28 research outputs found
Pressure-induced decoupling of the order-disorder and displacive contributions to the phase transition in diguanidinium tetrachlorostannate
Proton Spin-Lattice Relaxation in Organic Molecular Solids: Polymorphism and the Dependence on Sample Preparation
We report solidâstate nuclear magnetic resonance 1H spinâlattice relaxation, singleâcrystal Xâray diffraction, powder Xâray diffraction, field emission scanning electron microscopy, and differential scanning calorimetry in solid samples of 2âethylanthracene (EA) and 2âethylanthraquinone (EAQ) that have been physically purified in different ways from the same commercial starting compounds. The solidâstate 1H spinâlattice relaxation is always nonâexponential at high temperatures as expected when CH3 rotation is responsible for the relaxation. The 1H spinâlattice relaxation experiments are very sensitive to the âseveralâmoleculeâ (clusters) structure of these van der Waals molecular solids. In the three differently prepared samples of EAQ, the relaxation also becomes very nonâexponential at low temperatures. This is very unusual and the decay of the nuclear magnetization can be fitted with both a stretched exponential and a double exponential. This unusual result correlates with the powder Xâray diffractometry results and suggests that the anomalous relaxation is due to crystallites of two (or more) different polymorphs (concomitant polymorphism)
PetaFLOP Molecular Dynamics for Engineering Applications
Molecular dynamics (MD) simulations enable the investigation of multicomponent and multiphase processes relevant to engineering applications, such as droplet coalescence or bubble formation. These scenarios require the simulation of ensembles containing a large number of molecules. We present recent advances within the MD framework ls1 mardyn which is being developed with particular regard to this class of problems. We discuss several OpenMP schemes that deliver optimal performance at node-level. We have further introduced nonblocking communication and communication hiding for global collective operations. Together with revised data structures and vectorization, these improvements unleash PetaFLOP performance and enable multi-trillion atom simulations on the HLRS supercomputer Hazel Hen. We further present preliminary results achieved for droplet coalescence scenarios at a smaller scale.BMBF, 01IH16008, Verbundprojekt: TaLPas - Task-basierte Lastverteilung und Auto-Tuning in der Partikelsimulatio
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On Computationally-Enhanced Visual Analysis of Heterogeneous Data and Its Application in Biomedical Informatics
Structure, phase transitions and dielectric properties of a new inclusion compound of bis-thiourea pyridinium nitrate salt
NMR Study of Ion Motions in [C(NH)]GaF
Proton and fluorine spin-lattice relaxation times as well as second moments were measured in guanidinium hexafluorogallate over a wide range of temperature. The analysis of all cross-relaxation effects occurring in the four unlike spin system revealed two cation motions and yielded their activation parameters. It was found that the anion size did not influence C reorientation of cation nor isotropic reorientation of anion
ACTA PHYSICA POLONICA A NMR STUDY OF ION MOTIONS IN [C(NH 2 ) 3 ] 3 GaF6
Proton and fluorine spin-lattice relaxation times as well as second moments were measured in guanidinium hexafluorogallate over a wide range of temperature. The analysis of all cross-relaxation effects occurring in the four unlike spin system revealed two cation motions and yielded their activation parameters. It was found that the anion size did not influence C3 reorientation of cation nor isotropic reorientation of anion