Anion selective membrane

Experimental anion permselective membranes were prepared and tested for their suitability as cell separators in a chemical redox power storage system being developed at NASA-Lewis Research Center. The goals of long-term (1000 hr) oxidative and thermal stability at 80 C in FeCl3 and CrCl3 electrolytes were met by most of the weak base and strong base amino exchange groups considered in the program. Good stability is exhibited by several of the membrane substrate resins. These are 'styrene' divinylbenzene copolymer and PVC film. At least four membrane systems produce strong flexible films with electrochemical properties (resistivity, cation transfer) superior to those of the 103QZL, the most promising commercial membrane. The physical and chemical properties of the resins are listed

Scheduling spacecraft operations

A prototype scheduling system named MAESTRO currently under development is being used to explore possible approaches to the spacecraft operations scheduling problem. Results indicate that the appropriate combination of heuristic and other techniques can provide an acceptable solution to the scheduling problem over a wide range of operational scenarios and management approaches. These can include centralized or distributed instrument or systems control, batch or incremental scheduling, scheduling loose resource envelopes or exact profiles, and scheduling with varying degrees of user intervention. Techniques used within MAESTRO to provide this flexibility and power include constraint propagation mechanisms, multiple asynchronous processes, prioritized transaction-based command management, resource opportunity calculation, user-alterable selection and placement mechanisms, and maintenance of multiple schedules and resource profiles. These techniques and scheduling complexities requiring them are discussed

The role of artificial intelligence techniques in scheduling systems

Artificial Intelligence (AI) techniques provide good solutions for many of the problems which are characteristic of scheduling applications. However, scheduling is a large, complex heterogeneous problem. Different applications will require different solutions. Any individual application will require the use of a variety of techniques, including both AI and conventional software methods. The operational context of the scheduling system will also play a large role in design considerations. The key is to identify those places where a specific AI technique is in fact the preferable solution, and to integrate that technique into the overall architecture

Managing temporal relations

Various temporal constraints on the execution of activities are described, and their representation in the scheduling system MAESTRO is discussed. Initial examples are presented using a sample activity described. Those examples are expanded to include a second activity, and the types of temporal constraints that can obtain between two activities are explored. Soft constraints, or preferences, in activity placement are discussed. Multiple performances of activities are considered, with respect to both hard and soft constraints. The primary methods used in MAESTRO to handle temporal constraints are described as are certain aspects of contingency handling with respect to temporal constraints. A discussion of the overall approach, with indications of future directions for this research, concludes the study

Screening process for activity determination of conductive oxide electrodes for organic oxidation

A modified method for the calculation of the normalized faradaic charge (q fN) is proposed. The method involves the simulation of an oxidation process, by cyclic voltammetry, by employing potentials in the oxygen evolution reaction region. The method is applicable to organic species whose oxidation is not manifested by a defined oxidation peak at conductive oxide electrodes. The variation of q fN for electrodes of nominal composition Ti/RuX Sn1-X O2 (x = 0.3, 0.2 and 0.1), Ti/Ir0.3Ti0.7O2 and Ti/Ru0.3Ti0.7O2 in the presence of various concentrations of formaldehyde was analyzed. It was observed that electrodes containing SnO2 are the most active for formaldehyde oxidation. Subsequently, in order to test the validity of the proposed model, galvanostatic electrolyses (40 mA cm-2) of two different formaldehyde concentrations (0.10 and 0.01 mol dm-3) were performed. The results are in agreement with the proposed model and indicate that this new method can be used to determine the relative activity of conductive oxide electrodes. In agreement with previous studies, it can be concluded that not only the nature of the electrode material, but also the organic species in solution and its concentration are important factors to be considered in the oxidation of organic compounds.Um método modificado para o cálculo da carga faradaica normalizada (q fN) é proposto. O método envolve a simulação de um processo de oxidação, por voltametria cíclica, empregando potenciais na região da reação de desprendimento de oxigênio (RDO). Este método é aplicável a espécies orgânicas, cuja oxidação não é manifestada por um pico de oxidação definido em eletrodos de óxidos condutores. A variação de q fN para eletrodos de composição nominal Ti/RuX Sn1-X O2 (x = 0,3; 0,2 e 0,1), Ti/Ir0,3Ti0,7O2 e Ti/Ru0,3Ti0,7O2, na presença de diferentes concentrações de formaldeído foi investigada. Foi observado que eletrodos contendo SnO2 são os mais ativos frente à oxidação de formaldeído. Subseqüentemente, para investigar a aplicabilidade do modelo proposto, eletrólises galvanostáticas (40 mA cm-2) de formaldeído foram efetuadas em duas concentrações distintas (0,10 e 0,01 mol dm-3). Os resultados estão de acordo com o modelo proposto e indicam que este novo método pode ser usado para determinar a atividade relativa de eletrodos de óxido. De acordo com trabalhos prévios, pode ser concluído que não somente a natureza do material eletródico, mas também a espécie orgânica em solução e a sua concentração são fatores importantes a serem considerados na oxidação de espécies orgânicas.FAPES

Breaking arches with vibrations: the role of defects

We present experimental results about the stability of arches against external vibrations. Two dimensional strings of mutually stabilizing grains are geometrically analyzed and subsequently submitted to a periodic forcing at fixed frequency and increasing amplitude. The main factor that determines the granular arch resistance against vibrations is the maximum angle among those formed between any particle of the arch and its two neighbors: the higher the maximum angle is, the easier to break the arch. Based in an analysis of the forces, a simple explanation is given for this dependence. From this, interesting information can be extracted about the expected magnitudes of normal forces and friction coefficients of the particles conforming the arches

High efficiency GaAs-Ge tandem solar cells grown by MOCVD

High conversion efficiency and low weight are obviously desirable for solar cells intended for space applications. One promising structure is GaAs on Ge. The advantages of using Ge wafers as substrates include the following: they offer high efficiency by forming a two-junction tandem cell; low weight combined with superior strength allows usage of thin (3 mil) wafers; and they are a good substrate for GaAs, being lattice matched, thermal expansion matched, and available as large-area wafers