Quasi-Langmuir-Blodgett Thin Film Deposition of Carbon Nanotubes

The handling and manipulation of carbon nanotubes continues to be a challenge to those interested in the application potential of these promising materials. To this end, we have developed a method to deposit pure nanotube films over large flat areas on substrates of arbitrary composition. The method bears some resemblance to the Langmuir-Blodgett deposition method used to lay down thin organic layers. We show that this redeposition technique causes no major changes in the films' microstructure and that they retain the electronic properties of as-deposited film laid down on an alumina membrane.Comment: 3 pages, 3 figures, submitted Journal of Applied Physic

Observation of correlations up to the micrometer scale in sliding charge-density waves

High-resolution coherent x-ray diffraction experiment has been performed on the charge density wave (CDW) system K$_{0.3}$MoO$_3$. The $2k_F$ satellite reflection associated with the CDW has been measured with respect to external dc currents. In the sliding regime, the $2k_F$ satellite reflection displays secondary satellites along the chain axis which corresponds to correlations up to the micrometer scale. This super long range order is 1500 times larger than the CDW period itself. This new type of electronic correlation seems inherent to the collective dynamics of electrons in charge density wave systems. Several scenarios are discussed.Comment: 4 pages, 3 figures Typos added, references remove

Landau quantization effects in the charge-density-wave system (Per)2M_2M(mnt)2_2 (where M=M=Au and Pt)

A finite transfer integral $t_a$ orthogonal to the conducting chains of a highly one-dimensional metal gives rise to empty and filled bands that simulate an indirect-gap semiconductor upon formation of a commensurate charge-density-wave (CDW). In contrast to semiconductors such as Ge and Si with bandgaps $\sim 1$ eV, the CDW system possesses an indirect gap with a greatly reduced energy scale, enabling moderate laboratory magnetic fields to have a major effect. The consequent variation of the thermodynamic gap with magnetic field due to Zeeman splitting and Landau quantization enables the electronic bandstructure parameters (transfer integrals, Fermi velocity) to be determined accurately. These parameters reveal the orbital quantization limit to be reached at $\sim 20$ T in (Per)$_2M$(mnt)$_2$ salts, making them highly unlikely candidates for a recently-proposed cascade of field-induced charge-density wave states

Character of electron reflection at a normal metal-Peierls semiconductor boundary

The reflection of electrons incident from a normal metal on the boundary of the metal with a quasi-one-dimensional conductor containing a charge-density wave (CDW) is investigated theoretically. It is shown that the reflection is not of an Andreev character, as it was suggested earlier, but rather of a Bragg character. This is due to the fact that the CDW is actually an electronic crystal, and its wave vector is a reciprocal lattice vector of the electronic crystal. The ratio of the intensities of the standard and Bragg reflection depends on the phase of the CDW.Comment: 9 pages, no figures, revte

Wick's Theorem and a New Perturbation Theory Around the Atomic Limit of Strongly Correlated Electron Systems

A new type of perturbation expansion in the mixing $V$ of localized orbitals with a conduction-electron band in the $U\to\infty$ Anderson model is presented. It is built on Feynman diagrams obeying standard rules. The local correlations of the unperturbed system (the atomic limit) are included exactly, no auxiliary particles are introduced. As a test, an infinite-order ladder-type resummation is analytically treated in the Kondo regime, recovering the correct energy scale. An extension to the Anderson-lattice model is obtained via an effective-site approximation through a cumulant expansion in $V$ on the lattice. Relation to treatments in infinite spatial dimensions are indicated.Comment: selfextracting postscript file containing entire paper (10 pages) including 3 figures, in case of trouble contact author for LaTeX-source or hard copies (prep0994

Theoretical Study of Friction: A Case of One-Dimensional Clean Surfaces

A new method has been proposed to evaluate the frictional force in the stationary state. This method is applied to the 1-dimensional model of clean surfaces. The kinetic frictional force is seen to depend on velocity in general, but the dependence becomes weaker as the maximum static frictional force increases and in the limiting case the kinetic friction gets only weakly dependent on velocity as described by one of the laws of friction. It is also shown that there is a phase transition between state with vanishing maximum static frictional force and that with finite one. The role of randomness at the interface and the relation to the impurity pinning of the sliding Charge-Density-Wave are discussed. to appear in Phys.Rev.B. abstract only. Full text is available upon request. E-mail: [email protected]: 2 pages, Plain TEX, OUCMT-94-

Evidence of Spatially Inhomogeous Pairing on the Insulating Side of a Disorder-Tuned Superconductor-Insulator Transition

Measurements of transport properties of amorphous insulating indium oxide thin films have been interpreted as evidence of the presence of superconducting islands on the insulating side of a disorder-tuned superconductor-insulator transition. Although the films are not granular, the behavior is similar to that observed in granular films. The results support theoretical models in which the destruction of superconductivity by disorder produces spatially inhomogenous pairing with a spectral gap.Comment: Revised title and content/argument. Totals: 4 pages, 3 figure

SERS analysis of Ag nanostructures produced by ion-beam deposition

This study deals with the development of a novel technique for formation of advanced Ag nanostructures (NSs) to be applied to high-resolution analyses based on surface enhanced Raman scattering (SERS). It has direct bearing on human health and food quality, e.g., monitoring small amount or traces of pollutants or undesirable additives. Three types of nanostructured Ag samples were produced using ion-beam deposition at glancing angle (GLAD) on quartz. All fabricated structures were covered with BI-58 pesticide (dimethoate) or Rhodamine 6G (R6G) for testing their potential for use as substrates for (SERS)

Electrodynamics of a Coulomb Glass in n-type Silicon

Optical measurements of the real and imaginary frequency dependent conductivity of uncompensated n-type silicon are reported. The experiments are done in the quantum limit, $\hbar\omega > k_{B}T$, across a broad doping range on the insulating side of the Metal-Insulator transition (MIT). The observed low energy linear frequency dependence shows characteristics consistent with theories of a Coulomb glass, but discrepancies exist in the relative magnitudes of the real and imaginary components. At higher energies we observe a crossover to a quadratic frequency dependence that is sharper than expected over the entire dopant range. The concentration dependence gives evidence that the Coulomb interaction energy is the relevant energy scale that determines this crossover.Comment: 5 pages, 4 figures; accepted for publication in Phys. Rev. Let