36 research outputs found

    Structural-phase and Strained State of Vacuum-ARC Mo-N Coatings

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    The effect of substrate bias on the structural-phase and elastic stress-strained state during the formation of vacuum-arc deposited nanostructural coatings of the Mo–N system has been studied. An increase in the bias potential leads to (i) predominant [111] orientation of the growing molybdenum nitride crystals with a NaCl-type cubic lattice (Ξ³-Mo2N phase) and (ii) the appearance of a second phase with a body-centered cubic crystal lattice that is characteristic of pure molybdenum. The elastically strained (stressed) state of the coating is determined not only by the conditions of deposition, but also by the mechanical properties of a substrate. In order to provide for formation of coatings in a high-elastic-strained (stressed) state, it is necessary to deposit coatings onto substrates with high elastic modulus, which prevent metal flow at the interface. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3480

    The Influence of Thickness of the Layers on Structural-Phase and Strained State of Multiperiod Nanolayer Ti/TiN Coatings

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    The influence of condition of vacuum-arc multi-layer TiN/Ti coatings on their phase composition, structure, stress state and mechanical properties has been studied. The regularities of the phase composition, structural state of stress, hardness with dependence on the magnitude of the negative bias applied to the substrate during the deposition and the thickness of the Ti and TiN layers in a multilayer coating were obtained. The analysis of the causes of observed changes, based on the mechanism of formation of surface layers of vacuum-arc coatings in the condition of implantation processes stimulated by applying a negative bias to the substrate was held. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3481

    Fast Diffusion Process in Quenched hcp Dilute Solid 3^3He-4^4He Mixture

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    The study of phase structure of dilute 3^3He - 4^4He solid mixture of different quality is performed by spin echo NMR technique. The diffusion coefficient is determined for each coexistent phase. Two diffusion processes are observed in rapidly quenched (non-equilibrium) hcp samples: the first process has a diffusion coefficient corresponding to hcp phase, the second one has huge diffusion coefficient corresponding to liquid phase. That is evidence of liquid-like inclusions formation during fast crystal growing. It is established that these inclusions disappear in equilibrium crystals after careful annealing.Comment: 7 pages, 3 figures, QFS200

    COPPER(II), SILVER(I) AND GOLD(III) COMPLEXES WITH 2(4)-AZAFLUORENES AND THEIR METHYL ANALOGS

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    COPPER(II), SILVER(I) AND GOLD(III) COMPLEXES WITH 2(4)-AZAFLUORENES AND THEIR METHYL ANALOGS

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