17 research outputs found
Acyl Sonogashira Cross-Coupling: State of the Art and Application to the Synthesis of Heterocyclic Compounds
Dreikomponenten‐Kupplungs‐(3+3)‐Anellierung zum Aufbau von blaufluoreszierenden, wasserlöslichen, tricyclischen 2‐Aminopyridinsalzen
Synthesis of Water‐Soluble Blue‐Emissive Tricyclic 2‐Aminopyridinium Salts by Three‐Component Coupling‐(3+3)‐Anellation
Highly Convergent Synthesis of Intensively Blue Emissive Furo[2,3-c]isoquinolines by a Palladium-catalyzed Cyclization Cascade of Unsaturated Ugi Products
reserved5siA convergent and diversity-oriented approach to the unusual furo[2,3-c]isoquinoline scaffold is presented. This serendipity-driven approach is characterized by an Ugi multicomponent reaction, which gives the substrate for a palladium-catalyzed insertion-alkynylation-cycloisomerization cascade to provide the furo[2,3-c]isoquinolines in moderate to high yield. Upon UV excitation, all representatives are intensively blue luminescent, as observed by the naked eye, and quantitative fluorescence spectroscopy reveals a considerable effect of the substitution pattern on the quantum yields. The electronic structure is semiquantitatively rationalized by DFT and time-dependent DFT calculations.mixedMoni, L.; Gers-Panther, C.; Anselmo, M.; Müller, T. J. J.; Riva, R.Moni, Lisa; Gers Panther, C.; Anselmo, Manuel; Müller, T. J. J.; Riva, Renat
New 2,3-Bis(5-arylthiophen-2-yl)quinoxaline Derivatives: Synthesis and Photophysical Properties
Heck Reactions of Acrolein or Enones and Aryl Bromides – Synthesis of 3‐Aryl Propenals or Propenones and Consecutive Application in Multicomponent Pyrazole Syntheses
Crystallization and Aggregation-Induced Emission in a Series of Pyrrolidinylvinylquinoxaline Derivatives
Four- and Five-Component Syntheses and Photophysical Properties of Emission Solvatochromic 3‑Aminovinylquinoxalines
3-Aminovinylquinoxalines
are readily accessible from (hetero)aryl
glyoxylic acids or heterocyclic π-nucleophiles by consecutive
four- and five-component syntheses in the sense of an activation-alkynylation-cyclocondensation-addition
sequence or glyoxylation-alkynylation-cyclocondensation-addition sequence
in good yields. The title compounds are highly fluorescent with pronounced
emission solvatochromicity and protochromic fluorescence quenching.
Time-resolved fluorescence spectroscopy furnishes radiative and nonradiative
fluorescence decay rates in various solvent polarities. The electronic
structure is corroborated by DFT and TD-DFT calculations rationalizing
the observed spectroscopic effects