Generation of internal stress and its effects

Internal stresses may be generated continually in many polycrystalline materials. Their existence is manifested by changes in crystal defect concentration and arrangement, by surface observations, by macroscopic shape changes and particularly by alteration of mechanical properties when external stresses are simultaneously imposed

The effects of dust evolution on disks in the mid-IR

In this paper, we couple together the dust evolution code two-pop-py with the thermochemical disk modelling code ProDiMo. We create a series of thermochemical disk models that simulate the evolution of dust over time from 0.018 Myr to 10 Myr, including the radial drift, growth, and settling of dust grains. We examine the effects of this dust evolution on the mid-infrared gas emission, focussing on the mid-infrared spectral lines of C2H2, CO2, HCN, NH3, OH, and H2O that are readily observable with Spitzer and the upcoming E-ELT and JWST. The addition of dust evolution acts to increase line fluxes by reducing the population of small dust grains. We find that the spectral lines of all species except C2H2 respond strongly to dust evolution, with line fluxes increasing by more than an order of magnitude across the model series as the density of small dust grains decreases over time. The C2H2 line fluxes are extremely low due to a lack of abundance in the infrared line-emitting regions, despite C2H2 being commonly detected with Spitzer, suggesting that warm chemistry in the inner disk may need further investigation. Finally, we find that the CO2 flux densities increase more rapidly than the other species as the dust disk evolves. This suggests that the flux ratios of CO2 to other species may be lower in disks with less-evolved dust populations.Comment: 13 pages, 9 figures, accepted in A&

Irreversibility in response to forces acting on graphene sheets

The amount of rippling in graphene sheets is related to the interactions with the substrate or with the suspending structure. Here, we report on an irreversibility in the response to forces that act on suspended graphene sheets. This may explain why one always observes a ripple structure on suspended graphene. We show that a compression-relaxation mechanism produces static ripples on graphene sheets and determine a peculiar temperature $T_c$, such that for $T<T_c$ the free-energy of the rippled graphene is smaller than that of roughened graphene. We also show that $T_c$ depends on the structural parameters and increases with increasing sample size.Comment: 4 pages, 4 Figure

Optical and dc transport properties of a strongly correlated charge density wave system: exact solution in the ordered phase of the spinless Falicov-Kimball model with dynamical mean-field theory

We derive the dynamical mean-field theory equations for transport in an ordered charge-density-wave phase on a bipartite lattice. The formalism is applied to the spinless Falicov-Kimball model on a hypercubic lattice at half filling. We determine the many-body density of states, the dc charge and heat conductivities, and the optical conductivity. Vertex corrections continue to vanish within the ordered phase, but the density of states and the transport coefficients show anomalous behavior due to the rapid development of thermally activated subgap states. We also examine the optical sum rule and sum rules for the first three moments of the Green's functions within the ordered phase and see that the total optical spectral weight in the ordered phase either decreases or increases depending on the strength of the interactions.Comment: 14 pages, 14 figures, submitted to Phys. Rev.

Total scattering descriptions of local and cooperative distortions in the oxide spinel (Mg,Cu)Cr2O4 with dilute Jahn-Teller ions

The normal spinel oxide MgCr2O4 is cubic at room temperature while the normal spinel CuCr2O4 is tetragonal as a consequence of the Jahn-Teller nature of Cu2+ on the tetrahedral sites. Despite different end-member structures, complete solid solutions of Mg_{1-x}Cu_xCr2O4 can be prepared that display a first-order structural transition with composition x = 0.43 at room temperature. Reverse Monte Carlo analysis of total neutron scattering on data acquired between 300 K and 15 K on samples with x = 0.10, 0.20, and 0.43 provides unbiased local and average structure descriptions of the samples, including an understanding of the transition from local Jahn-Teller distortions in the cubic phase to cooperative distortions that result in a tetragonal structure. Distributions of continuous symmetry measures help to understand and distinguish distorted and undistorted coordination around the tetrahedral site in the solid solutions. Magnetic exchange bias is observed in field-cooled hysteresis loops of samples with dilute Cu2+ concentration and in samples with tetragonal--cubic phase coexistence around 300 K.Comment: 10 pages, 14 figure

Isis: protecting children in online social networks

The aim of the Isis project is to develop an ethics-centred monitoring framework and tools for supporting law enforcement agencies in policing online social networks for the purpose of protecting children. The project is developing natural language analysis techniques to help identify child sex offenders from chat logs and monitoring mechanisms that can be noninvasively attached to file sharing systems for identifying the distributors of child abuse media. The ethical issues associated with such monitoring activities are studied through consultations with representatives from stakeholder communities and fed back into the development of the framework and tools. The project results are to be used and evaluated by specialist international law enforcement agencies as part of their own policing activities

Thermodynamics of Finite Quantum Systems: Application to Spin Magnetism II

We extend our study of thermodynamics of a Kubo particle to temperatures smaller than the interlevel spacing. We obtain the distribution functions of spin susceptibility and heat capacity for Poisson and Wigner-Dyson level statistics. We evaluate the line shape of the Knight shift due to spin effects both in a single particle and for the ensemble average and compare it with orbital and spin-orbit contributions.Comment: 20 pages (16 text, 4 figures) uu-encoded, z-compressed PostScript. Latest versions of manuscripts available at http://physuna.phs.uc.edu/professors/serota.html or by e-mail, by request from [email protected]