Structure of polydisperse inverse ferrofluids: Theory and computer simulation

By using theoretical analysis and molecular dynamics simulations, we investigate the structure of colloidal crystals formed by nonmagnetic microparticles (or magnetic holes) suspended in ferrofluids (called inverse ferrofluids), by taking into account the effect of polydispersity in size of the nonmagnetic microparticles. Such polydispersity often exists in real situations. We obtain an analytical expression for the interaction energy of monodisperse, bidisperse, and polydisperse inverse ferrofluids. Body-centered tetragonal (bct) lattices are shown to possess the lowest energy when compared with other sorts of lattices and thus serve as the ground state of the systems. Also, the effect of microparticle size distributions (namely, polydispersity in size) plays an important role in the formation of various kinds of structural configurations. Thus, it seems possible to fabricate colloidal crystals by choosing appropriate polydispersity in size.Comment: 22 pages, 8 figure

Derivation of the Gauge Link in Light Cone Gauge

In light cone gauge, a gauge link at light cone infinity is necessary for transverse momentum-dependent parton distribution to restore the gauge invariance in some specific boundary conditions. We derive such transverse gauge link in a more regular and general method. We find the gauge link at light cone infinity naturally arises from the contribution of the pinched poles: one is from the quark propagator and the other is hidden in the gauge vector field in light cone gauge. Actually, in the amplitude level, we have obtained a more general gauge link over the hypersurface at light cone infinity which is beyond the transverse direction. The difference of such gauge link between semi-inclusive deep inelastic scattering and Drell-Yan processes can also be obtained directly and clearly in our derivation.Comment: 18 pages, 5 figures, published versio

On the use of an explicit chemical mechanism to dissect peroxy acetyl nitrate formation.

Peroxy acetyl nitrate (PAN) is a key component of photochemical smog and plays an important role in atmospheric chemistry. Though it has been known that PAN is produced via reactions of nitrogen oxides (NOx) with some volatile organic compounds (VOCs), it is difficult to quantify the contributions of individual precursor species. Here we use an explicit photochemical model--Master Chemical Mechanism (MCM) model--to dissect PAN formation and identify principal precursors, by analyzing measurements made in Beijing in summer 2008. PAN production was sensitive to both NOx and VOCs. Isoprene was the predominant VOC precursor at suburb with biogenic impact, whilst anthropogenic hydrocarbons dominated at downtown. PAN production was attributable to a relatively small class of compounds including NOx, xylenes, trimethylbenzenes, trans/cis-2-butenes, toluene, and propene. MCM can advance understanding of PAN photochemistry to a species level, and provide more relevant recommendations for mitigating photochemical pollution in large cities

Casimir effect for the massless Dirac field in two-dimensional Reissner-Nordstr\"{o}m spacetime

In this paper, the two-dimensional Reissner-Nordstr\"{o}m black hole is considered as a system of the Casimir type. In this background the Casimir effect for the massless Dirac field is discussed. The massless Dirac field is confined between two ``parallel plates'' separated by a distance $L$ and there is no particle current drilling through the boundaries. The vacuum expectation values of the stress tensor of the massless Dirac field at infinity are calculated separately in the Boulware state, the Hartle-Hawking state and the Unruh state.Comment: 10 pages, no figure. Accepted for publication in IJMP

Quantum broadcast communication

Broadcast encryption allows the sender to securely distribute his/her secret to a dynamically changing group of users over a broadcast channel. In this paper, we just consider a simple broadcast communication task in quantum scenario, which the central party broadcasts his secret to multi-receiver via quantum channel. We present three quantum broadcast communication schemes. The first scheme utilizes entanglement swapping and Greenberger-Horne-Zeilinger state to realize a task that the central party broadcasts his secret to a group of receivers who share a group key with him. In the second scheme, based on dense coding, the central party broadcasts the secret to multi-receiver who share each of their authentication key with him. The third scheme is a quantum broadcast communication scheme with quantum encryption, which the central party can broadcast the secret to any subset of the legal receivers

Experimental Long-Distance Decoy-State Quantum Key Distribution Based On Polarization Encoding

We demonstrate the decoy-state quantum key distribution (QKD) with one-way quantum communication in polarization space over 102km. Further, we simplify the experimental setup and use only one detector to implement the one-way decoy-state QKD over 75km, with the advantage to overcome the security loopholes due to the efficiency mismatch of detectors. Our experimental implementation can really offer the unconditionally secure final keys. We use 3 different intensities of 0, 0.2 and 0.6 for the pulses of source in our experiment. In order to eliminate the influences of polarization mode dispersion in the long-distance single-mode optical fiber, an automatic polarization compensation system is utilized to implement the active compensation.Comment: 4 pages,3 figure

Isomer-Resolved Mobility-Mass Analysis of alpha-Pinene Ozonolysis Products

Highly oxygenated organic molecules (HOMs) are important sources of atmospheric aerosols. Resolving the molecular-level formation mechanisms of these HOMs from freshly emitted hydrocarbons improves the understanding of aerosol properties and their influence on the climate. In this study, we measure the electrical mobility and mass-to-charge ratio of alpha-pinene oxidation products using a secondary electrospray-differential mobility analyzer-mass spectrometer (SESI-DMA-MS). The mass-mobility spectrum of the oxidation products is measured with seven different reagent ions generated by the electrospray. We analyzed the mobility-mass spectra of the oxidation products C9-10H14-18O2-6. Our results show that acetate and chloride yield the highest charging efficiencies. Analysis of the mobility spectra suggests that the clusters have 1-5 isomeric structures (i.e., ion-molecule cluster structures with distinct mobilities), and the number is affected by the reagent ion. Most of the isomers are likely cluster isomers originating from binding of the reagent ion to different sites of the molecule. By comparing the number of observed isomers and measured mobilities and collision cross sections between standard pinanediol and pinonic acid to the values observed for C10H18O2 and C10H16O3 produced from oxidation of alpha-pinene, we confirm that pinanediol and pinonic acid are the only isomers for these elemental compositions in our experimental conditions. Our study shows that the SESI-DMA-MS produces new information from the first steps of oxidation of alpha-pinene.Peer reviewe

Perovskite and organic solar cells fabricated by inkjet printing: progress and prospects

Inkjet printing (IJP) technology, adapted from home and office printing, has proven to be an essential research tool and industrial manufacturing technique in a wide range of printed electronic technologies, including optoelectronics. Its primary advantage over other deposition methods is the low-cost and maskless on-demand patterning, which offers unmatched freedom-of-design. Additional benefits include the efficient use of materials, contactless high-resolution deposition, and scalability, enabling rapid translation of learning from small-scale, laboratory-based research into large-scale industrial roll-to-roll manufacturing. In the development of organic solar cells (OSCs), IJP has enabled the printing of many of the multiple functional layers which comprise the complete cell as part of an additive printing scheme. Although IJP is only recently employed in perovskite solar cell (PeSC) fabrication, it is already showing great promise and is anticipated to find broader application with this class of materials. As OSCs and PeSCs share many common functional materials and device architectures, this review presents a progress report on the IJP of OSCs and PeSCs in order to facilitate knowledge transfer between the two technologies, with critical analyses of the challenges and opportunities also presented