Acquisition of acid vapor and aerosol concentration data for use in dry deposition studies in the South Coast Air Basin

An atmospheric monitoring network was operated throughout the South Coast Air Basin in the greater Los Angeles area during the year 1986. The primary objective of this study was to measure the spatial and temporal concentration distributions of atmospheric gas phase and particulate phase acids and bases in support of the California Air Resources Board's dry deposition research program. Gaseous pollutants measured include HNO_3, HCl, HF, HBr, formic acid, acetic acid and ammonia. The chemical composition of the airborne particulate matter complex was examined in three size ranges: fine particles (less than 2.2 μm aerodynamic diameter, AD), PM_(10) (less than 10 μm AD) and total particles (no size discrimination). Upwind of the air basin at San Nicolas Island, gas phase acids concentrations are very low: averaging 0.3 μg m^(-3) (0.1 ppb) for HNO_3, 0.8 μg m^(-3) for HCl, 0.13 μg m^(-3) for HF, and 2.6 μg m^(-3) for formic acid. Annual average HN03 concentrations ranged from 3.1 μg m^(-3) (1.2 ppb) near the Southern California coast to 6.9 μg m^(-3) (2.7 ppb) at an inland site in the San Gabriel Mountains. HCl concentrations within the South Coast Air Basin averaged from 0.8 μg m^(-3) to 1.8 μg m^(-3) during the year 1986. Long-term average HF concentrations within the air basin are very low, in the range from 0.14 to 0.22 μg m^(-3) between monitoring sites. Long-term average formic acid concentrations are lowest near the coastline (5.0 μg m^(-3) at Hawthorne), with the highest average concentrations (10.7 μg m^(-3)) observed inland at Upland. Ammonia concentrations at low elevation within the South Coast Air Basin average from 2.1 μg m^(-3) to 4.4 μg m^(-3) at all sites except Rubidoux. Rubidoux is located directly downwind of a large ammonia source created by dairy farming and other agricultural activities in the Chino area. Ammonia concentrations at Rubidoux average 30 μg m^(-3) during 1986, a factor of approximately 10 higher than elsewhere in the air basin. Annual average PM_(10) mass concentrations within the South Coast Air Basin ranged from 47.0 μg m^(-3) along the coast to 87.4 μg m^(-3) at Rubidoux, the farthest inland monitoring site. Five major aerosol components (carbonaceous material, NO_3^-, SO_4^-, NH_4^+ and soil-related material) accounted for greater than 80% of the annual average PM_(10) mass concentration at all on-land monitoring stations. A peak 24-h average PM_(10) mass concentration of 299 μg m^(-3) was observed at Rubidoux during 1986. That value is a factor of 2 higher than the federal 24-h average PM_(10) concentration standard, and a factor of 6 higher than the State of California PM_(10) standard. More than 40% of the PM_(10) aerosol mass measured at Rubidoux during that peak day event consisted of aerosol nitrates plus ammonium ion. Reaction of gaseous nitric acid to form aerosol nitrates was a major contributor to the high PM_(10) concentrations observed in the Rubidoux area near Riverside, California

A Coloring Problem for Sturmian and Episturmian Words

We consider the following open question in the spirit of Ramsey theory: Given an aperiodic infinite word $w$, does there exist a finite coloring of its factors such that no factorization of $w$ is monochromatic? We show that such a coloring always exists whenever $w$ is a Sturmian word or a standard episturmian word

Modeling the Concentrations of Gas-Phase Toxic Organic Air Pollutants: Direct Emissions and Atmospheric Formation

An Eulerian photochemical air quality model is described for the prediction of the atmospheric transport and chemical reactions of gas-phase toxic organic air pollutants. Model performance was examined in the Los Angeles, CA, area over the period August 27-28, 1987. The organic compounds were drawn from a list of 189 species selected for control as hazardous air pollutants in the Clean Air Act amendments of 1990. The species considered include benzene, various alkylbenzenes, phenol, cresols, 1,3- butadiene, acrolein, formaldehyde, acetaldehyde, and perchloroethylene among others. It is found that photochemical generation contributes significantly to form-aldehyde, acetaldehyde, acetone, and acrolein concentrations for the 2-day period studied. Phenol concentrations are dominated by direct emissions, despite the existence of a pathway for atmospheric formation from benzene oxidation. The finding that photochemical production can be a major contributor to the total concentrations of some toxic organic species implies that control programs for those species must consider more than just direct emissions

FMRI Clustering and False Positive Rates

Recently, Eklund et al. (2016) analyzed clustering methods in standard FMRI packages: AFNI (which we maintain), FSL, and SPM [1]. They claimed: 1) false positive rates (FPRs) in traditional approaches are greatly inflated, questioning the validity of "countless published fMRI studies"; 2) nonparametric methods produce valid, but slightly conservative, FPRs; 3) a common flawed assumption is that the spatial autocorrelation function (ACF) of FMRI noise is Gaussian-shaped; and 4) a 15-year-old bug in AFNI's 3dClustSim significantly contributed to producing "particularly high" FPRs compared to other software. We repeated simulations from [1] (Beijing-Zang data [2], see [3]), and comment on each point briefly.Comment: 3 pages, 1 figure. A Letter accepted in PNA

FDI in Space: Spatial Autoregressive Relationships in Foreign Direct Investment

Theoretical models of foreign direct investment (FDI) have only recently begun to model the role of third countries, and the empirical FDI literature has almost exclusively examined bilateral FDI data without recognizing the potential interdependence between FDI decisions to alternative host countries. This paper uses spatial econometric techniques to examine the spatial correlation between FDI to alternative (neighboring) regions. The sign of such correlations can provide evidence for or against alternative theories for FDI motivations. Using data on OECD countries from 1980-2000, we find evidence consistent with export platform FDI in Europe.

Models of planetary rings

The Voyager occultations provide several uniform and high quality data sets for Saturn, Uranus, and Neptune. These data are intercompared, and theoretical models for the particle sizes and the particle transport are developed. The major topics covered include: ring size distribution, torques and resonances, and satellite wakes

On Quasiperiodic Morphisms

Weakly and strongly quasiperiodic morphisms are tools introduced to study quasiperiodic words. Formally they map respectively at least one or any non-quasiperiodic word to a quasiperiodic word. Considering them both on finite and infinite words, we get four families of morphisms between which we study relations. We provide algorithms to decide whether a morphism is strongly quasiperiodic on finite words or on infinite words.Comment: 12 page

Rotational torque measurement device

A device for measuring torque applied through a rotating member. A first torsion reference member is fixedly coupled to the rotating member at a first axial position and a second torsion reference member is fixedly coupled to the rotating member at a second axial position. A first detector detects the passage of the first torsion reference member past the first detector upon each full rotation of the rotating member and to generate a first signal upon each passage of the first torsion reference member. A second detector detects the passage of the second torsion reference member past the second detector upon each full rotation of the rotating member and to generate a second signal upon each passage of the second torsion reference member. A controller calculates a phase difference between the first signal and the second signal relative during rotation of the rotating member under a torsional load.https://digitalcommons.mtu.edu/patents/1003/thumbnail.jp

Success of Wild-Trapped Compared to Captivity-Raised Birds in Restoring Wild Turkey Populations to Northwestern Arkansas

Reintroduction of wild turkeys into northwestern Arkansas was studied at 10 release sites in the late 1950\u27s. Native birds trapped in southern Arkansas were released at five study areas, and birds from wild Pennsylvania stock reared in captivity were released in five other areas. Although both types of turkeys reproduced, most populations of captivity-raised turkeys decreased sharply whereas all populations of wild-trapped birds exhibited marked increases. Range extension averaged nearly 2.5 miles per year in expanding wild-trapped populations. Captivity-raised birds were comparatively tame and often were found near human habitation. Current expanding turkey populations in the Arkansas Ozarks undoubtedly are due to the introductions of wild-trapped birds

Human GUCY2C-Targeted Chimeric Antigen Receptor (CAR)-Expressing T Cells Eliminate Colorectal Cancer Metastases.

One major hurdle to the success of adoptive T-cell therapy is the identification of antigens that permit effective targeting of tumors in the absence of toxicities to essential organs. Previous work has demonstrated that T cells engineered to express chimeric antigen receptors (CAR-T cells) targeting the murine homolog of the colorectal cancer antigen GUCY2C treat established colorectal cancer metastases, without toxicity to the normal GUCY2C-expressing intestinal epithelium, reflecting structural compartmentalization of endogenous GUCY2C to apical membranes comprising the intestinal lumen. Here, we examined the utility of a human-specific, GUCY2C-directed single-chain variable fragment as the basis for a CAR construct targeting human GUCY2C-expressing metastases. Human GUCY2C-targeted murine CAR-T cells promoted antigen-dependent T-cell activation quantified by activation marker upregulation, cytokine production, and killing of GUCY2C-expressing, but not GUCY2C-deficient, cancer cells in vitro. GUCY2C CAR-T cells provided long-term protection against lung metastases of murine colorectal cancer cells engineered to express human GUCY2C in a syngeneic mouse model. GUCY2C murine CAR-T cells recognized and killed human colorectal cancer cells endogenously expressing GUCY2C, providing durable survival in a human xenograft model in immunodeficient mice. Thus, we have identified a human GUCY2C-specific CAR-T cell therapy approach that may be developed for the treatment of GUCY2C-expressing metastatic colorectal cancer