Nanotechnology Solutions for Global Water Challenges

The lack of clean and safe drinking water is responsible for more deaths than war, terrorism and weapons of mass destruction combined. This suggests contaminated water poses a significant threat to human health and welfare. In addition, standard water disinfection approaches such as sedimentation, filtration, and chemical or biological degradation are not fully capable of destroying emerging contaminants (e.g. pesticides, pharmaceutical waste products) or certain types of bacteria (e.g. Cryptosporidium parvum). Nanomaterials and nanotechnology based devices can potentially be employed to solve the challenges posed by various contaminants and microorganisms. Nanomaterials of different shapes, namely nanoparticles, nanotubes, nanowires and fibers have the ability to function as adsorbents and catalysts. These possess an expansive array of physicochemical characteristics deeming them highly attractive for the production of reactive media for water membrane filtration, a vital step in the production of potable water. As a result of their exceptional adsorptive capacity for water contaminants, graphene based nanomaterials have emerged as an area of significant importance in the area of membrane filtration and water treatment. In addition, Advanced Oxidation Processes (AOPs) together with or without sources of light irradiation or ultrasound, have been found to be promising alternatives for water treatment at near ambient temperature and pressure. Furthermore, the uses of visible light active titanium dioxide photocatalysts and photo-Fenton processes have shown significant potential for water purification. A wide variety of nanomaterial based sensors, for the monitoring of water quality, have also been reviewed in detail. In conclusion, the rapid and continued growth in the area of nanomaterial based devices offers significant hope for addressing future water quality challenges

A Study of the Degradation of LEV by Transparent PVA/NCD-TiO2 Nanocomposite Films with Enhanced Visible-Light Photocatalytic Activity

In recent years, antibiotics (such as levofloxacin (LEV)) have been detected widely in the environment. Semiconductor photocatalysis has been recognized as a promising technology for removing pollutants in the environment. In this work, nitrogen and carbon codoped titanium dioxide nano-catalyst (NCD-TiO2) was immobilized in polyvinyl alcohol (PVA) matrix to form PVA/NCD-TiO2 films through solution casting and thermal treatment, which exhibited good photocatalytic efficiency for LEV degradation. The results showed that about 42% LEV can be degraded after 2 h in the presence of PVA/NCD-TiO2 nanocomposite film (the weight ratio of NCD-TiO2 to PVA is 8% and thermal treatment is 120 °C) under visible light. Moreover, possible pathways of photocatalytic degradation of LEV according to the detected intermediates are proposed, which provide insight into the degradation mechanism of LEV by using PVA/NCD-TiO2 photocatalytic films. Finally, the synthesized PVA/NCD-TiO2 films exhibited excellent reusability and stability in photocatalysis. This work provides fundamental support for the design of a high-stability, excellent photocatalyst for practical application

A Study of the Degradation of LEV by Transparent PVA/NCD-TiO₂ Nanocomposite Films with Enhanced Visible-Light Photocatalytic Activity

In recent years, antibiotics (such as levofloxacin (LEV)) have been detected widely in the environment. Semiconductor photocatalysis has been recognized as a promising technology for removing pollutants in the environment. In this work, nitrogen and carbon codoped titanium dioxide nano-catalyst (NCD-TiO2) was immobilized in polyvinyl alcohol (PVA) matrix to form PVA/NCD-TiO2 films through solution casting and thermal treatment, which exhibited good photocatalytic efficiency for LEV degradation. The results showed that about 42% LEV can be degraded after 2 h in the presence of PVA/NCD-TiO2 nanocomposite film (the weight ratio of NCD-TiO2 to PVA is 8% and thermal treatment is 120 °C) under visible light. Moreover, possible pathways of photocatalytic degradation of LEV according to the detected intermediates are proposed, which provide insight into the degradation mechanism of LEV by using PVA/NCD-TiO2 photocatalytic films. Finally, the synthesized PVA/NCD-TiO2 films exhibited excellent reusability and stability in photocatalysis. This work provides fundamental support for the design of a high-stability, excellent photocatalyst for practical application

Mechanism of One-Step Hydrothermally Synthesized Titanate Catalysts for Ozonation

A titanate nanotube catalyst for ozonation was synthesized with a simple one-step NaOH hydrothermal treatment without energy-consuming calcination. The synthesized titania catalysts were characterized by X-ray diffraction (XRD), Raman, porosimetry analysis, high-resolution transmission electron microscopy (HR-TEM), Fourier transformed infrared (FTIR), and electron paramagnetic resonance (EPR) analysis. The catalyst treated with a higher concentration of NaOH was found to be more catalytically active for phenol removal due to its higher titanate content that would facilitate more OH groups on its surface. Furthermore, the main active oxidizing species of the catalytic ozonation process were recognized as singlet oxygen and superoxide radical, while the hydroxyl radical may only play a minor role. This work provides further support for the correlation between the properties of titania and catalytic performance, which is significant for understanding the mechanism of catalytic ozonation with titania-based materials

Degradation Mechanism of Cyanobacterial Toxin Cylindrospermopsin by Hydroxyl Radicals in Homogeneous UV/H₂O₂ Process

The degradation of cylindrospermopsin (CYN), a widely distributed and highly toxic cyanobacterial toxin (cyanotoxin), remains poorly elucidated. In this study, the mechanism of CYN destruction by UV-254 nm/H₂O₂ advanced oxidation process (AOP) was investigated by mass spectrometry. Various byproducts identified indicated three common reaction pathways: hydroxyl addition (+16 Da), alcoholic oxidation or dehydrogenation (−2 Da), and elimination of sulfate (−80 Da). The initiation of the degradation was observed at the hydroxymethyl uracil and tricyclic guanidine groups; uracil moiety cleavage/fragmentation and further ring-opening of the alkaloid were also noted at an extended reaction time or higher UV fluence. The degradation rates of CYN decreased and less byproducts (species) were detected using natural water matrices; however, CYN was effectively eliminated under extended UV irradiation. This study demonstrates the efficiency of CYN degradation and provides a better understanding of the mechanism of CYN degradation by hydroxyl radical, a reactive oxygen species that can be generated by most AOPs and is present in natural water environment

Photocatalytic degradation of organic contaminants in water: Process optimization and degradation pathways

This chapter discusses thoroughly the outcomes of the TiO2 photocatalytic degradation of organic contaminants of emerging concern, including manmade (insecticides, organochlorinated compounds, and antibiotics) and naturally occurring compounds (cyanotoxins and taste and odor compounds). Specifically, information is provided on the degradation of various organic contaminants in actual water samples, their corresponding reaction kinetics, the individual effects of water quality parameters (including pH, natural organic matter, and alkalinity) and nano-interfacial adsorption phenomena. Emphasis is given to the mechanisms of photocatalytic degradation of organic contaminants based on their structural differences and the corresponding transformation products formed