Monte Carlo simulations for Ising spins with spin greater than 1/2 applied to the square and triangular lattices with antiferromagnetic interactions and comparing results using Kawasaki and Glauber dynamics

This paper has a pedagogical introduction. We describe the correct method for performing Monte Carlo simulations of Ising model systems with spin greater than one half. Correct and incorrect procedures are clearly outlined and the consequences of using the incorrect procedure are shown. The difference between Kawasaki and Glauber dynamics is then outlined and both methods are applied to the antiferromagnetic square and triangular lattices for S =1

Evaluation of Service-Quality Dimensions during Antenatal care in Primary Health Care Centers, Southern Kaduna Senatorial District, Nigeria

Shortage of qualified health care providers, weak health systems characterized by deficiencies of functioning equipment and essential medications, attitude of health workers as well as a range of physical, cultural, and financial barriers have been implicated for inaccessibility of quality care to many women. Poor acceptance of antenatal care is due to pervasive poverty, subordinate role of women, low literacy levels and the non-existent social systems in most developing countries. A cross-sectional, descriptive research design was used and a total of 296 respondents (pregnant women) who met the inclusion criteria participated in the study. A multistage sampling technique was used in selecting the required facilities and sample were selected in proportion with the inflow of clients in the facilities. Data were collected with the aid of questionnaires adapted from  Parasuraman etal (1988) and mean of 2.5 was used to ascertain satisfaction on the Likert scales. PHCs in southern Kaduna Senatorial district arevery accessible to the Clients (2.574±0.540) both financially and geographically as well as the opening hours of the clinics. The Clients have full confidence in the health care givers (2.977±0.483). Clients were satisfied with the level of empathy exhibited by the health care givers toward them during antenatal care (3.346±0.688) and that PHCs Centres' care was reliable (3.017±0.346). The mean score (3.043±0.375) shows satisfaction with the responsiveness of the Health care givers to the need of the Clients' during ANC. Clients were satisfied with the general appearance of the health facilities (3.103±0.364). Keywords: Evaluation, Service, Quality, Dimensions, Antenata

Supermassive black hole winds in X-rays: SUBWAYS: II. HST UV spectroscopy of winds at intermediate redshifts

We present a UV spectroscopic study of ionized outflows in 21 active galactic nuclei (AGN), observed with the Hubble Space Telescope (HST). The targets of the Supermassive Black Hole Winds in X-rays (SUBWAYS) sample were selected with the aim to probe the parameter space of the underexplored AGN between the local Seyfert galaxies and the luminous quasars at high redshifts. Our targets, spanning redshifts of 0.1–0.4 and bolometric luminosities (Lbol) of 1045–1046 erg s-1, have been observed with a large multi-wavelength campaign using XMM-Newton, NuSTAR, and HST. Here, we model the UV spectra and look for different types of AGN outflows that may produce either narrow or broad UV absorption features. We examine the relations between the observed UV outflows and other properties of the AGN. We find that 60% of our targets show a presence of outflowing H¿I absorption, while 40% exhibit ionized outflows seen as absorption by either C¿IV, N¿V, or O¿VI. This is comparable to the occurrence of ionized outflows seen in the local Seyfert galaxies. All UV absorption lines in the sample are relatively narrow, with outflow velocities reaching up to -3300 km s-1. We did not detect any UV counterparts to the X-ray ultra-fast outflows (UFOs), most likely due to their being too highly ionized to produce significant UV absorption. However, all SUBWAYS targets with an X-ray UFO that have HST data demonstrate the presence of UV outflows at lower velocities. We find significant correlations between the column density (N) of the UV ions and Lbol of the AGN, with NH I decreasing with Lbol, while NO VI is increasing with Lbol. This is likely to be a photoionization effect, where toward higher AGN luminosities, the wind becomes more ionized, resulting in less absorption by neutral or low-ionization ions and more absorption by high-ionization ions. In addition, we find that N of the UV ions decreases as their outflow velocity increases. This may be explained by a mechanical power that is evacuating the UV-absorbing medium. Our observed relations are consistent with multiphase AGN feeding and feedback simulations indicating that a combination of both radiative and mechanical processes are in play.Peer ReviewedPostprint (published version

Electronic excitations and the tunneling spectra of metallic nanograins

Tunneling-induced electronic excitations in a metallic nanograin are classified in terms of {\em generations}: subspaces of excitations containing a specific number of electron-hole pairs. This yields a hierarchy of populated excited states of the nanograin that strongly depends on (a) the available electronic energy levels; and (b) the ratio between the electronic relaxation rate within the nano-grain and the bottleneck rate for tunneling transitions. To study the response of the electronic energy level structure of the nanograin to the excitations, and its signature in the tunneling spectrum, we propose a microscopic mean-field theory. Two main features emerge when considering an Al nanograin coated with Al oxide: (i) The electronic energy response fluctuates strongly in the presence of disorder, from level to level and excitation to excitation. Such fluctuations produce a dramatic sample dependence of the tunneling spectra. On the other hand, for excitations that are energetically accessible at low applied bias voltages, the magnitude of the response, reflected in the renormalization of the single-electron energy levels, is smaller than the average spacing between energy levels. (ii) If the tunneling and electronic relaxation time scales are such as to admit a significant non-equilibrium population of the excited nanoparticle states, it should be possible to realize much higher spectral densities of resonances than have been observed to date in such devices. These resonances arise from tunneling into ground-state and excited electronic energy levels, as well as from charge fluctuations present during tunneling.Comment: Submitted to the Physical Review

Supermassive black hole winds in X-rays: SUBWAYS: I. Ultra-fast outflows in quasars beyond the local Universe

We present a new X-ray spectroscopic study of 22 luminous (2 × 1045 ¿ Lbol/erg s-1 ¿ 2 × 1046) active galactic nuclei (AGNs) at intermediate redshifts (0.1 ¿ z ¿ 0.4), as part of the SUpermassive Black hole Winds in the x-rAYS (SUBWAYS) sample, mostly composed of quasars and type 1 AGNs. Here, 17 targets were observed with XMM-Newton in 2019–2020, and the remaining 5 are from previous observations. The aim of this large campaign (1.45 Ms duration) is to characterise the various manifestations of winds in the X-rays driven from supermassive black holes in AGNs. In this paper we focus on the search for and characterisation of ultra-fast outflows (UFOs), which are typically detected through blueshifted absorption troughs in the Fe K band (E > 7 keV). By following Monte Carlo procedures, we confirm the detection of absorption lines corresponding to highly ionised iron (e.g. Fe¿XXV Ha and Fe¿XXVI Lya) in 7 out of 22 sources at the ¿95% confidence level (for each individual line). The global combined probability of such absorption features in the sample is > 99.9%. The SUBWAYS campaign, based on XMM-Newton, extends to higher luminosities and redshifts than previous local studies on Seyferts. We find a UFO detection fraction of ~30% of the total sample, which is in agreement with previous findings. This work independently provides further support for the existence of highly ionised matter propagating at mildly relativistic speeds (¿0.1c) in a considerable fraction of AGNs over a broad range of luminosities, which is believed to play a key role in the self-regulated AGN feeding-feedback cycle, as also supported by hydrodynamical multi-phase simulations.Peer ReviewedPostprint (published version

High pressure phases in highly piezoelectric Pb(Zr0.52Ti0.48)O3

Two novel room-temperature phase transitions are observed, via synchrotron x-ray diffraction and Raman spectroscopy, in the Pb(Zr0.52Ti0.48)O3 alloy under hydrostatic pressures up to 16 GPa. A monoclinic (M)-to-rhombohedral (R1) phase transition takes place around 2-3 GPa, while this R1 phase transforms into another rhombohedral phase, R2, at about 6-7 GPa. First-principles calculations assign the R3m and R3c symmetry to R1 and R2, respectively, and reveal that R2 acts as a pressure-induced structural bridge between the polar R3m and a predicted antiferrodistortive R-3c phase.Comment: REVTeX, 4 pages with 3 figures embedded. Figs 1 and 3 in colo

Transcriptome and phenotypic analysis reveals Gata3-dependent signalling pathways in murine hair follicles

Abstract The transcription factor Gata3 is crucially involved in epidermis and hair follicle differentiation. Yet, little is known about how Gata3 co-ordinates stem cell lineage determination in skin, what pathways are involved and how Gata3 differentially regulates distinct cell populations within the hair follicle. Here, we describe a conditional Gata3-/- mouse (K14-Gata3-/-) in which Gata3 is specifically deleted in epidermis and hair follicles. K14-Gata3-/- mice show aberrant postnatal growth and development, delayed hair growth and maintenance, abnormal hair follicle organization and irregular pigmentation. After the first hair cycle, the germinative layer surrounding the dermal papilla was not restored; instead, proliferation was pronounced in basal epidermal cells. Transcriptome analysis of laser-dissected K14-Gata3-/- hair follicles revealed mitosis, epithelial differentiation and the Notch, Wnt and BMP signaling pathways to be significantly overrepresented. Elucidation of these pathways at the RNA and protein levels and physiologic endpoints suggests that Gata3 integrates diverse signaling networks to regulate the balance between hair follicle and epidermal cell fates

A Bichromatic Incidence Bound and an Application

We prove a new, tight upper bound on the number of incidences between points and hyperplanes in Euclidean d-space. Given n points, of which k are colored red, there are O_d(m^{2/3}k^{2/3}n^{(d-2)/3} + kn^{d-2} + m) incidences between the k red points and m hyperplanes spanned by all n points provided that m = \Omega(n^{d-2}). For the monochromatic case k = n, this was proved by Agarwal and Aronov. We use this incidence bound to prove that a set of n points, no more than n-k of which lie on any plane or two lines, spans \Omega(nk^2) planes. We also provide an infinite family of counterexamples to a conjecture of Purdy's on the number of hyperplanes spanned by a set of points in dimensions higher than 3, and present new conjectures not subject to the counterexample.Comment: 12 page

Bioinspired total synthesis of erectones A and B, and the revised structure of hyperelodione D

Version of record online: March 14, 2022The field of biomimetic synthesis seeks to apply biosynthetic hypotheses to the efficient construction of complex natural products. This approach can also guide the revision of incorrectly assigned structures. Herein, we describe the evolution of a concise total synthesis and structural reassignment of hyperelodione D, a tetracyclic meroterpenoid derived from a Hypericum plant, alongside some biogenetically related natural products, erectones A and B. The key step in the synthesis of hyperelodione D forms six stereocentres and three rings in a bioinspired cascade reaction that features an intermolecular Diels-Alder reaction, an intramolecular Prins reaction and a terminating cycloetherification.Liam J. Franov, Jacob D. Hart, Glenn A. Pullella, Christopher J. Sumby, and Jonathan H. Georg