Classic and local analysis of corrosion behaviour of graphite and stainless steels in polluted phosphoric acid

In phosphoric acid solution (40% H3PO4), the corrosion behaviour of graphite and stainless steels was studied by the use of different electrochemical methods, namely polarization curve analysis, electrochemical impedance spectroscopy (EIS) and scanning vibrating electrode technique (SVET). The combined effect of chemical impurities and the increase of medium temperature was studied to approach the real conditions in the process of phosphoric acid manufacturing. It was found that the current density measured by polarization curves increased with the presence of chloride and sulphate ions in the acid solution whatever the tested material. Compared to stainless steels, graphite had the best corrosion resistance in polluted phosphoric acid. However, for graphite the increase of temperature from 20 to 80 ◦C induced an increase of the corrosion rate and potential and a decrease of the resistance confirmed by EIS results. Subsequently, local currents were detected at the surface of the sample by using the scanning vibrating electrode technique. From the data obtained, graphite surface manifested a distinctive behaviour from that of stainless steels. A generalized corrosion was occurred on graphite whereas a localized corrosion was observed for stainless steels. These results show a clear interest of graphite as component material in some of the equipments of the phosphoric acid industry

LE DEVOIR DE LOYAUTE : UN VECTEUR DE LA MORALISATION DE LA VIE DES AFFAIRES

Ce travail a pour objectif de réfléchir sur le devoir de loyauté qui impose au dirigeant une obligation d'information à l’égard des associés et une obligation de non-concurrence à l’égard de la société. Ces deux expressions du devoir trouvent leur fondement dans le pouvoir du dirigeant d'agir dans l'intérêt des associés ou de la société ; le manquement à ce devoir est caractérisé lorsqu'il viole l'une de ces obligations afin de privilégier un intérêt personnel. Devant ce constat, le droit doit encadrer les comportements des dirigeants pour instaurer une moralisation de la vie des affaires

LE SORT DES ACTIONNAIRES MINORITAIRES DNS LES OPERTIONS DE FUSION

Ce travail a pour objectif de préciser qu’il est régulièrement constaté que les opérations de fusions donnent souvent lieu à des oppositions alors même que chaque partie à la fusion est censée être le représentant d’une communauté d’actionnaires et doit par conséquent assurer la sauvegarde des intérêts. A vrai dire, la fusion comporte des risques certains qui ne pèseront d’ailleurs pas toujours sur lesdites parties. Elle emporte ensuite un effet relatif très confronté. On fait allusion dans ce contexte aux risques auxquels les actionnaires sont confrontés et notamment les actionnaires minoritaires qui constituent les parents pauvres dans les opérations de fusion

Preparation and characterization of electrolytic alumina deposit on austenitic stainless steel

Conversion coating modified by alumina has been studied as a way for improving the resistance to thermal oxidation of an austenitic stainless steel. Conversion coating, characterized by a particular morphology and strong interfacial adhesion with the substrate, facilitate the electrochemical deposition of ceramic layers and enhance their adhesion to the substrate. The influence of the current density and treatment time on alumina deposit was studied using statistical experimental designs like Doehlert uniform shell design. After heating, coatings present a continuous composition gradient with refractory compounds at the surface. The behavior at high temperature (1000 8C) of the alumina coating was investigated. The presence of alumina increases the oxidation resistance of an austenitic stainless steel at 1000 8C. The morphology and the chemical composition of the deposit are analyzed. Results on the thermal stability of coating on austenitic stainless steel are presented

Investigations on composition and morphology of electrochemical conversion layer/titanium dioxide deposit on stainless steel

In this study, the formation and characterization of conversion coatings modified by a sol-gel TiO2 deposit were investigated as a way to develop a new photocatalyst for water and air depollution. The conversion coating, characterised by strong interfacial adhesion, high roughness and high surface area facilitates the sol-gel deposition of titania and enhances its adhesion to the substrate. The conversion treatment is carried out in an acid solution. Observation by Scanning Electron Microscopy (SEM) reveals a rough surface with pores and cavities. According to SIMS measurements, the thickness of the initial conversion layer is evaluated at about 1.5 μm. On this pre-functionalised support, the titanium dioxide was deposited by the sol-gel method. The roughness measurements coupled with SIMS analysis allowed a precise evaluation of the surface state of the final layers. The coating consists of two layers: a TiO2 outer layer and an inner layer containing iron chromium oxides. Characterization by X-ray diffraction (XRD) showed the existence of the TiO2 anatase structure as the main compound

An efficient protection of stainless steel against corrosion: Combination of a conversion layer and titanium dioxide deposit

In the present work, a novel process has been developed to improve the corrosion properties of ferritic stainless steels. Titanium oxide coatings have been deposited onto stainless steel by sol–gel process after a pre-functionalization of the substrate in a conversion bath. Gel titania was prepared by hydrolysis of a titanium butoxide through a sol–gel process. Duplex systems "conversion layer/uniform TiO2 coating" have been prepared on stainless steels using a dipping technique and thermal post-treatments at 450 °C. The preparation of sol–gel coatings with specific chemical functions offers tailoring of their structure, texture and thickness and allows the fabrication of large coatings. The morphology and structure of the coatings were analysed using scanning electron microscopy with field effect gun (SEM-FEG), Mass spectroscopy of secondary ions (SIMS) and X-ray diffraction (XRD). The anticorrosion performances and the ageing effects of the coatings have been evaluated in neutral and aggressive media by using several normalized tests. The results show that the conversion layer was not sufficient to protect steel but sol–gel TiO2 coatings, anchored on the metal substrate via the conversion layer, show good adhesion with the substrate and act as a very efficient protective barrier against corrosion. So, duplex layers with TiO2 nanoparticle coatings on steels exhibit an excellent corrosion resistance due to a ceramic protective barrier on metal surface. Analysis of the data indicates that the films act as geometric blocking layers against exposure to the corrosive media and increase drastically the lifetime of the substrate

Influence of temperature and hydrodynamic conditions on the corrosion behavior of AISI 316L stainless steel in pure and polluted H3PO4: Application of the response surface methodology

Phosphoric acid is mainly produced by the wet acid process, where corrosion problems could be intensified due to the presence of impurities in the phosphate ores. Operating temperatures and flowing conditions aggravate the aforementioned problems. This work studies the influence of temperature (25-60 degrees C) and hydrodynamic conditions (Reynolds numbers from 1456 to 5066) on the corrosion of AISI 316L stainless steel in pure and polluted phosphoric acid solutions, by means of cyclic potentiodynamic polarization curves in a hydrodynamic circuit. The effect of temperature is the same as that caused by impurities, that is, higher corrosion rates and hindered passivation and repassivation resistance of the alloy. Statistical analysis by means of surface response methodology proved that the effect of temperature on the corrosion parameters of AISI 316L is more influential than the Reynolds number effect. The Reynolds number seems to have no significant influence on the corrosion behavior of stainless steel. Furthermore, the influence of temperature on the corrosion rate is much higher than on the rest of the corrosion parameters analyzed, especially in polluted phosphoric acid solutions. AISI 316L stainless steel has a clear interest for the phosphoric acid industry as a component material of some equipment due to its good corrosion properties at the different temperatures and Reynolds numbers studied even in polluted media. (C) 2012 Elsevier B.V. All rights reserved.The authors would like to express their gratitude to the Spanish MAEC (PCI Mediterraneo C/8196/07, C/018046/08, D/023608/09, D/030177/10), to the FPU grant given to Rita Sanchez Tovar, to the Generalitat Valenciana for its help in the CLSM acquisition (MY08/ISIRM/S/100) and to Dr. Asuncion Jaime for her translation assistance.Sánchez Tovar, R.; Montañés Sanjuan, MT.; Garcia-Anton, J.; Guenbour, A. (2012). Influence of temperature and hydrodynamic conditions on the corrosion behavior of AISI 316L stainless steel in pure and polluted H3PO4: Application of the response surface methodology. Materials Chemistry and Physics. 133(1):289-298. https://doi.org/10.1016/j.matchemphys.2012.01.024S289298133

Effect of Temperature on Galvanic Corrosion of Non-Welded/Welded AISI 316L Stainless Steel in H3PO4

[EN] Galvanic corrosion of non-welded/welded AISI 316L SS at different temperatures (25 degrees C to 60 degrees C) at a Reynolds number of 1456 in phosphoric acid has been studied using polarization curves (by the mixed potential theory) and zero resistance ammeter (ZRA) measurements. Imposed potential measurements provide more active predicted coupled potentials and higher Galvanic current densities than those obtained using ZRA measurements. Polarization curves show that the anode of the pair is the non-welded AISI 316L. Galvanic current density values obtained from polarization curves increase with temperature. ZRA tests present the highest i(G) values at 60 degrees C; however, the values are very close to zero for all the temperatures studied. This is in agreement with the low value of the compatibility limit and of the parameter which evaluate the Galvanic phenomenon importance. Both techniques present the most positive potentials at the highest temperature.The authors would like to express their gratitude to the Spanish MAEC (PCI Mediterráneo C/018046/08).Sánchez Tovar, R.; Montañés, M.; Garcia-Anton, J.; Guenbour, A. (2010). Effect of Temperature on Galvanic Corrosion of Non-Welded/Welded AISI 316L Stainless Steel in H3PO4. ECS Transactions. 25(37):63-81. https://doi.org/10.1149/1.3407548S6381253

Corrosion Behaviour of a Highly Alloyed Austenitic Alloy UB6 in Contaminated Phosphoric Acid

The influence of temperature (20-80°C) on the electrochemical behaviour of passive films anodically formed on UB6 stainless steel in phosphoric acid solution (5.5 M H3PO4) has been examined by using potentiodynamic curves, electrochemical impedance spectroscopy, and Mott-Schottky analysis. UB6 stainless steel in contaminated phosphoric acid is characterised by high interfacial impedance, thereby, illustrating its high corrosion resistance. The obtained results show that the films behave as n-type and p-type semiconductors in the potential range above and below the flat band potential, respectively. This behaviour is assumed to be the consequence of the semiconducting properties of the iron oxide and chromium oxide regions which compose the passive film