Synthesis and analysis of jet fuels from shale oil and coal syncrudes

The technical problems involved in converting a significant portion of a barrel of either a shale oil or coal syncrude into a suitable aviation turbine fuel were studied. TOSCO shale oil, H-Coal and COED coal syncrudes were the starting materials. They were processed by distillation and hydrocracking to produce two levels of yield (20 and 40 weight percent) of material having a distillation range of approximately 422 to 561 K (300 F to 550 F). The full distillation range 311 to 616 K (100 F to 650 F) materials were hydrotreated to meet two sets of specifications (20 and 40 volume percent aromatics, 13.5 and 12.75 weight percent H, 0.2 and 0.5 weight percent S, and 0.1 and 0.2 weight percent N). The hydrotreated materials were distilled to meet given end point and volatility requirements. The syntheses were carried out in laboratory and pilot plant equipment scaled to produce thirty-two 0.0757 cu m (2-gal)samples of jet fuel of varying defined specifications. Detailed analyses for physical and chemical properties were made on the crude starting materials and on the products

Observation of a resonant four-body interaction in cold cesium Rydberg atoms

Cold Rydberg atoms subject to long-range dipole-dipole interactions represent a particularly interesting system for exploring few-body interactions and probing the transition from 2-body physics to the many-body regime. In this work we report the direct observation of a resonant 4-body Rydberg interaction. We exploit the occurrence of an accidental quasi-coincidence of a 2-body and a 4-body resonant Stark-tuned Forster process in cesium to observe a resonant energy transfer requiring the simultaneous interaction of at least four neighboring atoms. These results are relevant for the implementation of quantum gates with Rydberg atoms and for further studies of many-body physics.Comment: 5 pages, 5 figure

Near-IR Spectroscopy of a Young Super-Star Cluster in NGC 6946: Chemical Abundances and Abundance Patterns

Using the NIRSPEC spectrograph at Keck II, we have obtained H and K-band echelle spectra for a young (10-15 Myr), luminous (MV=-13.2) super-star cluster in the nearby spiral galaxy NGC 6946. From spectral synthesis and equivalent width measurements we obtain for the first time accurate abundances and abundance patterns in an extragalactic super-star cluster. We find [Fe/H]=-0.45+/-0.08 dex, an average alpha-enhancement of +0.22+/-0.1 dex, and a relatively low 12C/13C~ 8+/-2 isotopic ratio. We also measure a velocity dispersion of ~9.1 km/s, in agreement with previous estimates. We conclude that integrated high-dispersion spectroscopy of massive star clusters is a promising alternative to other methods for abundance analysis in extragalactic young stellar populations.Comment: 5 pages, incl. 2 figures. Accepted for publication in MNRAS Letters. The definitive version will be available at http://www.blackwell-synergy.co

Technology for satellite power conversion

The work is this reporting period was concentrated on electronically calibrating the bolometer detectors. The calibration is necessary for two reasons: first, the power delivered to the rectifying circuit must be known in order to choose a diode with the appropriate barrier height, and second, the power captured by the antenna must be measured if the efficiency of the rectenna is to be divided into antenna efficiency and rectification efficiency. The millimeter wave region operation of the bolometers was simulated with a VHF (10 to 90 MHz) test signal. These detectors are accurate to within roughly 10%. The typical responsivity of the bolometers is 10 volts/watt and the NEP at 20 Hz is 5 times 10 to the minus 9th power W(Hz)-1/2

Technology for satellite power conversion

The work performed in this reporting period has concentrated on the metal-oxide-metal (MOM) diode. The fabrication procedure begins with the deposition of gold probing pads to provide a non-oxidizing contact to test the dc characteristics to the diode accurately. A thin patch capped with an insulating SiO2 layer, is deposited next to form the first half of the diode. The other half of the diode, typically Ni, is deposited completing the conduction path from the oxidized edge of the Ni patch to the opposite gold probing pad. It is important in this step that the last metallization take place without exposing the newly oxidized surface to the atmosphere. Successful production of diodes has been achieved. Work on millimeter wave frequency rectennas incorporating known semiconductor diode technology has been initiated

Technology for satellite power conversion

Components were examined that will be needed for high frequency rectenna devices. The majority of the effort was spent on measuring the directivity and efficiency of the half-wave dipole antenna. It is felt that the antenna and diode should be roughly optimized before they are combined into a rectenna structure. An integrated low pass filter had to be added to the antenna structure in order to facilitate the field pattern measurements. A calculation was also made of the power density of the Earth's radiant energy as seen by satellites in Earth orbit. Finally, the feasibility of using a Metal-Oxide-Metal (MOM) diode for rectification of the received power was assessed

Energy challenges for ICT

The energy consumption from the expanding use of information and communications technology (ICT) is unsustainable with present drivers, and it will impact heavily on the future climate change. However, ICT devices have the potential to contribute signi - cantly to the reduction of CO2 emission and enhance resource e ciency in other sectors, e.g., transportation (through intelligent transportation and advanced driver assistance systems and self-driving vehicles), heating (through smart building control), and manu- facturing (through digital automation based on smart autonomous sensors). To address the energy sustainability of ICT and capture the full potential of ICT in resource e - ciency, a multidisciplinary ICT-energy community needs to be brought together cover- ing devices, microarchitectures, ultra large-scale integration (ULSI), high-performance computing (HPC), energy harvesting, energy storage, system design, embedded sys- tems, e cient electronics, static analysis, and computation. In this chapter, we introduce challenges and opportunities in this emerging eld and a common framework to strive towards energy-sustainable ICT

Solar Flare X-ray Source Motion as a Response to Electron Spectral Hardening

Context: Solar flare hard X-rays (HXRs) are thought to be produced by nonthermal coronal electrons stopping in the chromosphere, or remaining trapped in the corona. The collisional thick target model (CTTM) predicts that sources produced by harder power-law injection spectra should appear further down the legs or footpoints of a flare loop. Therefore, hardening of the injected power-law electron spectrum during flare onset should be concurrent with a descending hard X-ray source. Aims: To test this implication of the CTTM by comparing its predicted HXR source locations with those derived from observations of a solar flare which exhibits a nonthermally-dominated spectrum before the peak in HXRs, known as an early impulsive event. Methods: HXR images and spectra of an early impulsive C-class flare were obtained using the Ramaty High-Energy Solar Spectroscopic Imager (RHESSI). Images were reconstructed to produce HXR source height evolutions for three energy bands. Spatially-integrated spectral analysis was performed to isolate nonthermal emission, and to determine the power-law index of the electron injection spectrum. The observed height-time evolutions were then fit with CTTM-based simulated heights for each energy. Results: A good match between model and observed source heights was reached, requiring a density model that agreed well with previous studies of flare loop densities. Conclusions: The CTTM has been used to produce a descent of model HXR source heights that compares well with observations of this event. Based on this interpretation, downward motion of nonthermal sources should indeed occur in any flare where there is spectral hardening in the electron distribution during a flare. However, this would often be masked by thermal emission associated with flare plasma pre-heating.Comment: 8 pages, 5 figure

Photoionization Rates of Cs Rydberg Atoms in a 1064 nm Far Off-Resonance Trap

Experimental measurements of photoionization rates of $nD_{5/2}$ Rydberg states of Cs ($50 \leq n \leq 75$) in a 1064 nm far off-resonance dipole trap are presented. The photoionization rates are obtained by measuring the lifetimes of Rydberg atoms produced inside of a 1064 nm far off-resonance trap and comparing the lifetimes to corresponding control experiments in a magneto-optical trap. Experimental results for the control experiments agree with recent theoretical predictions for Rydberg state lifetimes and measured photoionization rates are in agreement with transition rates calculated from a model potential.Comment: 12 pages, 4 figure