This coronal-to-photospheric abundance ratio, commonly called the FIP bias, is typically 1 for element with a high-FIP (> 10 eV). We have used EIS spectroscopic observations made on 2007 March 13 and 14 over an ~24 hour period to characterize abundance variations in plumes and interplumes. To assess their elemental composition, we have used a differential emission measure (DEM) analysis, which accounts for the thermal structure of the observed plasma. We have used lines from ions of iron, silicon, and sulfur. From these we have estimated the ratio of the iron and silicon FIP bias relative to that for sulfur. From the results, we have created FIP-bias-ratio maps. We find that the FIP-bias ratio is sometimes higher in plumes than in interplumes and that this enhancement can be time dependent. These results may help to identify whether plumes or interplumes contribute to the fast solar wind observed in situ and may also provides constraints on the formation and heating mechanisms of plumes.Comment: 21 pages; 3 tables; 12 figure

Testing predictors of eruptivity using parametric flux emergence simulations

Solar flares and coronal mass ejections (CMEs) are among the most energetic events in the solar system, impacting the near-Earth environment. Flare productivity is empirically known to be correlated with the size and complexity of active regions. Several indicators, based on magnetic-field data from active regions, have been tested for flare forecasting in recent years. None of these indicators, or combinations thereof, have yet demonstrated an unambiguous eruption or flare criterion. Furthermore, numerical simulations have been only barely used to test the predictability of these parameters. In this context, we used the 3D parametric MHD numerical simulations of the self-consistent formation of the flux emergence of a twisted flux tube, inducing the formation of stable and unstable magnetic flux ropes of Leake (2013, 2014). We use these numerical simulations to investigate the eruptive signatures observable in various magnetic scalar parameters and provide highlights on data analysis processing. Time series of 2D photospheric-like magnetograms are used from parametric simulations of stable and unstable flux emergence, to compute a list of about 100 different indicators. This list includes parameters previously used for operational forecasting, physical parameters used for the first time, as well as new quantities specifically developed for this purpose. Our results indicate that only parameters measuring the total non-potentiality of active regions associated with magnetic inversion line properties, such as the Falconer parameters $L_{ss}$, $WL_{ss}$, $L_{sg}$ and $WL_{sg}$, as well as the new current integral $WL_{sc}$ and length $L_{sc}$ parameters, present a significant ability to distinguish the eruptive cases of the model from the non-eruptive cases, possibly indicating that they are promising flare and eruption predictors.Comment: 46 pages, 16 figures, accepted for publication in Space Weather and Space Climate on June, 8t

High-pressure phase transitions in BiFeO3: hydrostatic vs. non-hydrostatic conditions

We report high-pressure x-ray diffraction experiments on BiFeO3 (BFO) single crystals in diamond-anvil cells up to 14 GPa. Two data sets are compared, one in hydrostatic conditions, with helium used as pressure-transmitting medium, and the other in non-hydrostatic conditions, with silicon oil as pressure-transmitting medium. It is shown that the crystal undergoes different phase transitions in the two cases, highlighting the high sensitivity of BFO to non-hydrostatic stress. Consequences for the interpretation of high-pressure structural studies are discussed.Comment: 6 pages, 4 figure

Rules and mechanisms governing octahedral tilts in perovskites under pressure

The rotation of octahedra (octahedral tilting) is common in ABO3 perovskites and relevant to many physical phenomena, ranging from electronic and magnetic properties, metal-insulator transitions to improper ferroelectricity. Hydrostatic pressure is an efficient way to tune and control octahedral tiltings. However, the pressure behavior of such tiltings can dramatically differ from one material to another, with the origins of such differences remaining controversial. In this work, we discover several new mechanisms and formulate a set of simple rules that allow to understand how pressure affects oxygen octahedral tiltings, via the use and analysis of first-principles results for a variety of compounds. Besides the known A-O interactions, we reveal that the interactions between specific B-ions and oxygen ions contribute to the tilting instability. We explain the previously reported trend that the derivative of the oxygen octahedral tilting with respect to pressure (dR/dP) usually decreases with both the tolerance factor and the ionization state of the A-ion, by illustrating the key role of A-O interactions and their change under pressure. Furthermore, three new mechanisms/rules are discovered. We further predict that the polarization associated with the so-called hybrid improper ferroelectricity could be manipulated by hydrostatic pressure, by indirectly controlling the amplitude of octahedral rotations.Comment: Submitted to Phys. Re