Approximate Controllability, Exact Controllability, and Conical Eigenvalue Intersections for Quantum Mechanical Systems

International audienceWe study the controllability of a closed control-affine quantum system driven by two or more external fields. We provide a sufficient condition for controllability in terms of existence of conical intersections between eigenvalues of the Hamiltonian in dependence of the controls seen as parameters. Such spectral condition is structurally stable in the case of three controls or in the case of two controls when the Hamiltonian is real. The spectral condition appears naturally in the adiabatic control framework and yields approximate controllability in the infinite-dimensional case. In the finite-dimensional case it implies that the system is Lie-bracket generating when lifted to the group of unitary transformations, and in particular that it is exactly controllable. Hence, Lie algebraic conditions are deduced from purely spectral properties. We conclude the article by proving that approximate and exact controllability are equivalent properties for general finite-dimensional quantum systems

Transition from confined to bulk dynamics in symmetric star-linear polymer mixtures

We report on the linear viscoelastic properties of mixtures comprising multiarm star (as model soft colloids) and long linear chain homopolymers in a good solvent. In contrast to earlier works, we investigated symmetric mixtures (with a size ratio of 1) and showed that the polymeric and colloidal responses can be decoupled. The adopted experimental protocol involved probing the linear chain dynamics in different star environments. To this end, we studied mixtures with different star mass fraction, which was kept constant while linear chains were added and their entanglement plateau modulus ($G_p$) and terminal relaxation time ($\tau_d$) were measured as functions of their concentration. Two distinct scaling regimes were observed for both $G_p$ and $\tau_d$: at low linear polymer concentrations, a weak concentration dependence was observed, that became even weaker as the fraction of stars in the mixtures increased into the star glassy regime. On the other hand, at higher linear polymer concentrations, the classical entangled polymer scaling was recovered. Simple scaling arguments show that the threshold crossover concentration between the two regimes corresponds to the maximum osmotic star compression and signals the transition from confined to bulk dynamics. These results provide the needed ingredients to complete the state diagram of soft colloid-polymer mixtures and investigate their dynamics at large polymer-colloid size ratios. They also offer an alternative way to explore aspects of the colloidal glass transition and the polymer dynamics in confinement. Finally, they provide a new avenue to tailor the rheology of soft composites.Comment: 9 Figure

Urban planning and sustainable development

The concept of sustainable development has emerged over the past decades as a new requirement for urban and metropolitan level public action, which involves conceptual principles and practices as applied to land-use and urban planning. Today, it is commonplace to find the term “sustainable city” and the expression “sustainable urban development” cited to denote intentions and paragons of political utopia and of land-use and urban planning practices considered to be innovative (Da Cunha et al...