33 research outputs found
Effect of impurities on pentacene island nucleation
Pentacenequinone (PnQ) impurities have been introduced into a pentacene
source material in a controlled manner to quantify the relative effects of the
impurity content on grain boundary structure and thin film nucleation. Atomic
force microscopy (AFM) has been employed to directly characterize films grown
using 0.0-7.5% PnQ by weight in the source material. Analysis of the
distribution of capture zones areas of submonolayer islands as a function of
impurity content shows that for large PnQ content the critical nucleus size for
forming a Pn island is smaller than for low PnQ content. This result indicates
a favorable energy for formation of Pn-PnQ complexes, which in turn suggests
that the primary effect of PnQ on Pn mobility may arise from homogeneous
distribution of PnQ defects.Comment: 16 Pages, 5 figures, 1 Tabl
Effect of Impurities on Pentacene Thin Film Growth for Field-Effect Transistors
Pentacenequinone (PnQ) impurities have been introduced into a pentacene
source material at number densities from 0.001 to 0.474 to quantify the
relative effects of impurity content and grain boundary structure on transport
in pentacene thin-film transistors. Atomic force microscopy (AFM) and
electrical measurements of top-contact pentacene thin-film transistors have
been employed to directly correlate initial structure and final film
structures, with the device mobility as a function of added impurity content.
The results reveal a factor four decrease in mobility without significant
changes in film morphology for source PnQ number fractions below ~0.008. For
these low concentrations, the impurity thus directly influences transport,
either as homogeneously distributed defects or by concentration at the
otherwise-unchanged grain boundaries. For larger impurity concentrations, the
continuing strong decrease in mobility is correlated with decreasing grain
size, indicating an impurity-induced increase in the nucleation of grains
during early stages of film growth.Comment: 18 pages, 4 Figures, 1 Tabl
Chiral molecular tapes from novel tetra(thiafulvalene-crown-ether)-substituted phthalocyanine building blocks
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Immobilization of Zinc Porphyrin Complexes on Pyridine-Functionalized Glass Surfaces
To immobilize sublimable and fluorescent dye mols. on transparent surfaces for the detection of far field mol. interference expts., the authors study the potential of pyridine-functionalized glass substrates as coordination sites for the zinc complex of tetraphenylporphyrin (ZnTPP). Borosilicate glass is functionalized with 4-(6-(ethoxydimethylsilyl)hexyloxy)pyridine to cover the glass surface with pyridine subunits. ZnTPP mols. are deposited by sublimation through mech. masks of various sizes in a high-vacuum chamber. The resulting micropatterns are analyzed using epifluorescence microscopy which also allows one to define a measure for the quality of mol. immobilization. The authors observe a reduced mobility and an increased efficiency for the trapping of ZnTPP on pyridine-functionalized surfaces. [on SciFinder(R)
Chiral semiconductor phases : the optically pure D3[MIII(S,S-EDDS)]2(D = TTF, TSF) family
A new family of optically pure tetrathiafulvalenium and tetraselenafulvalenium salts, D3[MIII(S,S-EDDS)]2·nH2O (where D = TTF, TSF; M = Co, Fe, Cr; EDDS = ethylenediaminedisuccinato), were synthesized electrochemically. These phases are semiconductors with conductivities between 6.9 Ă 10â6 and 1.3 Ă 10â5 S·cmâ1 (Eaca. 0.3 eV) for TTF and 2.8 Ă 10â4 to 2.8 Ă 10â5 S·cmâ1 (Eaca. 0.1 eV) for TSF compounds. While some crystals suffer from twinning, other well resolved structures consist of TTF/TSF stacks which, under the influence of the chiral anion, exhibit a periodic undulation described by an elliptical helix. The crystallographic data, along with computational work, indicate charge localization in the semiconducting motifs