8 research outputs found

    High-performance flexible energy storage and harvesting system for wearable electronics.

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    This paper reports on the design and operation of a flexible power source integrating a lithium ion battery and amorphous silicon solar module, optimized to supply power to a wearable health monitoring device. The battery consists of printed anode and cathode layers based on graphite and lithium cobalt oxide, respectively, on thin flexible current collectors. It displays energy density of 6.98 mWh/cm(2) and demonstrates capacity retention of 90% at 3C discharge rate and ~99% under 100 charge/discharge cycles and 600 cycles of mechanical flexing. A solar module with appropriate voltage and dimensions is used to charge the battery under both full sun and indoor illumination conditions, and the addition of the solar module is shown to extend the battery lifetime between charging cycles while powering a load. Furthermore, we show that by selecting the appropriate load duty cycle, the average load current can be matched to the solar module current and the battery can be maintained at a constant state of charge. Finally, the battery is used to power a pulse oximeter, demonstrating its effectiveness as a power source for wearable medical devices

    Printed complaint Electrochemical Systems

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    Understanding the Effects of Electrode Formulation on the Mechanical Strength of Composite Electrodes for Flexible Batteries

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    Flexible lithium-ion batteries are necessary for powering the next generation of wearable electronic devices. In most designs, the mechanical flexibility of the battery is improved by reducing the thickness of the active layers, which in turn reduces the areal capacity and energy density of the battery. The performance of a battery depends on the electrode composition, and in most flexible batteries, standard electrode formulation is used, which is not suitable for flexing. Even with considerable efforts made toward the development of flexible lithium-ion batteries, the formulation of the electrodes has received very little attention. In this study, we investigate the relation between the electrode formulation and the mechanical strength of the electrodes. Peel and drag tests are used to compare the adhesion and cohesion strength of the electrodes. The strength of an electrode is sensitive to the particle size and the choice of polymeric binder. By optimizing the electrode composition, we were able to fabricate a high areal capacity (∼2 mAh/cm<sup>2</sup>) flexible lithium-ion battery with conventional metal-based current collectors that shows superior electrochemical and mechanical performance in comparison to that of batteries with standard composition

    Charge-integrating organic heterojunction phototransistors for wide-dynamic-range image sensors

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    Solution-processed phototransistors can substantially advance the performance of image sensors. Phototransistors exhibit large photoconductive gain and a sublinear responsivity to irradiance, which enables a logarithmic sensing of irradiance that is akin to the human eye and has a wider dynamic range than photodiode-based image sensors. Here, we present a novel solution-processed phototransistor composed of a heterostructure between a high-mobility organic semiconductor and an organic bulk heterojunction. The device efficiently integrates photogenerated charge during the period of a video frame then quickly discharges it, which significantly increases the signal-To-noise ratio compared with sampling photocurrent during readout. Phototransistor-based image sensors processed without photolithography on plastic substrates integrate charge with external quantum efficiencies above 100% at 100 frames per second. In addition, the sublinear responsivity to irradiance of these devices enables a wide dynamic range of 103 dB at 30 frames per second, which is competitive with state-of-The-Art image sensors
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