Applicability of the photogrammetry technique to determine the volume and the bulk density of small soil aggregates

Aggregate density (¿) is defined as the relationship between the mass and the volume occupied by an aggregate. Previous studies have characterised ¿ on large to medium-sized soil aggregates (>4mm diameter); however, little information is available for smaller aggregates (0.99, P<0.0001) between the volumes estimated on rough stones with the PHM and Archimedes methods demonstrates that this technique can be satisfactorily used to estimate the volume and, consequently, the ¿ of small soil aggregates. The results showed an increase in ¿ with decreasing aggregate size. A general trend of increasing ¿ with the degree of soil disturbance by tillage was also observed

Internal attribution of outcome moderates the cortisol response to a cooperative task in women

Las observaciones etológicas actuales indican que las conductas cooperativas desempeñan un papel adaptativo. En humanos, las situaciones competitivas han sido mayoritariamente investigadas en varones, aunque en escasas ocasiones se ha estudiado la cooperación. Se pretende analizar la respuesta psicológica y del cortisol a una situación cooperativa, en comparación con una competitiva en el laboratorio en mujeres. Se establecieron cuatro grupos en función de la tarea y su resultado: cooperación positiva, cooperación negativa, competición con victoria y competición con derrota. La cooperación produce efectos diferentes en cortisol que la competición, pero no en las variables psicológicas, aunque estos efectos únicamente se producen cuando se considera el resultado y su atribución. Solo las participantes que cooperaron y fueron evaluadas positivamente y las que compitieron y perdieron mostraron descensos signifi cativos de cortisol. La atribución interna se asocia a niveles de cortisol más estables, sugiriendo un efecto modulador de la controlabilidad en la vivencia de la situación. Estos resultados podrían hacerse extensibles a situaciones en las que la negociación, la mediación y las estrategias cooperativas son relevantes para la toma de decisiones y/o resolución de conflictos

The in-plane paraconductivity in La_{2-x}Sr_xCuO_4 thin film superconductors at high reduced-temperatures: Independence of the normal-state pseudogap

The in-plane resistivity has been measured in $La_{2-x}Sr_xCuO_4$ (LSxCO) superconducting thin films of underdoped ($x=0.10,0.12$), optimally-doped ($x=0.15$) and overdoped ($x=0.20,0.25$) compositions. These films were grown on (100)SrTiO$_3$ substrates, and have about 150 nm thickness. The in-plane conductivity induced by superconducting fluctuations above the superconducting transition (the so-called in-plane paraconductivity, $\Delta\sigma_{ab}$) was extracted from these data in the reduced-temperature range 10^{-2}\lsim\epsilon\equiv\ln(T/\Tc)\lsim1. Such a $\Delta\sigma_{ab}(\epsilon)$ was then analyzed in terms of the mean-field--like Gaussian-Ginzburg-Landau (GGL) approach extended to the high-$\epsilon$ region by means of the introduction of a total-energy cutoff, which takes into account both the kinetic energy and the quantum localization energy of each fluctuating mode. Our results strongly suggest that at all temperatures above Tc, including the high reduced-temperature region, the doping mainly affects in LSxCO thin films the normal-state properties and that its influence on the superconducting fluctuations is relatively moderate: Even in the high-$\epsilon$ region, the in-plane paraconductivity is found to be independent of the opening of a pseudogap in the normal state of the underdoped films.Comment: 35 pages including 10 figures and 1 tabl

Mechanistic studies on the: N -alkylation of amines with alcohols catalysed by iridium(i) complexes with functionalised N-heterocyclic carbene ligands

Iridium(i) cyclooctadiene complexes featuring O- and N-donor functionalised NHC ligands efficiently catalyse the C-N coupling of amines with alcohols through a borrowing hydrogen mechanism. These catalysts have been applied for the N-alkylation of several aromatic and aliphatic primary amines with a range of alcohols including benzyl alcohol derivatives, straight-chain primary alcohols and secondary alcohols. The cationic complex [Ir(NCCH3)(cod){MeIm(2-methoxybenzyl)}]+ (cod = 1, 5-cyclooctadiene, MeIm = 3-methylimidazol-2-ylidene) having a rigid O-donor wingtip exhibits the best catalytic performance for the N-alkylation of aniline with benzyl alcohol giving a quantitative conversion to N-benzylaniline in 3 h. Experimental and theoretical studies at the DFT level on the N-alkylation of aniline with benzyl alcohol catalysed by the model compound [IrCl(cod)(IMe)] (IMe = 1, 3-dimethyl-imidazol-2-ylidene) support the participation of the iridium catalyst not only in the alcohol dehydrogenation and imine hydrogenation steps but also in the key step leading to the formation of the new C-N bond. Nucleophilic attack of an iridium-amido species generated in basic medium on the electrophilic aldehyde results in a hemiaminolate intermediate species from which the hemiaminal is released by alcoholysis. The free hemiaminal dehydrates to give the corresponding intermediate imine product that is hydrogenated by the iridium catalyst to the N-alkylated amine product. The iridium(i) complexes featuring functionalised NHC ligands are more active than [IrCl(cod)(IMe)] which highlights the positive influence of the functional group on the N-alkylation catalytic activity

Simultaneous gain and phase profile determination on an interferometric BOTDA

24th International Conference on Optical Fibre Sensors, 96343Y, Curitiba, Brazil, September 28, 2015.Up to now, complex (phase and intensity) measurements in Brillouin Optical Time-Domain Analysis (BOTDA) systems required complex phase modulation methods and high-bandwidth (multi-GHz) detection. In this work, we propose a novel technique that is able to retrieve simultaneously both gain/loss and phase characteristics of the Brillouin interaction by just introducing a Sagnac Interferometer (SI) 011 a standard BOTDA sensing scheme. The technique is described analytically and demonstrated experimentally. With this technique, a reliability increase is produced since redundant measurements can be performed.European CommissionMinisterio de Economía y CompetitividadUniversidad de AlcaláComunidad de MadridGeneralitat Valencian

Towards the characterization of individual users through Web analytics

We perform an analysis of the way individual users navigate in the Web. We focus primarily in the temporal patterns of they return to a given page. The return probability as a function of time as well as the distribution of time intervals between consecutive visits are measured and found to be independent of the level of activity of single users. The results indicate a rich variety of individual behaviors and seem to preclude the possibility of defining a characteristic frequency for each user in his/her visits to a single site.Comment: 8 pages, 4 figures. To appear in Proceeding of Complex'0

The electrical double layer for a fully asymmetric electrolyte around a spherical colloid: an integral equation study

The hypernetted chain/mean spherical approximation (HNC/MSA) integral equation is obtained and solved numerically for a totally asymmetric primitive model electrolyte around a spherical macroparticle. The ensuing radial distribution functions show a very good agreement when compared to our Monte Carlo and molecular dynamics simulations for spherical geometry and with respect to previous anisotropic reference HNC calculations in the planar limit. We report an analysis of the potential vs charge relationship, radial distribution functions, mean electrostatic potential and cumulative reduced charge for representative cases of 1:1 and 2:2 salts with a size asymmetry ratio of 2. Our results are collated with those of the Modified Gouy-Chapman (MGC) and unequal radius Modified Gouy-Chapman (URMGC) theories and with those of HNC/MSA in the restricted primitive model (RPM) to assess the importance of size asymmetry effects. One of the most striking characteristics found is that,\textit{contrary to the general belief}, away from the point of zero charge the properties of an asymmetric electrical double layer (EDL) are not those corresponding to a symmetric electrolyte with the size and charge of the counterion, i.e. \textit{counterions do not always dominate}. This behavior suggests the existence of a new phenomenology in the EDL that genuinely belongs to a more realistic size-asymmetric model where steric correlations are taken into account consistently. Such novel features can not be described by traditional mean field theories like MGC, URMGC or even by enhanced formalisms, like HNC/MSA, if they are based on the RPM.Comment: 29 pages, 13 figure

Sustainable production of graphene-anchored NHC-iridium catalyst for water splitting by using coke-like wastes: Investigation of different chemical synthetic routes

The authors thank the Spanish Ministry of Science and innovation (MICINN) (PID2019-104028RB-I00) and Spanish council for research (icoop program, COOPB22006) for their financial support. Dr. M-González-Ingelmo acknowledges his fellowship from the Asturias regional Government (FICYT, Severo Ochoa Program BP20-168)