3,839 research outputs found
Nanostructured graphene for spintronics
Zigzag edges of the honeycomb structure of graphene exhibit magnetic
polarization making them attractive as building blocks for spintronic devices.
Here, we show that devices with zigzag edged triangular antidots perform
essential spintronic functionalities, such as spatial spin-splitting or spin
filtering of unpolarized incoming currents. Near-perfect performance can be
obtained with optimized structures. The device performance is robust against
substantial disorder. The gate-voltage dependence of transverse resistance is
qualitatively different for spin-polarized and spin-unpolarized devices, and
can be used as a diagnostic tool. Importantly, the suggested devices are
feasible within current technologies.Comment: 6 pages, 5 figures, publishe
Graphene on graphene antidot lattices: Electronic and transport properties
Graphene bilayer systems are known to exhibit a band gap when the layer
symmetry is broken, by applying a perpendicular electric field. The resulting
band structure resembles that of a conventional semiconductor with a parabolic
dispersion. Here, we introduce a novel bilayer graphene heterostructure, where
single-layer graphene is placed on top of another layer of graphene with a
regular lattice of antidots. We dub this class of graphene systems GOAL:
graphene on graphene antidot lattice. By varying the structure geometry, band
structure engineering can be performed to obtain linearly dispersing bands
(with a high concomitant mobility), which nevertheless can be made gapped with
the perpendicular field. We analyze the electronic structure and transport
properties of various types of GOALs, and draw general conclusions about their
properties to aid their design in experiments.Comment: 13 pages, 10 figures, submitte
Dichotomy in the Dynamical Status of Massive Cores in Orion
To study the evolution of high mass cores, we have searched for evidence of
collapse motions in a large sample of starless cores in the Orion molecular
cloud. We used the Caltech Submillimeter Observatory telescope to obtain
spectra of the optically thin (\H13CO+) and optically thick (\HCO+) high
density tracer molecules in 27 cores with masses 1 \Ms. The red- and
blue-asymmetries seen in the line profiles of the optically thick line with
respect to the optically thin line indicate that 2/3 of these cores are not
static. We detect evidence for infall (inward motions) in 9 cores and outward
motions for 10 cores, suggesting a dichotomy in the kinematic state of the
non-static cores in this sample. Our results provide an important observational
constraint on the fraction of collapsing (inward motions) versus non-collapsing
(re-expanding) cores for comparison with model simulations.Comment: 9 pages, 2 Figures. To appear in ApJ(Letters
Saline Aquifer CO2 Storage (SACS2). Final report, geological characterisation of the Utsira Sand reservoir and caprocks (Work Area 1)
This report summarises the results and highlights the main findings of SACS Work Area 1, the
geological and reservoir characterisation of the Utsira Sand and its caprock. For more detailed
technical information on each topic, the reader is directed to the relevant SACS Technical Reports and,
in particular, two earlier Work Area 1 interim reports, Holloway et al. (1999) and Chadwick et al.
(2000).
The Utsira Sand comprises a basinally-restricted deposit of Mio-Pliocene age forming a clearly
defined seismic unit, pinching out to east and west, and seismically distinct from overlying and
underlying strata.The reservoir is highly elongated, extending for more than 400 km from north to
south and between 50 and 100 km from east to west, with an area of some 26100 km2. Its eastern and
western limits are defined by stratigraphical lap-out, to the southwest it passes laterally into shaly
sediments, and to the north it occupies a narrow channel deepening towards the More Basin. Locally,
particularly in the north, depositional patterns are quite complex with some isolated depocentres, and
lesser areas of non-deposition within the main depocentre. The top Utsira Sand surface generally
varies relatively smoothly, mainly in the range 550 to 1500 m, but mostly from 700 to 1000 m. The
base of the sand is more irregular, disturbed by diapirism of the underlying shales. Isopachs of the
reservoir sand show two main depocentres. One is in the south, around Sleipner, where thicknesses
range up to more than 300 m. The second depocentre lies some 200 km to the north of Sleipner. Here
the Utsira Sand is locally 200 m thick, with an underlying sandy unit adding further to the total
reservoir thickness.
Macroscopic and microscopic analysis of core and cuttings samples of the Utsira Sand show that it
consists of a largely uncemented fine-grained sand, with medium and occasional coarse grains. The
grains are predominantly angular to sub-angular and consist primarily of quartz with some feldspar and
shell fragments. Sheet silicates are present in small amounts (a few percent). The sand is interpreted as
being deposited by mass flows in a marine environment in water depths of 100 m or more. The
porosity of the Utsira Sand core ranges generally from 27% to 31%, but reaches values as high as 42%
Regional log porosities are quite uniform, in the range 35 to 40% over much of the reservoir.
Geophysical logs show a number of peaks on the -ray, sonic and neutron density logs, and also on
some induction and resistivity logs. These are interpreted as mostly marking thin (~1m thick) intrareservoir
shale layers. The shale layers constitute important permeability barriers within the reservoir
sand, and have proved to have a significant effect on CO2 migration through, and entrapment within,
the reservoir. The proportion of clean sand in the total reservoir thickness varies generally from about
0.7 to nearly 1.0.
The caprock succession overlying the Utsira reservoir is rather variable, and can be divided into three
main units. The Lower Seal forms a shaly basin-restricted unit, some 50 to 100 m thick. The Middle
Seal mostly comprises prograding sediment wedges of Pliocene age, dominantly shaly in the basin
centre, but coarsening into a sandier facies both upwards and towards the basin margins. The Upper
Seal comprises Quaternary strata, mostly glacio-marine clays and glacial tills. The Lower Seal extends
well beyond the area currently occupied by the CO2 injected at Sleipner and seems to be providing an
effective seal at the present time. Cuttings samples comprise dominantly grey clay silts or silty clays.
Most are massive although some show a weak sedimentary lamination. XRD analysis typically reveal
quartz (30%), undifferentiated mica (30%), kaolinite (14%), K-feldspar (5%), calcite (4%), smectite
(4%), albite (2%), chlorite (1%), pyrite (1%) and gypsum (1%) together with traces of drilling mud
contamination. The clay fraction is generally dominated by illite with minor kaolinite and traces of
chlorite and smectite. The cuttings samples are classified as non-organic mudshales and mudstones.
Although the presence of small quantities of smectite may invalidate its predictions, XRD-determined
quartz contents suggest displacement pore throat diameters in the range 14 to 40 nm. Such
displacement pore throat diameters are consistent with capillary entry pressures of between about 2 and 5.5 MPa capable of trapping a CO2 column several hundred metres high. In addition, the
predominant clay fabric with limited grain support resembles caprocks which are stated in the
literature to be capable of supporting a column of 35 API oil greater than 150 m in height.
Empirically, therefore, the caprock samples suggest the presence of an effective seal at Sleipner, with
capillary leakage of CO2 unlikely to occur. Around and east of the injection point, a layer of sand, 0 -
50 m thick, lies close to the base of the Lower Seal and is termed the Sand-wedge. The geometry of
this unit is likely to prove important in determining the long-term migration behaviour of the CO2.
Fluid flow in the Utsira Sand, based on limited pressure measurements and basin-modelling, is likely
to be low, in the range 0.3 – 4 metres per year, depending on assumed permeabilities.
The total pore-space within the Utsira Sand is estimated at 6.05 x 1011 m3. However not all of this can
necessarily be utilised for CO2 storage. The simplest assumption is that long-term storage of CO2 can
only be accomplished in structural traps at the top of the reservoir. A detailed study around Sleipner
indicates that 0.3% of the reservoir porosity is actually situated within structural closures such as this.
In practical terms moreover, with a small number of injection wells, it is unlikely that all of the small
traps could be utilised in any case. Around Sleipner the most realistic estimate of the pore-space
situated within accessible closed structures is just 0.11% of the total pore-volume. On the other hand,
trapping of CO2 beneath the intra-reservoir shales could significantly increase realisable storage
volumes, particularly if it encouraged dissolution of CO2 into the groundwater. Similarly trapping of
CO2 in the Sand-wedge, as well as beneath the top of the Utsira Sand, will increase the overall storage
capacity significantly. In conclusion, the theoretical storage capacity of the Utsira Sand is very high,
but how much of this can be utilised in reality is uncertain, and a function of several complex
parameters.
Migration models have been constructed with 30 x 106 m3 of CO2, injected into the Utsira Sand
(approximating to the expected final injected mass of 20 million tonnes). They show that if the CO2 is
trapped at the top of the Utsira Sand it will migrate generally northwestward, reaching a maximum
distance from the injection site of about 12 km. However, if the CO2 is trapped within the Sand-wedge,
migration is less well constrained, being northwards then northeastwards. Data limitations to the east
of the injection point preclude quantitative estimates of the maximum migration distance in this case
Charge and Spin Transport Anisotropy in Nanopatterned Graphene
Anisotropic electronic transport is a possible route towards nanoscale
circuitry design, particularly in two-dimensional materials. Proposals to
introduce such a feature in patterned graphene have to date relied on
large-scale structural inhomogeneities. Here we theoretically explore how a
random, yet homogeneous, distribution of zigzag-edged triangular perforations
can generate spatial anisotropies in both charge and spin transport.
Anisotropic electronic transport is found to persist under considerable
disordering of the perforation edges, suggesting its viability under realistic
experimental conditions. Furthermore, controlling the relative orientation of
perforations enables spin filtering of the transmitted electrons, resulting in
a half-metallic anisotropic transport regime. Our findings point towards a
co-integration of charge and spin control in a two-dimensional platform of
relevance for nanocircuit design. We further highlight how geometrical effects
allow finite samples to display finite transverse resistances, reminiscent of
Spin Hall effects, in the absence of any bulk fingerprints of such mechanisms,
and explore the underlying symmetries behind this behaviour.Comment: 11 pages, 6 figure
Does Infall End Before the Class I Stage?
We have observed HCO+ J=3-2 toward 16 Class I sources and 18 Class 0 sources,
many of which were selected from Mardones et al. (1997). Eight sources have
profiles significantly skewed to the blue relative to optically thin lines. We
suggest six sources as new infall candidates. We find an equal "blue excess"
among Class 0 and Class I sources after combining this sample with that of
Gregersen et al. (1997). We used a Monte Carlo code to simulate the temporal
evolution of line profiles of optically thick lines of HCO+, CS and H2CO in a
collapsing cloud and found that HCO+ had the strongest asymmetry at late times.
If a blue-peaked line profile implies infall, then the dividing line between
the two classes does not trace the end of the infall stage.Comment: 21 pages, 8 figures, accepted by ApJ for April 20, 2000, added
acknowledgmen
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