Boosting the Performance of WO3/n‐Si Heterostructures for Photoelectrochemical Water Splitting: from the Role of Si to Interface Engineering

Metal oxide/Si heterostructures make up an exciting design route to high‐performance electrodes for photoelectrochemical (PEC) water splitting. By monochromatic light sources, contributions of the individual layers in WO3/n‐Si heterostructures are untangled. It shows that band bending near the WO3/n‐Si interface is instrumental in charge separation and transport, and in generating a photovoltage that drives the PEC process. A thin metal layer inserted at the WO3/n‐Si interface helps in establishing the relation among the band bending depth, the photovoltage, and the PEC activity. This discovery breaks with the dominant Z‐scheme design idea, which focuses on increasing the conductivity of an interface layer to facilitate charge transport, but ignores the potential profile around the interface. Based on the analysis, a high‐work‐function metal is predicted to provide the best interface layer in WO3/n‐Si heterojunctions. Indeed, the fabricated WO3/Pt/n‐Si photoelectrodes exhibit a 2 times higher photocurrent density at 1.23 V versus reversible hydrogen electrode (RHE) and a 10 times enhancement at 1.6 V versus RHE compared to WO3/n‐Si. Here, it is essential that the native SiO2 layer at the interface between Si and the metal is kept in order to prevent Fermi level pinning in the Schottky contact between the Si and the metal.</p

Approximation of explicit model predictive control using regular piecewise affine functions: an input-to-state stability approach

Abstract Piecewise affine (PWA) feedback control laws defined on general polytopic partitions, as for instance obtained by explicit MPC, will often be prohibitively complex for fast systems. In this work we study the problem of approximating these high-complexity controllers by low-complexity PWA control laws defined on more regular partitions, facilitating faster on-line evaluation. The approach is based on the concept of input-to-state stability (ISS). In particular, the existence of an ISS Lyapunov function (LF) is exploited to obtain a priori conditions that guarantee asymptotic stability and constraint satisfaction of the approximate low-complexity controller. These conditions can be expressed as local semidefinite programs (SDPs) or linear programs (LPs), in case of 2-norm or 1, ∞-norm based ISS, respectively, and apply to PWA plants. In addition, as ISS is a prerequisite for our approximation method, we provide two tractable computational methods for deriving the necessary ISS inequalities from nominal stability. A numerical example is provided that illustrates the main results. The authors are with the Hybrid an

Presence of 1/f noise in the temporal structure of psychoacoustic parameters of natural and urban sounds.

1/f noise or pink noise, which has been shown to be universal in nature, has also been observed in the temporal envelope of music, speech, and environmental sound. Moreover, the slope of the spectral density of the temporal envelope of music has been shown to correlate well to its pleasing, dull, or chaotic character. In this paper, the temporal structure of a number of instantaneous psychoacoustic parameters of environmental sound is examined in order to investigate whether a 1/f temporal structure appears in various types of sound that are generally preferred by people in everyday life. The results show, to some extent, that different categories of environmental sounds have different temporal structure characteristics. Only a number of urban sounds considered and birdsong, generally, exhibit 1/f behavior on short to medium duration time scales, i.e., from 0.1 s to 10 s, in instantaneous loudness and sharpness, whereas a more chaotic variation is found in birdsong at longer time scales, i.e., of 10 s-200 s. The other sound categories considered exhibit random or monotonic variations in the different time scales. In general, this study shows that a 1/f temporal structure is not necessarily present in environmental sounds that are commonly perceived as pleasant

Software architecture for control and data acquisition of linear plasma generator Magnum-PSI

The FOM Institute DIFFER – Dutch Institute for Fundamental Energy Research has completed the construction phase of Magnum-PSI, a magnetized, steady-state, large area, high-flux linear plasma beam generator to study plasma surface interactions under ITER divertor conditions. Magnum-PSI consists of several hardware subsystems, and a variety of diagnostic systems. The COntrol, Data Acquisition and Communication (CODAC) system integrates these subsystems and provides a complete interface for the Magnum-PSI users. Integrating it all, from the lowest hardware level of sensors and actuators, via the level of networked PLCs and computer systems, up to functions and classes in programming languages, demands a sound and modular software architecture, which is extendable and scalable for future changes. This paper describes this architecture, and the modular design of the software subsystems. The design is implemented in the CODAC system at the level of services and subsystems (the overall software architecture), as well as internally in the software subsystems.</p

Power handling of a liquid-metal based CPS structure under high steady-state heat and particle fluxes

Liquid metal infused capillary porous structures (CPSs) are considered as a potential divertor solution for DEMO due to their potential power handling capability and resilience to long term damage. In this work the power handling and performance of such Sn-based CPS systems is assessed both experimentally and via modelling. A Sn-CPS target was exposed to heat fluxes of up to 18.1 MW m−2 in He plasma in the Pilot-PSI linear device. Post-mortem the target showed no damage to nor any surface exposure of the underlying W-CPS felt. The small pore size (∼40 µm) employed resulted in no droplet formation from the target in agreement with calculated Rayleigh-Taylor and Kelvin-Helmoholtz instability thresholds. The temperature response of the Sn-target was used to determine the thermal conductivity of the mixed Sn-CPS material using COMSOL modelling. These values were then used via further finite element analysis to extrapolate to DEMO relevant monoblock designs and estimate the maximum power handling achievable based on estimated temperature windows for all component elements of the design. For an optimized design a heat-load of up to 20 MW m−2 may be received while the use of CPS also offers other potential design advantages such as the removal of interlayer requirements

Thermographic investigation of the effect of plasma exposure on the surface of a MAST upgrade divertor tile in Magnum-PSI

One of the issues faced by future fusion devices will be high divertor target heat loads. Alternative divertors can promote detachment, flux expansion and dissipation mechanisms to mitigate these heat loads. They have been investigated in several devices including TCV and DIII-D, and will be investigated on MAST-U. To evaluate their effectiveness, accurate target heat flux and power balance measurements are required in these machines. Infrared (IR) thermography is a widely used technique to determine the target heat flux, but is susceptible to surface effects and emissivity in carbon-walled machines. In this work, the effect of plasma exposure on graphite is assessed to understand what may happen in MAST-U. A sample of fine grain graphite, as used on MAST-U, is exposed to 30min plasma exposures, with density ne=6 × 1018m−3 and temperature Te=0.08eV as measured by Thomson scattering. During these pulses, the temperature is measured by a medium wave IR camera and is seen to decrease by ≈70 °C over the course of 3h of plasma exposure. Pyrometer measurements suggest that the IR camera data is affected by a change in the surface emissivity. Profilometry confirms erosion of graphite at the tile centre to a depth of ≈100µm, and a larger region of deposition further out, amounting to ≈40µm of material