thermal characterization methodology for dry finishing turning of saf 2507 stainless steel based on finite element simulations and surrogate models

Abstract This paper addresses the numerical thermal characterization of a 3D turning process of a SAF 2507 stainless steel. A thermographic test campaign was conducted to measure the temperature distribution at the tool-workpiece interface. The campaign was accommodated by means of a L18 fractional factorial design of experiment. The 3D turning process was simulated using the software TWS Advantedge. The heat transfer numerical coefficients were calibrated against experimental measures to obtain temperature values as accurate as possible. A statistical methodology frame work was adopted to study the dependence of the coefficients from the machining parameters. A heat transfer surrogate model was then built and next experimentally validated

IC.IDO as a tool for displaying machining processes. The logic interface between Computer-Aided-Manufacturing and Virtual Reality

Abstract This scientific communication investigates the logic interface of a CAM solver, i.e., MasterCAM, into a Virtual Reality (VR) environment. This integration helps in displaying machining operations in virtual reality. Currently, to partially visualize the results of a simulation in an immersive environment, an import/export procedure must be done manually. Here, a software plugin integrated into IC.IDO (by ESI Group) has been realized and fully described. This application allows the complete integration of CAM solver into the VR environment. In particular, the VERICUT solver has been integrated into VR. This kind of integration has never been done yet

Validation of TiAlN functional coatings through cryo-tribological characterization using a pin-on-disk experiment

Abstract The purpose of this study has been to investigate the effects of TiAlN functional coatings in cryo-tribological pin-on-disk experiments. Nowadays, the introduction of new machining technologies for chip removal, both at high speed and in cryogenic conditions, is posing new challenges and opening new horizons to research. As a matter of fact, that in this technology needs to focus on the choice of workpiece materials to be machining and tools coatings used. For the latter, the wear phenomenon has been studied employing pins-on-disk (made by nickel-based alloys) under a liquid nitrogen jet flows simulating cryogenic machining. The coatings used have been of two different types: the coating C1 is a ZrTiAlN quaternary, while the coating C2 is a TiAlN/ZrN. The films were deposited with processes developed by the ENEA Brindisi laboratory using a dual magnetron sputtering and HiPPMS physical deposition technique. The wear measures were acquired employing a full factorial design with two factors: i.e., the test conditions (DRY or CRYO) and the pin coatings (not coated NC, coating C1 or C2). The number of tests was 12 since 2 were the replications. Based on preliminary experimental results, it can be stated that there is a type of coating, i.e., TiAlN/ZrN, that allows for high processing speed, high material removal, and a considerable increase in tool life

Shape and Morphology Effects on the Electronic Structure of TiO2 Nanostructures: From Nanocrystals to Nanorods

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Charge recombination reduction in dye-sensitized solar cells by means of an electron beam-deposited TiO2 buffer layer between conductive glass and photoelectrode

A thin anatase titanium dioxide compact film was deposited by electron beam evaporation as buffer layer between the conductive transparent electrode and the porous TiO2-based photoelectrode in dye-sensitized solar cells. The effect of such a buffer layer on the back transfer reaction of electrons to tri-iodide ions in liquid electrolyte-based cells has been studied by means of both electrochemical impedance spectroscopy and open circuit photovoltage decay analysis. The influence of the thickness has been also investigated and an increment in overall quantum conversion efficiency eta as high as +31% with respect to the standard cell - fabricated onto an uncoated conductive glass - has been revealed in the case of a 120 nm thick buffer layer. (C) 2010 Elsevier B.V. All rights reserve

Technetium-99m sestamibi tomographic evaluation of residual ischemia after anterior myocardial infarction

Objectives.This study investigated the value of sestamibi scintigraphy in assessing residual ischemia after anterior myocardial infarction.Background.Serial imaging with sestamibi, the uptake and retention of which correlate with regional myocardial blood flow and viability, has been used to estimate salvaged myocardium and risk area after acute infarction. We recently documented that recovery of perfusion and contraction in the infarcted area may continue well after the subacute phase, suggesting myocardial hibernation. Some underestimation of viability in the setting of hibernating myocardium by sestamibi imaging has been reported.Methods.We studied 58 patients in stable condition after Q wave anterior infarction. Regional perfusion and function were quantitatively assessed by sestamibi tomography and two-dimensional echocardiography at 4 to 6 weeks and at 7 months after infarction. In sestamibi polar maps, abnormal areas with tracer uptake >2.5 SD below our reference values were computed at rest and after symptom-limited exercise. On two-dimensional echocardiography the ejection fraction and extent of rest wall motion abnormalities were assessed by a computerized system. All patients had coronary angiography between the two studies.Results.At 7 months the extent of rest sestamibi defect was significantly reduced in 40 patients (69%, group 1) and unchanged in 18 (31%, group 2). Rest wall motion abnormalities and ventricular ejection fraction significantly improved in group 1 but not in group 2. Underlying coronary disease, patency of the infarct-related vessel and rest sestamibi defect extent at 5 weeks were comparable between the two groups. At 7 months, an increase in the reversible (stress-rest defect) tracer defect was observed in group 1 (p < 0.05) despite a smaller stress-induced hypoperfusion (p < 0.05). Reversible sestamibi defects and stress hypoperfusion were unchanged in group 2. In 38 (95%) of 40 group 1 patients, the area showing reversible sestamibi defects at 7 months matched the area showing fixed hypoperfusion at 5 weeks.Conclusions.The reduction in the rest tracer uptake defect that can occur late after infarction may affect the assessment of ischemic burden by sestamibi imaging early after anterior myocardial infarction

Novel Preparation Method of TiO2-Nanorod-Based Photoelectrodes for Dye-Sensitized Solar Cells with Improved Light-Harvesting Efficiency

We present a novel, facile, and cost-effective method to prepare highly transparent mesoporous films made by anatase TiO2 nanorods that have been synthesized by a single-step solvothermal process. Such nanorods have been conveniently used as prepared-without completely removing the residual organics-to obtain suitable screen-printable paste by means of the use of proper polymeric binders. This method has been successfully implemented to fabricate highly efficient nanorod-based photoelectrodes for dye-sensitized solar cells. They showed an increment of the overall quantum conversion efficiency comprised between 34% and 58% with respect to cells based oil commercial P25 titanium dioxide nanoparticles. In particular, a maximum photocurrent density and solar conversion efficiency of 16.9 mA/cm(2) and 7.9% have been obtained, respectively

Hematite as an Electrocatalytic Marker for the Study of Archaeological Ceramic Clay bodies: A VIMP and SECM Study**

[EN] The electrocatalytic effect exerted by hematite, a ubiquitous component of clay bodies, on the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) can be used to acquire information on archaeological ceramics. The solid-state voltammetric response of different hematite and ochre specimens, accompanied by SECM analysis in contact with 0.10 M HCl aqueous solution, is described. In air-saturated solutions, catalytic effects on the ORR and OER are accompanied by Fe(III)/Fe(II) and Fe(IV)/Fe(III) redox reactions. Such processes are conditioned by a variety of factors, the hydroxylation degree of the mineral surfaces being particularly influential, and exhibit significant variations upon heating the specimens between 300 and 900 degrees C. Voltammetric measurements carried out on a set of archaeological samples of Apulian red-figured pottery dated back within 5(th) and 4(th) centuries BCE permit to obtain site-characteristic voltammetric profiles.The work was carried out within the framework of project PID2020-113022GB-I00 which was financially support by Ministerio de Ciencia e Innovacion and Agencia Estatal de Investigacion (AEI) of the Spanish government.Doménech-Carbó, A.; Giannuzzi, M.; Mangone, A.; Giannossa, LC.; Di Turo, F.; Cofini, E.; Domenech Carbo, MT. (2022). Hematite as an Electrocatalytic Marker for the Study of Archaeological Ceramic Clay bodies: A VIMP and SECM Study**. ChemElectroChem. 9(2):59-68. https://doi.org/10.1002/celc.20210119759689

Enhancing Dye-Sensitized Solar Cell Performances by Molecular Engineering: Highly Efficient π-Extended Organic Sensitizers

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A Novel Modeling for Assessing Frequency Behavior During a Hydro-to-Thermal Plant Black Start Restoration Test

Northern electric grid of Italy was involved in a black start mock drill. This test took place on November 2016 in order to check the coordination and efficiency of all the operational staffs and the automatic regulators involved in the case of a real blackout scenario. This paper presents the results of a research carried out in collaboration with Terna Rete Italia (the Italian Transmission System Operator), in order to find strengths and weaknesses and eventually to upgrade the existing restoration plan. Starting from the measures coming from generating plants and substations bars, the model of frequency regulation system for both the participating hydro and thermal power plants is developed. This work gives the system operator an essential tool to understand many complex dynamics and phenomena occurred during the test. At the same time, a robust model simulating the system behavior with different grid configurations is presented: it gives the opportunity to enhance both the classical power system control theory and the black start practices