Analysis of different polypropylene waste bales: evaluation of the source material for PP recycling

The use of the polypropylene (PP) recyclates in certain processing methods and applications is still limited by their quality. The high melt flow rate (MFR) and the inconsistent properties of recyclates are common obstacles to their use. Therefore, this work aims to identify possible reasons for the low and inconsistent quality of PP recyclates depending on the source material in PP waste bales. The levels of polymeric and non-polymeric contaminants were assessed. As mixing of different PP grades is an issue for the MFR, the proportions of the different processing grades were also investigated and the potential of sorting by processing method to produce lower MFR recyclates was assessed. The analysis showed that the waste bales, although pre-sorted, still contained high amounts of contaminants. Injection moulding was found to be the predominant processing method in the bales, explaining the high MFR of PP recyclates. However, a sufficiently high amount of low MFR products was found in the bales, which seems promising for the production of low MFR recyclates. Seasonal variations in the composition of the waste bales were identified as one of the reasons for the inconsistent qualities of recyclates. These results highlight the importance of proper sorting and treatment of PP waste bales prior to reprocessing in order to obtain high-quality recycled products

CHARACTERIZATION OF THE DAMPING BEHAVIOR OF THIN FILMS WITH DYNAMIC MECHANIC ANALYSIS IN BENDING MODE

ABSTRACT Usually damped structures, consisting of a constrained layer damping (CLD) and free layer damping (FLD) design, are characterized via dynamic mechanic analysis (DMA) in bending mode. Since laminates with thicknesses from 10 to 100 µm exhibit a very low bending stiffness it isn't possible to determine their damping properties in bending mode with standard DMA setups. Therefore in the present work the main objective was to introduce a new method to overcome this drawback. Two main geometries were used, such as a variation of the bending mode where the laminates were clamped at the outer supports and on the other hand a set-up where the geometry of a support of loudspeakers was replicated, which was called "speaker" mode. The damping behavior of the laminates then was characterized via the mechanical loss factor tan δ and subsequently compared to results in DMA shear mode. The second objective was to characterize the influence of the design, with a 2-layer laminate consisting of a free layer damping design and a 3-layer laminate with a constrained layer damping design. A method in DMA "speaker" mode was successfully set up. The test parameters were chosen in order to resemble the support of loudspeakers. Therefore with the laminates two beads with a height of approximately 1 mm were formed symmetrically in gaps of 3 mm between the outer fixtures and the drive shaft. Furthermore in the test the laminates were loaded with a dynamic displacement of 600 µm. Due to the low bending stiffness of the laminates the highest test frequency was limited to 10 Hz. In accordance with literature for the 2-layer laminates significant lower damping levels were found than for the 3-layer laminates. Whereas the constrained layer damping laminate (3-layer) showed a good correlation between measurements in "speaker" and in shear mode, the 2-layer laminate showed a significant loss factor increase at high temperatures in shear mode, which was related to entropy elastic effects. Keywords: constrained layer damping, dynamic mechanic analysis, thin laminates, mechanical damping, bending mode NOMENCLATURE CLD constrained layer damping. DMA dynamic mechanic analysis. FLD free layer damping. tan δ mechanical loss factor

Lifecycle assessment for recycling processes of monolayer and multilayer films: a comparison

This work covers a lifecycle assessment of monolayer and multilayer films to quantify the environmental impacts of changing the management of plastic film waste. This lifecycle assessment offers the possibility of quantifying the environmental impacts of processes along the lifecycle of monolayer and multilayer films and mapping deviating impacts due to changed process parameters. Based on the status quo, the changes in global warming potential and abiotic fossil resource depletion were calculated in different scenarios. The changes included collecting, sorting, and recycling mono- and multilayer films. The “Functional Unit” under consideration comprised 1000 kg of plastic film waste, generated as post-consumer waste in Austria and captured in the lightweight packaging collection system. The results showed the reduction of environmental impacts over product lifecycles by improving waste management and creating a circular economy. Recycling all plastic film reduced global warming potential by 90% and abiotic fossil resource consumption by 93%. The necessary optimisation steps to meet the politically required recycling rates by 2025 and 2030 could be estimated, and the caused environmental impacts are presented. This work shows the need for increased collection, recycling, and significant improvement in the sorting of films to minimise global warming potential and resource consumption

STABILITY OF BLACK INTERCONNECT COATINGS FOR SOLAR PHOTOVOL-TAIC MODULE APPLICATIONS

Aesthetics is crucial in the development of Building Integrated Photovoltaic (BIPV) products. Manufacturers strive to mask, typically through expensive manual processes, the reflective metallic interconnects to obtain uniform module colors. Inks offer an automated alternative but must be implemented in the production line and remain stable, maintaining their appearance over time. In this study, three black metallic ribbons were tested: one commercially pre-coated and two coated with UV-curable inkjet printing. Accelerated UV-light exposure was applied according to IEC standards on coupons mimicking glass/backsheet (G/Bs) samples including encapsulant with and without UV blockers. Additionally, one-cell modules with ink-coated ribbons were fabricated using a laboratory-designed automatic inkjet printer and exposed to accelerated UV ageing. Results showed that the commercially available coated ribbon remained stable after 120 kWh/m2 of UV exposure. However, UV-curable inkjet inks caused color changes in the encapsulant around metallic interconnects, regardless of the encapsulant used or the presence or not of UV blockers in the encapsulant. Ink #1 exhibited the most color change under UV-dose. Its main component, 2-phenoexyethyl-acrylate (2-PEA), photodegraded and caused yellowing. An early sign of degradation with a slight increase of 22% in carbonyl index (CI) was observed after 15 kWh/m2 of UV exposure. Encapsulants with UV blockers successfully mitigated 2-PEA photodegradation on G/BS laminates; however, color change occurred with ink #1 despite their application. Using this ink on PV modules results in color change, but the electrical performance remains relatively stable, with less than a 3% power loss after 360 kWh/m2 of UV exposure

Peeling of Flexible Laminates—Determination of Interlayer Adhesion of Backsheet Laminates Used for Photovoltaic Modules

Delamination is one of the most critical failure modes of a PV module during service lifetime. Delamination within a backsheet primarily imposes a safety risk, but may also accelerate various other PV module degradation modes. The main aim of this paper is to present a peel test set-up, which is more practical in sample preparation and execution than the width-tapered cantilever beam test and overcomes some issues of standard peel tests like the influence of sample geometry and energy dissipation through deformation on the peel test results. The best results with respect to accuracy and effort were achieved by using a 180° peel geometry where an additional adhesive tape is applied to the peel arm in order to avoid plastic deformation or breakage. The additional support of the adhesive tape leads to comparable peel strength values without any influence of the plastic deformation behavior of the peel arms with different thickness