3,209 research outputs found
The changing UK careers landscape : tidal waves, turbulence and transformation
This article explores how the UK careers landscape in each of the four home nations is changing in response to neo-liberal policies. In this context, careers services are increasingly under pressure to demonstrate their added value, impact and returns on investment. As fiscal arrangements tighten and governments state their preferences and priorities for national careers services, differing strategic responses are beginning to emerge. A quasi-market, experimental approach is now the dominant discourse in England, in contrast to differing and complementary arrangements in Northern Ireland, Scotland and Wales. The article suggests that insofar as these developments are transforming national careers services, they are also creating significant challenges which require new forms of policy imagery and imagination for high-impact, all-age careers services
Liquid-Solid Phase Transition of the System with Two particles in a Rectangular Box
We study the statistical properties of two hard spheres in a two dimensional
rectangular box. In this system, the relation like Van der Waals equation loop
is obtained between the width of the box and the pressure working on side
walls. The auto-correlation function of each particle's position is calculated
numerically. By this calculation near the critical width, the time at which the
correlation become zero gets longer according to the increase of the height of
the box. Moreover, fast and slow relaxation processes like and
relaxations observed in supper cooled liquid are observed when the height of
the box is sufficiently large. These relaxation processes are discussed with
the probability distribution of relative position of two particles.Comment: 6 figure
Postfeminist Media Cultures
This entry provides an overview of postfeminism, which has become central in the last two decades not only within feminist cultural discourse but also within neoliberal discourses and popular culture. The dominant attempts to conceptualize postfeminism often bring to the surface approaches that are complex and contradictory in nature. For instance, postfeminism is viewed as a theoretical framework, as a sensibility, as an expansion of feminist theory, or as a rejection of it. The discussion of postfeminism against the backdrop of media productions further highlights its implications for women and gender representation. A look at quintessential postfeminist texts shows, for instance, that postfeminism essentially problematizes contemporary constructions of gender as it simultaneously evokes and rejects basic feminist tenets
Accurate ab initio spin densities
We present an approach for the calculation of spin density distributions for
molecules that require very large active spaces for a qualitatively correct
description of their electronic structure. Our approach is based on the
density-matrix renormalization group (DMRG) algorithm to calculate the spin
density matrix elements as basic quantity for the spatially resolved spin
density distribution. The spin density matrix elements are directly determined
from the second-quantized elementary operators optimized by the DMRG algorithm.
As an analytic convergence criterion for the spin density distribution, we
employ our recently developed sampling-reconstruction scheme [J. Chem. Phys.
2011, 134, 224101] to build an accurate complete-active-space
configuration-interaction (CASCI) wave function from the optimized matrix
product states. The spin density matrix elements can then also be determined as
an expectation value employing the reconstructed wave function expansion.
Furthermore, the explicit reconstruction of a CASCI-type wave function provides
insights into chemically interesting features of the molecule under study such
as the distribution of - and -electrons in terms of Slater
determinants, CI coefficients, and natural orbitals. The methodology is applied
to an iron nitrosyl complex which we have identified as a challenging system
for standard approaches [J. Chem. Theory Comput. 2011, 7, 2740].Comment: 37 pages, 13 figure
String-like Clusters and Cooperative Motion in a Model Glass-Forming Liquid
A large-scale molecular dynamics simulation is performed on a glass-forming
Lennard-Jones mixture to determine the nature of dynamical heterogeneities
which arise in this model fragile liquid. We observe that the most mobile
particles exhibit a cooperative motion in the form of string-like paths
(``strings'') whose mean length and radius of gyration increase as the liquid
is cooled. The length distribution of the strings is found to be similar to
that expected for the equilibrium polymerization of linear polymer chains.Comment: 6 pages of RevTex, 6 postscript figures, uses epsf.st
Muon spin rotation and relaxation in magnetic materials
A review of the muon spin rotation and relaxation (SR) studies on
magnetic materials published from July 1993 is presented. It covers the
investigation of magnetic phase diagrams, of spin dynamics and the analysis of
the magnetic properties of superconductors. We have chosen to focus on selected
experimental works in these different topics. In addition, a list of published
works is provided.Comment: Review article, 59 pages, LaTeX with IoP macro
The negatively charged nitrogen-vacancy centre in diamond: the electronic solution
The negatively charged nitrogen-vacancy centre is a unique defect in diamond
that possesses properties highly suited to many applications, including quantum
information processing, quantum metrology, and biolabelling. Although the
unique properties of the centre have been extensively documented and utilised,
a detailed understanding of the physics of the centre has not yet been
achieved. Indeed there persists a number of points of contention regarding the
electronic structure of the centre, such as the ordering of the dark
intermediate singlet states. Without a sound model of the centre's electronic
structure, the understanding of the system's unique dynamical properties can
not effectively progress. In this work, the molecular model of the defect
centre is fully developed to provide a self consistent model of the complete
electronic structure of the centre. The application of the model to describe
the effects of electric, magnetic and strain interactions, as well as the
variation of the centre's fine structure with temperature, provides an
invaluable tool to those studying the centre and a means to design future
empirical and ab initio studies of this important defect.Comment: 24 pages, 6 figures, 10 table
Grain refinement of Al-Mg-Sc alloy by ultrasonic treatment
In foundry practice, ultrasonic treatment has been used as an efficient technique to achieve grain refinement in aluminium and magnesium alloys. This article shows the strong effect of pouring temperature and ultrasonic treatment at various temperatures on the grain refinement of Al-1 wt% Mg-0.3 wt% Sc alloy. Without ultrasonic treatment, a fine grain structure was obtained at the pouring temperature of 700 °C. The average grain size sharply decreases from 487 ± 20 to 103 ± 2 μm when the pouring temperature decreases from 800 to 700 °C. Ultrasonic vibration proved to be a potential grain refinement technique with a wide range of pouring tem- perature. A microstructure with very fine and homogeneous grains was obtained by applying ultrasonic treatment to the melt at the temperature range between 700 and 740 °C, before pouring. Cavitation-enhanced hetero- geneous nucleation is the mechanism proposed to explain grain refinement by ultrasound in this alloy. Moreover, ultrasonic treatment of the melt was found to lead to cast samples with hardness values similar to those obtained in samples submitted to precipitation hardening, suggesting that ultrasonic treatment can avoid carrying out heat treatment of cast parts.This research was supported by The Project Bridging The Gap, funded by the Erasmus Mundus External Cooperation Window Programme. Acknowledgements also to the University of Minho, for the provision of research facilities
Enumeration of States in a Periodic Glass
We present an analytic enumeration of the metastable states, , in a
periodic long-range Josephson array frustrated by a transverse field. We find
that the configurational entropy, , is extensive and
scales with frustration, confirming that the non-random system is glassy. We
also find that is different from that of its disordered analogue,
despite that fact that the two models share the same dynamical equations
THE ROLE OF INTERDEPENDENCE IN THE MICRO-FOUNDATIONS OF ORGANIZATION DESIGN: TASK, GOAL, AND KNOWLEDGE INTERDEPENDENCE
Interdependence is a core concept in organization design, yet one that has remained consistently understudied. Current notions of interdependence remain rooted in seminal works, produced at a time when managers’ near-perfect understanding of the task at hand drove the organization design process. In this context, task interdependence was rightly assumed to be exogenously determined by characteristics of the work and the technology. We no longer live in that world, yet our view of interdependence has remained exceedingly task-centric and our treatment of interdependence overly deterministic. As organizations face increasingly unpredictable workstreams and workers co-design the organization alongside managers, our field requires a more comprehensive toolbox that incorporates aspects of agent-based interdependence. In this paper, we synthesize research in organization design, organizational behavior, and other related literatures to examine three types of interdependence that characterize organizations’ workflows: task, goal, and knowledge interdependence. We offer clear definitions for each construct, analyze how each arises endogenously in the design process, explore their interrelations, and pose questions to guide future research
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