Sequential pulsed laser deposition of homoepitaxial SrTiO3_3 thin films

Control of thin film stoichiometry is of primary relevance to achieve desired functionality. Pulsed laser deposition ablating from binary-oxide targets (sequential deposition) can be applied to precisely control the film composition, offsetting the importance of growth conditions on the film stoichiometry. In this work, we demonstrate that the cation stoichiometry of SrTiO$_3$ thin films can be finely tuned by sequential deposition from SrO and TiO$_2$ targets. Homoepitaxial SrTiO$_3$ films were deposited at different substrate temperatures and Ti/Sr pulse ratios, allowing the establishment of a growth window for stoichiometric SrTiO$_3$. The growth kinetics and nucleation processes were studied by reflection high-energy electron diffraction and atomic force microscopy, providing information about the growth mode and the degree of off-stoichiometry. At the optimal (stoichiometric) growth conditions, films exhibit atomically flat surfaces, whereas off-stoichiometry is accommodated by crystal defects, 3D islands and/or surface precipitates depending on the substrate temperature and the excess cation. This technique opens the way to precisely control stoichiometry and doping of oxide thin films.Comment: 6 pages, 5 figure

On the semantics and logic of declaratives and interrogatives

In many natural languages, there are clear syntactic and/or intonational differences between declarative sentences, which are primarily used to provide information, and interrogative sentences, which are primarily used to request information. Most logical frameworks restrict their attention to the former. Those that are concerned with both usually assume a logical language that makes a clear syntactic distinction between declaratives and interrogatives, and usually assign different types of semantic values to these two types of sentences. A different approach has been taken in recent work on inquisitive semantics. This approach does not take the basic syntactic distinction between declaratives and interrogatives as its starting point, but rather a new notion of meaning that captures both informative and inquisitive content in an integrated way. The standard way to treat the logical connectives in this approach is to associate them with the basic algebraic operations on these new types of meanings. For instance, conjunction and disjunction are treated as meet and join operators, just as in classical logic. This gives rise to a hybrid system, where sentences can be both informative and inquisitive at the same time, and there is no clearcut division between declaratives and interrogatives. It may seem that these two general approaches in the existing literature are quite incompatible. The main aim of this paper is to show that this is not the case. We develop an inquisitive semantics for a logical language that has a clearcut division between declaratives and interrogatives. We show that this language coincides in expressive power with the hybrid language that is standardly assumed in inquisitive semantics, we establish a sound and complete axiomatization for the associated logic, and we consider a natural enrichment of the system with presuppositional interrogatives

Prediction of nitrogen and phosphorus leaching to groundwater and surface waters; process descriptions of the animo4.0 model

The fertilization reduction policy intended to pursue environmental objects and regional water management strategies to meet Water Framework Directive objectives justify a thorough evaluation of the effectiveness of measures and reconnaissance of adverse impacts. The model aims at the evaluation and prediction of nutrient leaching to groundwater and surface water systems under the influence of fertilization, land use and land management, water management and soil properties. Since the release of animo version 3.5 some new model formulations have been implemented regarding the influence of soil moisture content on mineralization and denitrification. Also the input of daily nutrient uptake rates as simulation results of external crop models is facilitated. A concise description is presented of the process descriptions as have been implemented in version 4.0 of the animo mode

Epitaxial growth and thermodynamic stability of SrIrO3/SrTiO3 heterostructures

Obtaining high-quality thin films of 5d transition metal oxides is essential to explore the exotic semimetallic and topological phases predicted to arise from the combination of strong electron correlations and spin-orbit coupling. Here, we show that the transport properties of SrIrO3 thin films, grown by pulsed laser deposition, can be optimized by considering the effect of laser-induced modification of the SrIrO3 target surface. We further demonstrate that bare SrIrO3 thin films are subject to degradation in air and are highly sensitive to lithographic processing. A crystalline SrTiO3 cap layer deposited in-situ is effective in preserving the film quality, allowing us to measure metallic transport behavior in films with thicknesses down to 4 unit cells. In addition, the SrTiO3 encapsulation enables the fabrication of devices such as Hall bars without altering the film properties, allowing precise (magneto)transport measurements on micro- and nanoscale devices.Comment: 5 pages, 3 figure

Two-dimensional superconductivity at the (111)LaAlO3_3/SrTiO3_3 interface

We report on the discovery and transport study of the superconducting ground state present at the (111)LaAlO$_3$/SrTiO$_3$ interface. The superconducting transition is consistent with a Berezinskii-Kosterlitz-Thouless transition and its 2D nature is further corroborated by the anisotropy of the critical magnetic field, as calculated by Tinkham. The estimated superconducting layer thickness and coherence length are 10 nm and 60 nm, respectively. The results of this work provide a new platform to clarify the microscopic details of superconductivity at LaAlO$_3$/SrTiO$_3$ interfaces, in particular in what concerns the link with orbital symmetry.Comment: 4 pages, 4 figure