1,557 research outputs found
Physico-chemical properties of ionic-liquid water mixtures
In order for Ionic Liquids (ILs) to be utilized to their full potential, it is necessary to have a complete understanding of their physical properties, including phase transitions temperatures1.
We have previously reported into the extent of structuring of ILs using photochromic molecular probes, and investigated the appropriate IL water content to yield hydrated IL systems for analysis of polarity and to create environments suitable for effective enzyme activity 1,2,3.
In this study we investigated interactions in hydrated ILs containing variable hydrophobic and hydrophilic regions through optical and thermal analysis. The enthalpies and phase transitions of the systems were compared, between the temperature range -50°C to +30°C for the ILs with varying degrees of hydration. Reichardtʼs dye was used as a molecular probe to monitor changes in interactions in the ILs as a function of temperature. Comparisons were made between ILs and for ILs with varying degrees of hydration. Spectroscopic studies were performed using Perkin Elmer UV-Visible Spectrometer and phase transitions monitored using a Perkin Elmer Differential Scanning Calorimeter.
The ILs examined are; Trihexyltetradecylphosphonium Chloride [P6,6,6,14 Cl] Tributyl-tetradecylphosphonium Chloride, [P4,4,4,14 Cl], 1-Ethyl-methyl-3-imidazolium-ethyl Sulfate [Emim][EtSO4] and Trihexyltetradecylphosphonium Dicyanamide [P6,6,6,14 DCA].
1. Robert Byrne, Simon Coleman, Simon Gallagher, and Dermot Diamond. Designer Molecular Probes for Phosphonium Ionic Liquids. Physical Chemistry Chemical Physics, 2010.
2. Kyoko Fujita, Douglas R. MacFarlane, Maria Forsyth, Masahiro Yoshizawa-Fujita, Kenichi Murata,† Nobuhumi Nakamura, and Hiroyuki Ohno*,Solubility and Stability of Cytochrome c in Hydrated Ionic Liquids: Effect of Oxo Acid Residues and Kosmotropicity, 2007.
3. SergeiV.DzyubaandRichardA.Bartsch,Expandingthepolarityrange of ionic liquids, Tetrehedron Letters, 2002
Clustering of solutions in the random satisfiability problem
Using elementary rigorous methods we prove the existence of a clustered phase
in the random -SAT problem, for . In this phase the solutions are
grouped into clusters which are far away from each other. The results are in
agreement with previous predictions of the cavity method and give a rigorous
confirmation to one of its main building blocks. It can be generalized to other
systems of both physical and computational interest.Comment: 4 pages, 1 figur
Antiproliferative withanolides from several Solanaceous species
This is an Accepted Manuscript of an article published by Taylor & Francis in Natural Product Research in November 2014, available online: http://www.tandfonline.com/10.1080/14786419.2014.919286.To date, our work on Solanaceous species (Datura wrightii, Jaborosa caulescens, Physalis hispida, P. longifolia, Vassobia breviflora, and Withania somnifera) has resulted in the isolation of 65 withanolides, 31 of which were new, as well as the semi-synthesis of a further 30 withanolides. Structure identification and MTS assay-based antiproliferative evaluation of these 95 compounds revealed that a Δ2-1-oxo functionality in ring A; in conjunction with either a 5β,6β-epoxy or 5α-chloro-6β-hydroxy moiety in ring B; are the minimum structural requirements for withanolides to produce potent cytotoxic activity. Such structural-activity relationship analysis (SARA) also revealed that oxygenation (the –OH or –OR groups) at C-4, 7, 11, and 12; as well as C-14 to C-28; did not contribute toward the observed antiproliferative activity. Herein we present a complete overview of our work as it relates to the withanolides reported from 1965 to 2013
Supernovae in Early-Type Galaxies: Directly Connecting Age and Metallicity with Type Ia Luminosity
We have obtained optical spectra of 29 early-type (E/S0) galaxies that hosted
type Ia supernovae (SNe Ia). We have measured absorption-line strengths and
compared them to a grid of models to extract the relations between the
supernova properties and the luminosity-weighted age/composition of the host
galaxies. The same analysis was applied to a large number of early-type field
galaxies selected from the SDSS spectroscopic survey. We find no difference in
the age and abundance distributions between the field galaxies and the SN Ia
host galaxies. We do find a strong correlation suggesting that SNe Ia in
galaxies whose populations have a characteristic age greater than 5 Gyr are ~ 1
mag fainter at V(max) than those found in galaxies with younger populations.
However, the data cannot discriminate between a smooth relation connecting age
and supernova luminosity or two populations of SN Ia progenitors. We find that
SN Ia distance residuals in the Hubble diagram are correlated with host-galaxy
metal abundance, consistent with the predictions of Timmes, Brown & Truran
(2003). The data show that high iron abundance galaxies host less-luminous
supernovae. We thus conclude that the time since progenitor formation primarily
determines the radioactive Ni production while progenitor metal abundance has a
weaker influence on peak luminosity, but one not fully corrected by light-curve
shape and color fitters. Assuming no selection effects in discovering SNe Ia in
local early-type galaxies, we find a higher specific SN Ia rate in E/S0
galaxies with ages below 3 Gyr than in older hosts. The higher rate and
brighter luminosities seen in the youngest E/S0 hosts may be a result of recent
star formation and represents a tail of the "prompt" SN Ia progenitors.Comment: 44 pages, 11 figures, 4 tables; ApJ Accepted (Sept. 20, 2008 issue
Optical and ultraviolet observations of nova Vul 1987
The outburst for a nova discovered in Nov. 1987 and followed since then is summarized. Although it was possible to observe it with the IUE at maximum, its ultraviolet energy faded rapidly, and after the first 2 weeks it was impossible to observe it at IUE wavelengths. It is observed to form a thick dust shell and is in the nebular stage
Withanolides from Jaborosa caulescens var. bipinnatifida
Two new withanolides 2,3-dihydrotrechonolide A (1) and 2,3-dihydro-21-hydroxytrechonolide A (2) were isolated along with two known withanolides trechonolide A (3) and jaborosalactone 39 (4) from Jaborosa caulescens var. bipinnatifida (Solanaceae). The structures of 1-2 were elucidated through 2D NMR and other spectroscopic techniques. In addition, the structure of withanolide 1 was confirmed by X-ray crystallographic analysis
Session, Segmented Session, and Acute RPE and Affective Responses to Self-selected Treadmill Exercise
Please view abstract in the attached PDF file
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