Visualisation and characterisation of flame radical emissions through intensified spectroscopic imaging

Combustion flames contain strong emissions from excited radical species produced by the combustion process. The monitoring and characterisation of such emissions is important for an in-depth understanding of fuel energy conversion and pollutant formation processes. In this paper, an approach combining emission spectroscopy with intensified digital imaging techniques is proposed for visualising and quantifying the radiative characteristics of free radicals of combustion flames. Recent advances in CCD technology, especially in EM image intensification, have made it possible to obtain high resolution emission images of isolated spectral emissions from particular flame radicals. These can be used to study emission intensity and distribution, with the aim of correlating combustion emission products with flame spectral emission patterns

Carotenoids and chlorophyll content in natural soap with addition of vegetative raw material

In the present study, we performed quantitative and qualitative determination of carotenoids and chlorophyll in five samples of natural soap with addition of vegetative raw material: Green tea, Chamerion angustifolium (L.) Holub, Trifolium pratense L., Alchemilla vulgaris L. and Urtica dioica L. There was developed the method of quantitative content of carotenoids and chlorophyll using spectrophotometry with analytical wavelength at 450 nm (carotenoids) and 667 nm (chlorophyll). Qualitative determination was carried out by the comparative TLC analysis. As mobile phases were used in the experiment following a mixed solvent of hexane-acetone (3: 1). Identification of carotenoids was carried out according to standard samples β -carotene and literature data

Influence of shock wave propagation on dielectric barrier discharge plasma actuator performance

Interest in plasma actuators as active flow control devices is growing rapidly due to their lack of mechanical parts, light weight and high response frequency. Although the flow induced by these actuators has received much attention, the effect that the external flow has on the performance of the actuator itself must also be considered, especially the influence of unsteady high-speed flows which are fast becoming a norm in the operating flight envelopes. The primary objective of this study is to examine the characteristics of a dielectric barrier discharge (DBD) plasma actuator when exposed to an unsteady flow generated by a shock tube. This type of flow, which is often used in different studies, contains a range of flow regimes from sudden pressure and density changes to relatively uniform high-speed flow regions. A small circular shock tube is employed along with the schlieren photography technique to visualize the flow. The voltage and current traces of the plasma actuator are monitored throughout, and using the well-established shock tube theory the change in the actuator characteristics are related to the physical processes which occur inside the shock tube. The results show that not only is the shear layer outside of the shock tube affected by the plasma but the passage of the shock front and high-speed flow behind it also greatly influences the properties of the plasma

Experimental and numerical study of chemiluminescence characteristics in premixed counterflow flames of methane based fuel blends

Non-intrusive chemiluminescence measurements have been used as heat release rate and equivalence ratio indicators for gas turbine combustor active control. In the present study, measurements and modelling of OH*, CH(A)*, C 2 *, and CO 2 * chemiluminescence are used to examine chemiluminescence sensing of heat release rate and equivalence ratio in premixed counterflow methane – air flames with equivalence ratio from 0.6 to 1.3 and strain rate from 80 to 400 s -1 . Two spectrally resolved detecting optical systems were used to detect spatially-averaged (global) and spatially resolved (local) chemiluminescence characteristics in the reaction zone. A recently published reaction mechanism 1 for the chemiluminescence of the OH*, CH*, and C 2 * species is incorporated to GRI-Mech 3.0. The augmented mechanism is further validated against the experimental results of the present study and is used to predict the chemiluminescence characteristics of premixed counterflow methane – air flames. The mechanism includes OH* chemiluminescence formation paths from hydrogen reaction, which have not been evaluated before in premixed counterflow flames. The CHEMKIN based counterflow flame code, OPPDIF is employed to simulate the experiments. The calculated OH* and CH(A)* chemiluminescence agrees well with the experimental results measured by both optical methods. Both the experimental and numerical results demonstrate the ability of OH* and CH(A)* intensities to mark heat release rate in methane – air flames. Overall, CH* may be preferable for heat release rate sensing applications at elevated equivalence ratio and strain rate. For equivalence ratio sensing in methane combustion, the measured and simulated OH*/CH(A)* chemiluminescent intensity ratio is highly dependent on equivalence ratio and nearly independent of strain rate. Thus, this ratio can be used to monitor equivalence ratio. However, a non-monotonic behavior of the OH*/CH* ratio for very lean combustion (ER < 0.7) is observed, in agreement with previous studies. This behavior can be reproduced by the reaction mechanisms. The behavior of OH*/CH(A)* chemiluminescent intensity ratio for flames of methanepropane blends are also calculated with the detailed chemistry model. The addition of propane in methane modifies the behaviour of OH*/CH(A)* chemiluminescent intensity ratio dramatically. However, the numerical results suggest that the OH*/CH(A)* chemiluminescent intensity ratio is an indicator of equivalence ratio in lean methanepropane fuel blended flames

Oxidation of Reduced Sulfur Species: Carbon Disulfide

Article on the oxidation of reduced sulfur species and carbon disulfide