Photoluminescence Quantum Yield and Matrix-Induced Luminescence Enhancement of Colloidal Quantum Dots Embedded in Ionic Crystals

The incorporation of colloidal quantum dots (QDs) into solid matrices, especially ionic salts, holds several advantages for industrial applications. Here, we demonstrated via absolute measurements of photoluminescence quantum yields (PL-QY) that the photoluminescence of aqueous CdTe QDs can be considerably increased upon incorporation into a salt matrix with a simple crystallization procedure. Enhancement factors of up to 2.8 and a PL-QY of 50 to 80%, both in NaCl crystals and incorporated in silicone matrices, were reached. The fact that the achievable PL enhancement factors depend strongly on PL-QY of the parent QDs can be described by the change of the dielectric surrounding and the passivation of the QD surface, modifying radiative and nonradiative rate constants. Time-resolved PL measurements revealed noncorrelating PL lifetimes and PL-QY, suggesting that weakly emissive QDs of the ensemble are more affected by the enhancement mechanism, thereby influencing PL-QY and PL lifetime in a different manner

Implementation of High-Quality Warm-White Light-Emitting Diodes by a Model-Experimental Feedback Approach Using Quantum Dot–Salt Mixed Crystals

In this work, a model-experimental feedback approach is developed and applied to fabricate high-quality, warm-white light-emitting diodes based on quantum dots (QDs) as color-conversion materials. Owing to their unique chemical and physical properties, QDs offer huge potential for lighting applications. Nevertheless, both emission stability and processability of the QDs are limited upon usage from solution. Incorporating them into a solid ionic matrix overcomes both of these drawbacks, while preserving the initial optical properties. Here borax (Na₂B₄O₇·10H₂O) is used as a host matrix because of its lower solubility and thereby reduced ionic strength in water in comparison with NaCl. This guarantees the stability of high-quality CdSe/ZnS QDs in the aqueous phase during crystallization and results in a 3.4 times higher loading amount of QDs within the borax crystals compared to NaCl. All steps from the synthesis via mixed crystal preparation to the warm-white LED preparation are verified by applying the model-experimental feedback, in which experimental data and numerical results provide feedback to each other recursively. These measures are taken to ensure a high luminous efficacy of optical radiation (LER) and a high color rendering index (CRI) of the final device as well as a correlated color temperature (CCT) comparable to an incandescent bulb. By doing so, a warm-white LED with a LER of 341 lm/W_opt, a CCT of 2720 K and a CRI of 91.1 is produced. Finally, we show that the emission stability of the QDs within the borax crystals on LEDs driven at high currents is significantly improved. These findings indicate that the proposed warm-white light-emitting diodes based on QDs-in-borax hold great promise for quality lighting

Amplitude and frequency variability of the pulsating DB white dwarf stars KUV 05134+2605 and PG 1654+160 observed with the Whole Earth Telescope

We have acquired new time series photometry of the two pulsating DB white dwarf stars KUV 05134+2605 and PG 1654+160 with the Whole Earth Telescope. Additional single-site photometry is also presented. We use all these data plus all available archival measurements to study the temporal behaviour of the pulsational amplitudes and frequencies of these stars for the first time. We demonstrate that both KUV 05134+2605 and PG 1654+160 pulsate in many modes, the amplitudes of which are variable in time; some frequency variability of PG 1654+160 is also indicated. Beating of multiple pulsation modes cannot explain our observations; the amplitude variability must therefore be intrinsic. We cannot find stable modes to be used for determinations of the evolutionary period changes of the stars. Some of the modes of PG 1654+160 appear at the same periods whenever detected. The mean spacing of these periods (≈40 s) suggests that they are probably caused by non-radial gravity-mode pulsations of spherical degree l = 1. If so, PG 1654+160 has a mass around 0.6Mʘ. The time-scales of the amplitude variability of both stars (down to two weeks) are consistent with theoretical predictions of resonant mode coupling, a conclusion which might however be affected by the temporal distribution of our data

The interaction of morphology and syntax in affix order

In this article, I propose a constraint-based account of ordering restrictions on subject agreement affixes. Different orderings of subject agreement, crosslin-guistically and in single languages, are captured by different rankings of uni-versal well-formedness constraints in the sense of Optimality Theory (OT