High-mass star formation across the Large Magellanic Cloud I. Chemical properties and hot molecular cores observed with ALMA at 1.2 mm

To study the impact of the initial effects of metallicity (i.e., the abundance of elements heavier than helium) on star formation and the formation of different molecular species, we searched for hot molecular cores in the sub-solar metallicity environment of the Large Magellanic Cloud (LMC). We conducted an ALMA Band 6 observations of 20 fields centered on young stellar objects (YSOs) distributed over the LMC in order to search for hot molecular cores in this galaxy. We detected a total of 65 compact 1.2 mm continuum cores in the 20 ALMA fields and analyzed their spectra with XCLASS software. The main temperature tracers are CH3OH and SO2, with more than two transitions detected in the observed frequency ranges. Other molecular lines with high detection rates in our sample are CS , SO, H13CO+, H13CN, HC15 N, and SiO. More complex molecules, such as HNCO, HDCO, HC3N, CH3CN, and NH2CHO, and multiple transitions of SO and SO2 isotopologues showed tentative or definite detection toward a small subset of the cores. According to the chemical richness of the cores and high temperatures from the XCLASS fitting, we report the detection of four hot cores and one hot core candidate. With one new hot core detection in this study, the number of detected hot cores in the LMC increases to seven. Six out of seven hot cores detected in the LMC to date are located in the stellar bar region of this galaxy. These six hot cores show emission from complex organic molecules (COMs), such as CH3OH, CH3CN, CH3OCHO, and CH3OCH3. The only known hot core in the LMC with no detection of COMs is located outside the bar region. The metallicity in the LMC presents a shallow gradient increasing from outer regions toward the bar. We suggest that the formation of hot molecular cores containing COMs ensues from the new generation of stars forming in the more metal-rich environment of the LMC bar

Complex Organic Molecules in Star-Forming Regions of the Magellanic Clouds

The Large and Small Magellanic Clouds (LMC and SMC), gas-rich dwarf companions of the Milky Way, are the nearest laboratories for detailed studies on the formation and survival of complex organic molecules (COMs) under metal-poor conditions. To date, only methanol, methyl formate, and dimethyl ether have been detected in these galaxies-all three toward two hot cores in the N113 star-forming region in the LMC, the only extragalactic sources exhibiting complex hot-core chemistry. We describe a small and diverse sample of the LMC and SMC sources associated with COMs or hot-core chemistry, and compare the observations to theoretical model predictions. Theoretical models accounting for the physical conditions and metallicity of hot molecular cores in the Magellanic Clouds have been able to broadly account for the existing observations, but they fail to reproduce the dimethyl ether abundance by more than an order of magnitude. We discuss future prospects for research in the field of complex chemistry in the low-metallicity environment. The detection of COMs in the Magellanic Clouds has important implications for astrobiology. The metallicity of the Magellanic Clouds is similar to that of galaxies in the earlier epochs of the universe; thus, the presence of COMs in the LMC and SMC indicates that a similar prebiotic chemistry leading to the emergence of life, as it happened on Earth, is possible in low-metallicity systems in the earlier universe

ALMA Observations of Molecular Complexity in the Large Magellanic Cloud: The N105 Star-Forming Region

The Large Magellanic Cloud (LMC) is the nearest laboratory for detailed studies on the formation and survival of complex organic molecules (COMs), including biologically important ones, in low-metallicity environments--typical for earlier cosmological epochs. We report the results of 1.2 mm continuum and molecular line observations of three fields in the star-forming region N105 with the Atacama Large Millimeter/submillimeter Array (ALMA). N105 lies at the western edge of the LMC bar with on-going star formation traced by H$_2$O, OH, and CH$_3$OH masers, ultracompact H II regions, and young stellar objects. Based on the spectral line modeling, we estimated rotational temperatures, column densities, and fractional molecular abundances for twelve 1.2 mm continuum sources. We identified sources with a range of chemical make-ups, including two bona fide hot cores and four hot core candidates. The CH$_3$OH emission is widespread and associated with all the continuum sources. COMs CH$_3$CN and CH$_3$OCH$_3$ are detected toward two hot cores in N105 together with smaller molecules typically found in Galactic hot cores (e.g., SO$_2$, SO, and HNCO) with the molecular abundances roughly scaling with metallicity. We report a tentative detection of the astrobiologically relevant formamide molecule (NH$_2$CHO) toward one of the hot cores; if confirmed, this would be the first detection of NH$_2$CHO in an extragalactic sub-solar metallicity environment. We suggest that metallicity inhomogeneities resulting from the tidal interactions between the LMC and the Small Magellanic Cloud (SMC) might have led to the observed large variations in COM abundances in LMC hot cores.Comment: 75 pages, 48 figures, 7 tables (including appendices); Accepted for publication in the Astrophysical Journa