Spatial Overlay Analysis of Geochemical Singularity Index α-Value of Porphyry Cu Deposit in Gangdese Metallogenic Belt, Tibet, Western China

The statistical modeling with ILR-RPCA-back CLR has two problems when dealing with the closure effect of geochemical data. Firstly, after performing isometric logratio (ilr) transformation, robust principal component analysis (RPCA) is employed for processing. The double-plot diagram illustrates that the element sequence transformation occurs in the first and second principal components, while the unique principal component remains unattainable. Secondly, by transforming both the score and load into the centered logratio (CLR) space using the U matrix, it is possible to obtain a score result that corresponds to the original order of elements according to the CLR = ILR·U formula. However, for obtaining a load result that corresponds to the original order of elements, an alternative formula “CLR = UT·ILR” must be used instead. In order to determine the optimal element assemblage for porphyry copper deposits, this study conducted statistical analysis on mineral assemblages from discovered deposits in the Gangdese metallogenic belt and identified Cu, Mo, Au, Ag, W, and Bi as key elements associated with porphyry copper deposits. Subsequently, by analyzing the singularities of the composite elements, the spatial overlay of the combined element is carried out, and concentration-area (C-A) fractal filtering is applied to identify the anomaly and background areas. To facilitate comparison, we conducted an analysis of various mineral and ore deposit types, revealing the following findings: (1) Combination elements exhibit superior recognition capability than single elements in porphyry copper deposits; (2) Skarn-type copper deposits unrelated to porphyry show a high degree of dissimilarity compared to those related to porphyry; (3) this method offers advantages over the single element method in evaluating porphyry gold deposits by reducing anomaly levels and initial investment during the evaluation stage for porphyry copper anomalies; (4) However, this method has limited ability in distinguishing between porphyry copper and molybdenum deposits

GC-MS Analysis of Chemical Components of Taxus Chinensis Var. Mairei Seeds

The extracts of petroleum ether, methanol, ethyl acetate and ether from Taxus chinensis var. mairei seeds were analyzed by GC-MS, and relative contents were determined using a normalized method. 56 peaks were obtained from extracts of spermoderm and 79 peaks from endosperm of T. chinensis var. mairei. Among these peaks, 37 chemical constituents were gained, and 24 compounds of which were identified (64.86%). There were 35 chemical constituents with content more than 1%, accounting for 94.59% of the total of all chemical constituents. 32 peaks were gained from petroleum ether extract, and 7 peaks were identified (21.88%) with content more than 1%. 36 peaks were gained from methanol extracts, and 14 peaks were identified (38.89%), 13 of which with content more than 1%, accounting for 92.86% of the total of all chemical constituents. 34 peaks were gained from ethyl acetate extracts, while 10 peaks were identified (29.41%) with content more than 1%. 33 peaks were gained from aether extracts, and 11 peaks were identified (33.33%). T. chinensis var. mairei seeds have various bio-active ingredients and a higher value for development and utilization as a medicinal plant

Petrogenesis of the Late Jurassic Granodiorite and Its Implications for Tectonomagmatic Evolution in the Nuocang District, Western Gangdeses

The Gangdese magmatic rocks of the southern Lhasa terrane, are generally thought to be an important window to witness the formation and evolution of the Neo-Tethys oceanic opening, subduction, and closure, and India-Eurasian continental collision. We investigated a new occurrence of granodiorite in the Nuocang district of western Gangdese, southern Lhasa terrane, and conducted a series of analyses on their petrology, chronology, and geochemistry. The Nuocang granodiorites have the zircon U-Pb ages of 151–154 Ma, which suggest that Late Jurassic granitoids are present in the western Gangdese of southern Lhasa terrane. They are relatively high in SiO2, Al2O3, low K2O, Na2O, and Sr/Y ratios, enrichments of LILE and LREE, and depletion of HFSE, with the positive correlation between Rb and Th, and negative correlations between SiO2 and P2O5, Rb, and Y, showing the features of I-type granites. The relatively high (87Sr/86Sr)i values from 0.712231 to 0.712619, low εNd(t) values from −9.56 to −8.99, together with the negative εHf(t) values from −10.8 to −5.0 (mean value −8.9) suggested that the Nuocang granodiorites probably sourced from the partial melting of the ancient Lhasa terrane, with parts of mantle materials involving in. Combined with the previous geochronology and geochemical data of Mesozoic magmas in the Gangdese belt, as well as the Late Jurassic granodiorite, in this paper, we propose that the Nuocang granodiorites formed in a continental margin arc environment triggered by the northward subduction of Neo−Tethys oceanic crust

Petrogenesis of the Late Jurassic Granodiorite and Its Implications for Tectonomagmatic Evolution in the Nuocang District, Western Gangdeses

The Gangdese magmatic rocks of the southern Lhasa terrane, are generally thought to be an important window to witness the formation and evolution of the Neo-Tethys oceanic opening, subduction, and closure, and India-Eurasian continental collision. We investigated a new occurrence of granodiorite in the Nuocang district of western Gangdese, southern Lhasa terrane, and conducted a series of analyses on their petrology, chronology, and geochemistry. The Nuocang granodiorites have the zircon U-Pb ages of 151–154 Ma, which suggest that Late Jurassic granitoids are present in the western Gangdese of southern Lhasa terrane. They are relatively high in SiO2, Al2O3, low K2O, Na2O, and Sr/Y ratios, enrichments of LILE and LREE, and depletion of HFSE, with the positive correlation between Rb and Th, and negative correlations between SiO2 and P2O5, Rb, and Y, showing the features of I-type granites. The relatively high (87Sr/86Sr)i values from 0.712231 to 0.712619, low εNd(t) values from −9.56 to −8.99, together with the negative εHf(t) values from −10.8 to −5.0 (mean value −8.9) suggested that the Nuocang granodiorites probably sourced from the partial melting of the ancient Lhasa terrane, with parts of mantle materials involving in. Combined with the previous geochronology and geochemical data of Mesozoic magmas in the Gangdese belt, as well as the Late Jurassic granodiorite, in this paper, we propose that the Nuocang granodiorites formed in a continental margin arc environment triggered by the northward subduction of Neo−Tethys oceanic crust

Petrogenesis and tectonic setting of Early Cretaceous magmatism in the Jiwa area, central Lhasa Terrane, Tibet

<p>New zircon LA-ICP-MS U–Pb ages, Sr-Nd isotopic data, and whole-rock major and trace element data from Early Cretaceous volcanic rocks are reported for the Jiwa area in the southern central Lhasa Terrane of Tibet. These mainly silicic volcanic rocks and subordinate intermediate-basic volcanic rocks have long been considered to be Pliocene (Wuyu Group) or Eocene (Pana Formation) in age. However, our new zircon U–Pb ages constrain the timing of eruption to the Early Cretaceous (124.6 ± 1.6–126.1 ± 1.1 Ma); thus, we have redefined these volcanic rocks as the Lower Cretaceous Zenong Group. The silicic volcanic rocks feature high-K calc-alkaline to shoshonitic compositions and are mostly strongly peraluminous, rich in Rb, Th, and light rare earth elements (LREEs), and depleted in Nb, Ta, P, and Ti. They are also characterized by negative whole-rock <i>ε</i>Nd(t) values (–9.1 to –13.1) and variable ⁸⁷Sr/⁸⁶Sr ratios. Thus, the geochemical and zircon U–Pb age data of the Jiwa volcanic rocks suggest that these rocks are associated with a continental arc and are mostly likely derived from anatexis of ancient continental crustal material and minor basalt-derived melts. The discovery of Early Cretaceous volcanic rocks in the southern central Lhasa Terrane extends the duration of magmatism triggered by southward subduction of the Bangong-Nujiang oceanic lithosphere from the Late Jurassic to the Early Cretaceous. The spatial distribution of magmatism is also extended 70–80 km to the south. The Lower Cretaceous volcanic rocks in the Jiwa area are proposed to be a result of bi-directional subduction, with southward subduction of the Bangong-Nujiang oceanic crust and northward subduction of the Yarlung Zangbo oceanic crust. The bi-directional subduction of the oceanic lithosphere and gravitational sinking led to slab retreat at ca. 125 Ma. The roll-back of the slab would have then led to back-arc extension and asthenospheric upwelling. The subduction-induced decompression melting of the mantle led to the generation of widespread rhyolitic volcanism with continental arc geochemical signatures.</p

Magma mixing and magmatic-to-hydrothermal fluid evolution revealed by chemical and boron isotopic signatures in tourmaline from the Zhunuo–Beimulang porphyry Cu-Mo deposits

We present coupled textural, elemental, and boron isotopic data of tourmaline from the large Zhunuo–Beimulang collision-related porphyry copper deposits (PCDs) located within the western Gangdese, Tibet. Based on morphology and high-resolution mapping, the tourmaline is classified into three paragenetic generations. The first generation of schorlitic Tur-1 occurs in the monzogranite porphyry as disseminations intergrown with porphyritic K-feldspar and plagioclase. It shows decreasing Fe and Ca and increasing Mg and Al contents from core to rim and has relatively homogeneous δ 11B values (− 9.9 to − 8.6‰); low Fe 3+/(Fe 2+ + Fe 3+), Cu, F, H 2O, and Sr/Y ratios; and high rare earth elements. These features indicate Tur-1 formed in a low fO 2 and metal-poor granitic magma during the pre-mineralization stage. The second generation of porphyritic euhedral Tur-2 is hosted in diorite porphyry enclaves and dikes, where it is intergrown with plagioclase and biotite. It forms part of the schorl-dravite solid solution, with high Fe 3+/(Fe 2+ + Fe 3+), Cu, F, H 2O, Sr/Y, and δ 11B (− 9.7 to − 5.1‰) values. These features indicate it crystallized from a hydrous, oxidized, metal-, and volatile-rich diorite magma. The third generation of Tur-3 is the most volumetrically important and occurs as veinlets and disseminations in the porphyry, or around Tur-1 and Tur-2. It shows radial and oscillatory zoning and is locally intergrown with chalcopyrite and pyrite within the main mineralization assemblage. It has δ 11B values (− 10.5 to − 6.0‰) that overlap with Tur-1 and Tur-2 values. Tur-3 also has variable Fe 3+/(Fe 2+ + Fe 3+), Cu, and volatiles (F and H 2O), indicating it crystallized from oxidized to relatively reducing metal- and volatile-rich hydrothermal fluids. Overall, the three generations of tourmaline show a narrow range of δ 11B values between − 10.5 and − 5.1‰ that are indicative of a single magmatic source. The high Cu, ferric iron, volatiles, and δ 11B values in Tur-2 are interpreted to reflect injection of diorite magma into an open crustal magma storage system that led to the formation of an oxidizing and metal-volatile-rich porphyry system. The three stages of tourmaline formation reflect evolution of the magmatic–hydrothermal system from low fO 2 conditions towards more oxidizing, volatile-rich conditions and then a return to more reducing conditions that accompanied Cu precipitation. Overall, the injection of oxidized metal-rich magma into a long-lived magma reservoir is a critical driving force for the development of collision-related PCDs.</p