Energetics of hydrogen/lithium complexes in silicon analyzed using the Maxwell construction

We have studied hydrogen/lithium complexes in crystalline silicon using density-functional-theory methods and the ab initio random structure searching (AIRSS) method for predicting structures. A method based on the Maxwell construction and convex hull diagrams is introduced which gives a graphical representation of the relative stabilities of point defects in a crystal and enables visualization of the changes in stability when the chemical potentials are altered. We have used this approach to study lithium and hydrogen impurities in silicon, which models aspects of the anode material in the recently-suggested lithium-ion batteries. We show that hydrogen may play a role in these anodes, finding that hydrogen atoms bind to three-atom lithium clusters in silicon, forming stable {H,3Li} and {2H,3Li} complexes, while the {H,2Li} complex is almost stable.Comment: (5 pages, 4 figures

Altitude performance of a low-noise-technology fan in a turbofan engine with and without a sound suppressing nacelle

Test variables were inlet Reynolds number index (0.2 to 0.5), flight Mach number (0.2 to 0.8), and flow distortion (tip radial and combined circumferential - tip radial patterns). Results are limited to fan bypass and overall engine performance. There were no discernible effects of Reynolds number on fan performance. Increasing flight Mach number shifted the fan operating line such that pressure ratio decreased and airflow increased. Inlet flow distortion lowered stall margin. For a Reynolds number index of 0.2 and flight Mach number of 0.54, the sound suppressing nacelle lowered fan efficiency three points and increased specific fuel consumption about 10 percent

Cardiovascular effects of calcium supplementation

Peer reviewedPostprin

Lithiation of silicon via lithium Zintl-defect complexes

An extensive search for low-energy lithium defects in crystalline silicon using density-functional-theory methods and the ab initio random structure searching (AIRSS) method shows that the four-lithium-atom substitutional point defect is exceptionally stable. This defect consists of four lithium atoms with strong ionic bonds to the four under-coordinated atoms of a silicon vacancy defect, similar to the bonding of metal ions in Zintl phases. This complex is stable over a range of silicon environments, indicating that it may aid amorphization of crystalline silicon and form upon delithiation of the silicon anode of a Li-ion rechargeable battery.Comment: 4 pages, 3 figure

Calcium supplements with or without vitamin D and risk of cardiovascular events : reanalysis of the Women's Health Initiative limited access dataset and meta-analysis

Peer reviewedPublisher PD

Identifying the causal mechanisms of the quiet eye

Scientists who have examined the gaze strategies employed by athletes have determined that longer quiet eye (QE) durations (QED) are characteristic of skilled compared to less-skilled performers. However, the cognitive mechanisms of the QE and, specifically, how the QED affects performance are not yet fully understood. We review research that has examined the functional mechanism underlying QE and discuss the neural networks that may be involved. We also highlight the limitations surrounding QE measurement and its definition and propose future research directions to address these shortcomings. Investigations into the behavioural and neural mechanisms of QE will aid the understanding of the perceptual and cognitive processes underlying expert performance and the factors that change as expertise develops

Calcium supplements and cancer risk : a meta-analysis of randomised controlled trials

Peer reviewedPublisher PD

Effect of calcium supplements on risk of myocardial infarction and cardiovascular events : meta-analysis

Peer reviewedPublisher PD