297 research outputs found

    Monitoring the Petermann Ice Island with TanDEM-X

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    This paper presents the processing of TanDEM-X acquisitions for the monitoring of the topography of the Petermann ice island. In this particular case the area under study is continuously moving and the acquisition geometry is changing, so the processing of the iceberg’s DEMs is challenging and additional effects are to be considered. The SAR processing chain used is presented and the results obtained summarized, showing the effects and limitations observed during the process

    Rainfall partitioning after thinning in two low-biomass semiarid forests: Impact of meteorological variables and forest structure on the effectiveness of water-oriented treatments

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    [EN] Water-oriented forest management is an urgent need in semiarid catchments. In the case of low-biomass forests and shrublands, the magnitude, efficiency and temporal duration of thinning effects on rainfall partitioning needs further attention. This work studies the effects of juvenile thinning and shrub clearing on stemflow (Stf), throughfall (Thr) and interception (It) in two low-biomass forests (CAL: post-fire Aleppo pine saplings with 74% of basal area, BA, removed; and HU: evergreen oak coppice with 41% of BA removed), as well as the relative contribution of the event meteorology. The effects are compared with a control plot during the first 3¿4¿years. Stf rate (%) decreased with density and, on a tree scale, it was enhanced by the treatment only in the bigger oaks. Event Thr increased from 55 to 81% and from 68 to 86% of gross rainfall (Pg) for CAL and HU respectively after thinning, resulting in about 15% less intercepted Pg. High evaporative conditions and an open (ventilated) forest structure led to high It rates in the controls when comparing with other studies, thus making the treatments more efficient in net precipitation (Pn) gain (Pg intercepted decreased 17% or 2.3% per unit of LAI or BA removed respectively). In general, depths (mm) were mostly explained (>75%) by the rainfall characteristics of the event (e.g. amount, duration, intensity), with a limited contribution from forest structure (e.g. cover, LAI) and event meteorology (e.g. temperature, wind speed, vapor pressure deficit). On the contrary, when expressed as rates (% of Pg), forest structure and event-meteorology gained importance (explaining 25¿65%), especially in the drier site (CAL). In this site, the low gain in Pn (~25¿mm per year on average) was offset with no temporal dampening during the span of this study, as observed in the wetter site (HU), where plant growth tended to mitigate the effect of the treatment by the end of the study. The results presented here make a contribution to a better understanding of the effects of water-oriented forest management in low-biomass semiarid forests.This study is a component of research projects: HYDROSIL (CGL2011-28776-C02-02), SILWAMED (CGL2014-58127-C3-2) and CEHYRFO-MED (CGL2017-86839-C3-2-R) funded by the Spanish Ministry of Science and Innovation and the FEDER fund of the EU. The authors are grateful to the Valencia Regional Government (CMAAUV, Generalitat Valenciana), Serra municipality, VAERSA and ACCIONA for their support in allowing the use of the experimental forest and for their assistance in carrying out the fieldwork.Campo García, ADD.; González Sanchís, MDC.; Lidón, A.; Ceacero Ruiz, CJ.; Garcia-Prats, A. (2018). Rainfall partitioning after thinning in two low-biomass semiarid forests: Impact of meteorological variables and forest structure on the effectiveness of water-oriented treatments. Journal of Hydrology. 565:74-86. https://doi.org/10.1016/j.jhydrol.2018.08.013S748656

    Boosting the activity of transition metal carbides towards methane activation by nanostructuring

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    The interaction of methane with pristine surfaces of bulk MoC and Mo2C is known to be weak. In contrast, a series of X-ray photoelectron spectroscopy (XPS) experiments, combined with thermal desorption mass spectroscopy (TDS), for MoCy (y = 0.5-1.3) nanoparticles supported on Au(111)¿which is completely inert towards CH4¿show that these systems adsorb and dissociate CH4 at room temperature and low CH4 partial pressure. This industrially-relevant finding has been further investigated with accurate density functional theory (DFT) based calculations on a variety of MoCy supported model systems. The DFT calculations reveal that the MoCy/Au(111) systems can feature low C-H bond scission energy barriers, smaller than the CH4 adsorption energy. Our theoretical results for bulk surfaces of Mo2C and MoC show that a simple Brønsted-Evans-Polanyi (BEP) relationship holds for C-H bond scission on these systems. However, this is not the case for methane activation on the MoCy nanoparticles as a consequence of their unique electronic and chemical properties. The discovery that supported molybdenum carbide nanoparticles are able to activate methane at room temperature paves the road towards the design of a new family of active carbide catalysts for methane activation and valorisation, with important implications in climate change mitigation and carbon cycle closure

    Room temperature methane capture and activation by Ni clusters supported on TiC(001): effects of metal-carbide interactions on the cleavage of the C-H bond

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    Methane is an extremely stable molecule, a major component of natural gas, and also one of the most potent greenhouse gases contributing to global warming. Consequently, the capture and activation of methane is a challenging and intensively studied topic. A major research goal is to find systems that can activate methane even at low temperature. Here, combining ultrahigh vacuum catalytic experiments followed by X-ray photoemission spectra and accurate density functional theory (DFT) based calculations, we show that small Ni clusters dispersed on the (001) surface of TiC are able to capture and dissociate methane at room temperature. Our DFT calculations reveal that two-dimensional Ni clusters are responsible of this chemical transformation, evidencing that the lability of the supported clusters appears to be a critical aspect in the strong adsorption of methane. A small energy barrier of 0.18 eV is predicted for CH4 dissociation into adsorbed methyl and hydrogen atom species. In addition, the calculated reaction free energy profile at 300 K and 1 atm of CH4 shows no effective energy barriers in the system. Comparing with other reported systems which activate methane at room temperature, including oxide and zeolite-based materials, indicates that a different chemistry takes place on our metal/carbide system. The discovery of a carbide-based surface able to activate methane at low temperatures paves the road for the design of new types of catalysts towards an efficient conversion of this hydrocarbon into other added-value chemicals, with implications in climate change mitigation

    Electrohysterogram for ANN-Based Prediction of Imminent Labor in Women with Threatened Preterm Labor Undergoing Tocolytic Therapy

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    [EN] Threatened preterm labor (TPL) is the most common cause of hospitalization in the second half of pregnancy and entails high costs for health systems. Currently, no reliable labor proximity prediction techniques are available for clinical use. Regular checks by uterine electrohysterogram (EHG) for predicting preterm labor have been widely studied. The aim of the present study was to assess the feasibility of predicting labor with a 7- and 14-day time horizon in TPL women, who may be under tocolytic treatment, using EHG and/or obstetric data. Based on 140 EHG recordings, artificial neural networks were used to develop prediction models. Non-linear EHG parameters were found to be more reliable than linear for differentiating labor in under and over 7/14 days. Using EHG and obstetric data, the <7- and <14-day labor prediction models achieved an AUC in the test group of 87.1 +/- 4.3% and 76.2 +/- 5.8%, respectively. These results suggest that EHG can be reliable for predicting imminent labor in TPL women, regardless of the tocolytic therapy stage. This paves the way for the development of diagnostic tools to help obstetricians make better decisions on treatments, hospital stays and admitting TPL women, and can therefore reduce costs and improve maternal and fetal wellbeing.This work was supported by the Spanish Ministry of Economy and Competitiveness, the European Regional Development Fund (MCIU/AEI/FEDER, UE RTI2018-094449-A-I00-AR) and by the Generalitat Valenciana (AICO/2019/220).Mas-Cabo, J.; Prats-Boluda, G.; Garcia-Casado, J.; Alberola Rubio, J.; Monfort-Ortiz, R.; Martinez-Saez, C.; Perales, A.... (2020). Electrohysterogram for ANN-Based Prediction of Imminent Labor in Women with Threatened Preterm Labor Undergoing Tocolytic Therapy. 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(2011). Comparison between approximate entropy, correntropy and time reversibility: Application to uterine electromyogram signals. Medical Engineering & Physics, 33(8), 980-986. doi:10.1016/j.medengphy.2011.03.010Fergus, P., Idowu, I., Hussain, A., & Dobbins, C. (2016). Advanced artificial neural network classification for detecting preterm births using EHG records. Neurocomputing, 188, 42-49. doi:10.1016/j.neucom.2015.01.107Acharya, U. R., Sudarshan, V. K., Rong, S. Q., Tan, Z., Lim, C. M., Koh, J. E., … Bhandary, S. V. (2017). Automated detection of premature delivery using empirical mode and wavelet packet decomposition techniques with uterine electromyogram signals. Computers in Biology and Medicine, 85, 33-42. doi:10.1016/j.compbiomed.2017.04.013Fergus, P., Cheung, P., Hussain, A., Al-Jumeily, D., Dobbins, C., & Iram, S. (2013). Prediction of Preterm Deliveries from EHG Signals Using Machine Learning. PLoS ONE, 8(10), e77154. doi:10.1371/journal.pone.0077154Ren, P., Yao, S., Li, J., Valdes-Sosa, P. A., & Kendrick, K. M. (2015). Improved Prediction of Preterm Delivery Using Empirical Mode Decomposition Analysis of Uterine Electromyography Signals. PLOS ONE, 10(7), e0132116. doi:10.1371/journal.pone.0132116Degbedzui, D. K., & Yüksel, M. E. (2020). Accurate diagnosis of term–preterm births by spectral analysis of electrohysterography signals. Computers in Biology and Medicine, 119, 103677. doi:10.1016/j.compbiomed.2020.103677Borowska, M., Brzozowska, E., Kuć, P., Oczeretko, E., Mosdorf, R., & Laudański, P. (2018). Identification of preterm birth based on RQA analysis of electrohysterograms. Computer Methods and Programs in Biomedicine, 153, 227-236. doi:10.1016/j.cmpb.2017.10.018Vinken, M. P. G. C., Rabotti, C., Mischi, M., van Laar, J. O. E. H., & Oei, S. G. (2010). Nifedipine-Induced Changes in the Electrohysterogram of Preterm Contractions: Feasibility in Clinical Practice. 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Identification of Human Term and Preterm Labor using Artificial Neural Networks on Uterine Electromyography Data. Annals of Biomedical Engineering, 35(3), 465-473. doi:10.1007/s10439-006-9248-8Mas-Cabo, J., Prats-Boluda, G., Garcia-Casado, J., Alberola-Rubio, J., Perales, A., & Ye-Lin, Y. (2019). Design and Assessment of a Robust and Generalizable ANN-Based Classifier for the Prediction of Premature Birth by means of Multichannel Electrohysterographic Records. Journal of Sensors, 2019, 1-13. doi:10.1155/2019/5373810Terrien, J., Marque, C., & Karlsson, B. (2007). Spectral characterization of human EHG frequency components based on the extraction and reconstruction of the ridges in the scalogram. 2007 29th Annual International Conference of the IEEE Engineering in Medicine and Biology Society. doi:10.1109/iembs.2007.4352680Rooijakkers, M. J., Rabotti, C., Oei, S. G., Aarts, R. M., & Mischi, M. (2014). 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    Enhancement of the non-invasive electroenterogram to identify intestinal pacemaker activity

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    Surface recording of electroenterogram (EEnG) is a non-invasive method for monitoring intestinal myoelectrical activity. However, surface EEnG is seriously affected by a variety of interferences: cardiac activity, respiration, very low frequency components and movement artefacts. The aim of this study is to eliminate respiratory interference and very low frequency components from external EEnG recording by means of empirical mode decomposition (EMD), so as to obtain more robust indicators of intestinal pacemaker activity from external EEnG signal. For this purpose, 11 recording sessions were performed in an animal model under fasting conditions and in each individual session the myoelectrical signal was recorded simultaneously in the intestinal serosa and the external abdominal surface in physiological states. Various parameters have been proposed for evaluating the efficacy of the method in reducing interferences: the signal-to-interference ratio (S/I ratio), attenuation of the target and interference signals, the normal slow wave percentage and the stability of the dominant frequency (DF) of the signal. The results show that the S/I ratio of the processed signals is significantly greater than the original values (9.66±4.44 dB vs. 1.23±5.13 dB), while the target signal was barely attenuated (-0.63±1.02 dB). The application of the EMD method also increased the percentage of the normal slow wave to 100% in each individual session and enabled the stability of the DF of the external signal to be increased considerably. Furthermore, the variation coefficient of the DF derived from the external processed signals is comparable to the coefficient obtained using internal recordings. Therefore the EMD method could be a very useful tool to improve the quality of external EEnG recording in the low frequency range, and therefore to obtain more robust indicators of the intestinal pacemaker activity from non invasive EEnG recordingsThe authors would like to thank D Alvarez-Martinez, Dr C Vila and the Veterinary Unit of the Research Centre of 'La Fe' University Hospital (Valencia, Spain), where the surgical interventions and recording sessions were carried out, and the R+D+I Linguistic Assistance Office at the UPV for their help in revising this paper. This research study was sponsored by the Ministerio de Ciencia y Tecnologia de Espana (TEC2007-64278) and by the Universidad Politecnica de Valencia, as part of a UPV research and development Grant Programme.Ye Lin, Y.; Garcia Casado, FJ.; Prats Boluda, G.; Ponce, JL.; Martínez De Juan, JL. (2009). Enhancement of the non-invasive electroenterogram to identify intestinal pacemaker activity. 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    Methodology to improve water and energy use by proper irrigationscheduling in pressurised networks

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    With the aim of reducing energy consumption and improving water use in pressurised irrigation systems, the methodology to minimise energy consumption by grouping intakes of pressurised irrigation networks into sectors, as developed by Jimenez Bello et al. (2010a), was modified to enable irrigation intakes to operate during the scheduled period for each intake instead of operating during restricted irrigation periods of the same length. Moreover, a method was developed to detect the maximum number of intakes that can operate without extra energy if the source has sufficient head to feed at least some of the intakes. These methods were applied to a Mediterranean irrigation system, where the total cropped area was mainly citrus orchards. In this case study, water was allocated to two groups of intakes, one fed by gravity and the other by pumps. A saving of 36.3 % was achieved by increasing the total volume supplied by gravity, decreasing the injection pump head, and improving the pump performance. Therefore, all the intakes only operated during the irrigation periods at the minimum required pressure.This research was supported by funds from Climate-KIC AGADAPT and from EU 7th Framework Programme FIGARO projects. The authors wish to acknowledge the support provided by Picassent Sector XI staff. The revision of this paper was funded by "The Universitat Politecnica de Valencia, Spain".Jiménez Bello, MA.; Royuela Tomás, Á.; Manzano Juarez, J.; García Prats, A.; Martínez Alzamora, F. (2015). Methodology to improve water and energy use by proper irrigationscheduling in pressurised networks. Agricultural Water Management. 149:91-101. doi:10.1016/j.agwat.2014.10.026S9110114

    Experimental study of the sensitivity of a porous silicon ring resonator sensor using continuous in-flow measurements

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    A highly sensitive photonic sensor based on a porous silicon ring resonator was developed and experimentally characterized. The photonic sensing structure was fabricated by exploiting a porous silicon double layer, where the top layer of a low porosity was used to form photonic elements by e-beam lithography and the bottom layer of a high porosity was used to confine light in the vertical direction. The sensing performance of the ring resonator sensor based on porous silicon was compared for the different resonances within the analyzed wavelength range both for transverse-electric and transverse-magnetic polarizations. We determined that a sensitivity up to 439 nm/RIU for low refractive index changes can be achieved depending on the optical field distribution given by each resonance/polarization

    Commentaire ECJ-TF 1/2023 sur la décision de la CJUE du 16 février 2023 dans l'affaire Gallaher Limited (aff. C-707/20), sur la taxation des plus-values dans les transferts intra-groupes

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    peer reviewedIn this CFE Opinion Statement, submitted to the EU Institutions in June 2023, the CFE ECJ Task Force comments on the ECJ decision in Gallaher Limited (Case C-707/20), which provides further clarity on the scope of the fundamental freedoms, the correct comparator in establishing discrimination and the proportionality of discriminatory taxation of capital gains
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