10 research outputs found
Conjugated organic framework with three-dimensionally ordered stable structure and delocalized π clouds
Covalent organic frameworks are a class of crystalline organic porous materials that can
utilize p–p-stacking interactions as a driving force for the crystallization of polygonal sheets to
form layered frameworks and ordered pores. However, typical examples are chemically
unstable and lack intrasheet p-conjugation, thereby significantly limiting their applications.
Here we report a chemically stable, electronically conjugated organic framework with topologically
designed wire frameworks and open nanochannels, in which the p conjugation-spans
the two-dimensional sheets. Our framework permits inborn periodic ordering of conjugated
chains in all three dimensions and exhibits a striking combination of properties: chemical
stability, extended p-delocalization, ability to host guest molecules and hole mobility. We
show that the p-conjugated organic framework is useful for high on-off ratio photoswitches
and photovoltaic cells. Therefore, this strategy may constitute a step towards realizing
ordered semiconducting porous materials for innovations based on two-dimensionally
extended p systems.11521611sciescopu
Boron-rich benzene and pyrene derivatives for the detection of thermal neutrons
A synthetic methodology is developed to generate boron rich aromatic small molecules based on benzene and pyrene moieties for the detection of thermal neutrons. The prepared aromatic compounds have a relatively high boron content up to 7.4 wt%, which is important for application in neutron detection as (10)B (20% of natural abundance boron) has a large neutron induced reaction cross-section. This is demonstrated by preparing blends of the synthesized molecules with fluorescent dopants in poly(vinyltoluene) matrices resulting in comparable scintillation light output and neutron capture as state-of-the art commercial scintillators, but with the advantage of much lower cost. The boron-rich benzene and pyrene derivatives are prepared by Suzuki conditions using both microwave and traditional heating, affording yields of 40–93%. This new procedure is simple and straightforward, and has the potential to be scaled up
Evaluation of synthesis conditions for plastic scintillation foils used to measure alpha- and beta-emitting radionuclides
Rational design of crystalline supermicroporous covalent organic frameworks with triangular topologies
Covalent organic frameworks (COFs) are an emerging class of highly ordered porous polymers with many potential applications. They are currently designed and synthesized through hexagonal and tetragonal topologies, limiting the access to and exploration of new structures and properties. Here, we report that a triangular topology can be developed for the rational design and synthesis of a new class of COFs. The triangular topology features small pore sizes down to 12 Å, which is among the smallest pores for COFs reported to date, and high π-column densities of up to 0.25 nm−2, which exceeds those of supramolecular columnar π-arrays and other COF materials. These crystalline COFs facilitate π-cloud delocalization and are highly conductive, with a hole mobility that is among the highest reported for COFs and polygraphitic ensembles
Molecular docking sites designed for the generation of highly crystalline covalent organic frameworks
Designed synthesis of double-stage two-dimensional covalent organic frameworks
Covalent organic frameworks (COFs) are an emerging class of crystalline porous polymers in which organic building blocks are covalently and topologically linked to form extended crystalline polygon structures, constituting a new platform for designing π-electronic porous materials. However, COFs are currently synthesised by a few chemical reactions, limiting the access to and exploration of new structures and properties. The development of new reaction systems that avoid such limitations to expand structural diversity is highly desired. Here we report that COFs can be synthesised via a double-stage connection that polymerises various different building blocks into crystalline polygon architectures, leading to the development of a new type of COFs with enhanced structural complexity and diversity. We show that the double-stage approach not only controls the sequence of building blocks but also allows fine engineering of pore size and shape. This strategy is widely applicable to different polymerisation systems to yield hexagonal, tetragonal and rhombus COFs with predesigned pores and π-arrays