Poisoning of Hydrogen Dissociation at Pd (100) by Adsorbed Sulfur Studied by ab initio Quantum Dynamics and ab initio Molecular Dynamics

We report calculations of the dissociative adsorption of H_2 at Pd (100) covered with 1/4 monolayer of sulfur using quantum dynamics as well as molecular dynamics and taking all six degrees of freedom of the two H atoms fully into account. The ab initio potential-energy surface (PES) is found to be very strongly corrugated. In particular we discuss the influence of tunneling, zero-point vibrations, localization of the nuclei's wave function when narrow valleys of the PES are passed, steering of the approaching H_2 molecules towards low energy barrier configurations, and the time scales of the center of mass motion and the other degrees of freedom. Several ``established'' concepts, which were derived from low-dimensional dynamical studies, are shown to be not valid.Comment: 4 pages, 3 figures, submitted to Surf. Sci. Lett. Other related publications can be found at http://www.rz-berlin.mpg.de/th/paper.htm

Spin and angular momentum in the nucleon

Using the covariant spectator theory (CST), we present the results of a valence quark-diquark model calculation of the nucleon structure function f(x) measured in unpolarized deep inelastic scattering (DIS), and the structure functions g1(x) and g2(x) measured in DIS using polarized beams and targets. Parameters of the wave functions are adjusted to fit all the data. The fit fixes both the shape of the wave functions and the relative strength of each component. Two solutions are found that fit f(x) and g1(x), but only one of these gives a good description of g2(x). This fit requires the nucleon CST wave functions contain a large D-wave component (about 35%) and a small P-wave component (about 0.6%). The significance of these results is discussed.Comment: 27 pages; 13 figure

Quivers, curves, and the tropical vertex

Elements of the tropical vertex group are formal families of symplectomorphisms of the 2-dimensional algebraic torus. Commutators in the group are related to Euler characteristics of the moduli spaces of quiver representations and the Gromov-Witten theory of toric surfaces. After a short survey of the subject (based on lectures of Pandharipande at the 2009 Geometry summer school in Lisbon), we prove new results about the rays and symmetries of scattering diagrams of commutators (including previous conjectures by Gross-Siebert and Kontsevich). Where possible, we present both the quiver and Gromov-Witten perspectives.Comment: 43 page

Large-N limit of the generalized 2D Yang-Mills theory on cylinder

Using the collective field theory approach of large-N generalized two-dimensional Yang-Mills theory on cylinder, it is shown that the classical equation of motion of collective field is a generalized Hopf equation. Then, using the Itzykson-Zuber integral at the large-N limit, it is found that the classical Young tableau density, which satisfies the saddle-point equation and determines the large-N limit of free energy, is the inverse of the solution of this generalized Hopf equation, at a certain point.Comment: 11 pages, add a paragraph after eq.(20) and add one reference, accepted for publication in: Nucl. Phys. B (2000

Explosive hypervelocity drag accelerator

Accelerator for launching hypervelocity projectile by drag force of jet produced by gaseous explosive product