1,027 research outputs found
NaOH treatment of vacuum-plasma-sprayed titanium on carbon fibre-reinforced poly(etheretherketone)
Carbon fibre-reinforced polyetheretherketone (CF-PEEK) substrates were coated with titanium by vacuum-plasma-spraying and chemically treated in 10 M sodium hydroxide (NaOH) solution. After NaOH treatment, the specimens were immersed in simulated body fluid (SBF) containing ions in concentrations similar to those of human blood plasma. Scanning electron microscopy, energy-dispersive X-ray analysis and diffuse reflectance Fourier transformed-infrared spectroscopy were used to analyse the NaOH-treated VPS-Ti surface and the calcium phosphate layer formed during immersion in SBF. It was observed that a carbonate-containing calcium phosphate layer was formed on the NaOH-treated VPS-Ti surface during immersion in SBF, whereas no calcium phosphate precipitation occurred on the untreated surfaces. It is therefore concluded that vacuum-plasma-spraying with titanium and subsequent chemical modification in 10 M NaOH solution at 60°C for 2 h is a suitable method for the preparation of bioactive coatings for bone ongrowth on CF-PEE
Scaling Study and Thermodynamic Properties of the cubic Helimagnet FeGe
The critical behavior of the cubic helimagnet FeGe was obtained from
isothermal magnetization data in very close vicinity of the ordering
temperature. A thorough and consistent scaling analysis of these data revealed
the critical exponents , , and . The
anomaly in the specific heat associated with the magnetic ordering can be well
described by the critical exponent . The values of these
exponents corroborate that the magnetic phase transition in FeGe belongs to the
isotropic 3D-Heisenberg universality class. The specific heat data are well
described by ab initio phonon calculations and confirm the localized character
of the magnetic moments.Comment: 10 pages, 8 figure
Topographical characterization and microstructural interface analysis of vacuum-plasma-sprayed titanium and hydroxyapatite coatings on carbon fibre-reinforced poly(etheretherketone)
In the present study, topographical characterization and microstructural interface analysis of vacuum-plasma-sprayed titanium and hydroxyapatite (HA) coatings on carbon fibre-reinforced polyetheretherketone (CF/PEEK) was performed. VPS-Ti coatings with high roughness values (Ra=28.29±3.07 μm, Rz=145.35±9.88 μm) were obtained. On this titanium, intermediate layer HA coatings of various thicknesses were produced. With increasing coating thickness, roughness values of the HA coatings decreased. A high increase of profile length ratio, Lr, of the VPS-Ti coatings (Lr=1.45) compared to the grit-blasted CF/PEEK substrate (Lr=1.08) was observed. Increasing the HA coating thickness resulted in a reduction of the Lr values similar to the roughness values. Fractal analysis of the obtained roughness profiles revealed that the VPS-Ti coatings showed the highest fractal dimension of D=1.34±0.02. Fractal dimension dropped to a value of 1.23-1.25 for all HA coatings. No physical deterioration of the CF/PEEK substrate was observed, indicating that substrate drying and the used VPS process parameter led to the desired coatings on the composite material. Cross-section analysis revealed a good interlocking between the titanium intermediate layer and the PEEK substrate. It is therefore assumed that this interlocking results in suitable mechanical adhesive strength. From the results obtained in this study it is concluded that VPS is a suitable method for manufacturing HA coatings on carbon fibre-reinforced PEEK implant material
Striped instability of a holographic Fermi-like liquid
We consider a holographic description of a system of strongly-coupled
fermions in 2+1 dimensions based on a D7-brane probe in the background of
D3-branes. The black hole embedding represents a Fermi-like liquid. We study
the excitations of the Fermi liquid system. Above a critical density which
depends on the temperature, the system becomes unstable towards an
inhomogeneous modulated phase which is similar to a charge density and spin
wave state. The essence of this instability can be effectively described by a
Maxwell-axion theory with a background electric field. We also consider the
fate of zero sound at non-zero temperature.Comment: 16 pages, 9 figures; v2: added discussion and one figure. Typos
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Quantum state transformation by dispersive and absorbing four-port devices
The recently derived input-output relations for the radiation field at a
dispersive and absorbing four-port device [T. Gruner and D.-G. Welsch, Phys.
Rev. A 54, 1661 (1996)] are used to derive the unitary transformation that
relates the output quantum state to the input quantum state, including
radiation and matter and without placing frequency restrictions. It is shown
that for each frequency the transformation can be regarded as a well-behaved
SU(4) group transformation that can be decomposed into a product of U(2) and
SU(2) group transformations. Each of them may be thought of as being realized
by a particular lossless four-port device. If for narrow-bandwidth radiation
far from the medium resonances the absorption matrix of the four-port device
can be disregarded, the well-known SU(2) group transformation for a lossless
device is recognized. Explicit formulas for the transformation of Fock-states
and coherent states are given.Comment: 24 pages, RevTe
The Energy Density in the Casimir Effect
We compute the expectations of the squares of the electric and magnetic
fields in the vacuum region outside a half-space filled with a uniform
dispersive dielectric. We find a positive energy density of the electromagnetic
field which diverges at the interface despite the inclusion of dispersion in
the calculation. We also investigate the mean squared fields and the energy
density in the vacuum region between two parallel half-spaces. Of particular
interest is the sign of the energy density. We find that the energy density is
described by two terms: a negative position independent (Casimir) term, and a
positive position dependent term with a minimum value at the center of the
vacuum region. We argue that in some cases, including physically realizable
ones, the negative term can dominate in a given region between the two
half-spaces, so the overall energy density can be negative in this region.Comment: 16 pages, 4 figures; 3 references and some new material in Sect. 4.4
adde
Magnetic properties of small Pt-capped Fe, Co and Ni clusters: A density functional theory study
Theoretical studies on M (M = Fe, Co, Ni) and MPt (for
= 3, 4, 5, 20) clusters including the spin-orbit coupling are done using
density functional theory. The magnetic anisotropy energy (MAE) along with the
spin and orbital moments are calculated for M icosahedral clusters. The
angle-dependent energy differences are modelled using an extended classical
Heisenberg model with local anisotropies. From our studies, the MAE for
Jahn-Teller distorted Fe, Mackay distorted Fe and nearly
undistorted Co clusters are found to be 322, 60 and 5 eV/atom,
respectively, and are large relative to the corresponding bulk values, (which
are 1.4 and 1.3 eV/atom for bcc Fe and fcc Co, respectively.) However, for
Ni (which practically does not show relaxation tendencies), the
calculated value of MAE is found to be 0.64 eV/atom, which is
approximately four times smaller compared to the bulk fcc Ni (2.7
eV/atom). In addition, MAE of the capped cluster (FePt) is
enhanced compared to the uncapped Jahn-Teller distorted Fe cluster
Lattice dynamics and structural stability of ordered Fe3Ni, Fe3Pd and Fe3Pt alloys
We investigate the binding surface along the Bain path and phonon dispersion
relations for the cubic phase of the ferromagnetic binary alloys Fe3X (X = Ni,
Pd, Pt) for L12 and DO22 ordered phases from first principles by means of
density functional theory. The phonon dispersion relations exhibit a softening
of the transverse acoustic mode at the M-point in the L12-phase in accordance
with experiments for ordered Fe3Pt. This instability can be associated with a
rotational movement of the Fe-atoms around the Ni-group element in the
neighboring layers and is accompanied by an extensive reconstruction of the
Fermi surface. In addition, we find an incomplete softening in [111] direction
which is strongest for Fe3 Ni. We conclude that besides the valence electron
density also the specific Fe-content and the masses of the alloying partners
should be considered as parameters for the design of Fe-based functional
magnetic materials.Comment: Revised version, accepted for publication in Physical Review
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