6,494 research outputs found
The effect of Fe atoms on the adsorption of a W atom on W(100) surface
We report a first-principles calculation that models the effect of iron (Fe)
atoms on the adsorption of a tungsten (W) atom on W(100) surfaces. The
adsorption of a W atom on a clean W(100) surface is compared with that of a W
atom on a W(100) surface covered with a monolayer of Fe atoms. The total energy
of the system is computed as the function of the height of the W adatom. Our
result shows that the W atom first adsorbs on top of the Fe monolayer. Then the
W atom can replace one of the Fe atoms through a path with a moderate energy
barrier and reduce its energy further. This intermediate site makes the
adsorption (and desorption) of W atoms a two-step process in the presence of Fe
atoms and lowers the overall adsorption energy by nearly 2.4 eV. The Fe atoms
also provide a surface for W atoms to adsorb facilitating the diffusion of W
atoms. The combination of these two effects result in a much more efficient
desorption and diffusion of W atoms in the presence of Fe atoms. Our result
provides a fundamental mechanism that can explain the activated sintering of
tungsten by Fe atoms.Comment: 9 pages, 2 figure
Solidification characteristics of atomized AlCu4Mg1-SiC composite powders
In this study, rapidly solidified metal matrix composite powders have been produced by PREP (Plasma rotating electrode process) atomization. AlCu4Mg1 alloy is used as the matrix material while SiC particles, with about 650 nm average particle size, are used as the reinforcement phase. The microstructural and solidification characteristics of composite particles are studied using optical and scanning electron microscope (SEM). The relationship between secondary dendrite arm spacing (SDAS) and particle diameter was examined, and these composite powders were found to have dendritic and equiaxed solidification with a fine eutectic phase. SDAS measurements using various sized particles show that secondary dendrite arm spacing slightly decreases with the decrease in particle size
Extension of PRISM by Synthesis of Optimal Timeouts in Fixed-Delay CTMC
We present a practically appealing extension of the probabilistic model
checker PRISM rendering it to handle fixed-delay continuous-time Markov chains
(fdCTMCs) with rewards, the equivalent formalism to the deterministic and
stochastic Petri nets (DSPNs). fdCTMCs allow transitions with fixed-delays (or
timeouts) on top of the traditional transitions with exponential rates. Our
extension supports an evaluation of expected reward until reaching a given set
of target states. The main contribution is that, considering the fixed-delays
as parameters, we implemented a synthesis algorithm that computes the
epsilon-optimal values of the fixed-delays minimizing the expected reward. We
provide a performance evaluation of the synthesis on practical examples
Collaborative Project Development in the Creation of an Interdepartmental Digitization Workflow
Creating workflows that involve the work of multiple departments within a large organization can be challenging, especially when the procedure itself is complex and involves a number of stakeholders. This paper describes and evaluates a collaborative project to develop an interdepartmental workflow for the digitization of unique library materials in a mid-sized academic library. The project includes an automated project management and materials tracking system. Project development involved three separate departments with different reporting channels. In order to navigate this difficulty and manage the large size of the project, a visual planning technique that included graphical representations of current and proposed workflows, as well as implementation timelines, was used. This visual planning technique allowed the project team to clearly organize their thoughts and plans and proved helpful in soliciting buy-in from stakeholders. The paper will outline the collaborative planning process, addressing the rewards and challenges of tackling such a project within a large organization, and present lessons learned for others attempting similar endeavors
Nerd thrill your users: Collaborating with liaisons to create an appealing gateway to digital collections
Purpose – The purpose of this paper is to present a case study in which reference librarians were a
catalyst for an innovative web project designed to market digital collections to students and faculty.
The web project was titled “Image Cafe´” and offered users a taste of the materials available in the
University of Houston Digital Library in an interface and format that was simple to navigate and that
encouraged reuse of the materials, specifically in presentations.
Design/methodology/approach – The approach to this project was a collaborative strategy in
which a team of digital librarians reached out to reference librarians to engage them in more effective
promotion of digital collections to students and faculty. Prior to this project, reference librarians were
an under-utilized stakeholder group whose feedback about the organization and presentation of digital
collections had been difficult to implement. The Image Cafe´ project was an opportunity to pilot ideas
directly from the librarians focused on outreach to students and faculty in an effort to make digital
collections more approachable and discoverable for that audience.
Findings – Based on initial findings, use of Image Cafe´ has been strong and consistently growing.
Originality/value – This paper provides a valuable model for building bridges between groups
within libraries that do not traditionally collaborate in order to make digital collections intuitive and
relevant for users.
Keywords Digital collections, Digital libraries, Collaboration, Web project, Technical services,
Marketing, Promotion of images and photographs, Outreach, Presentation tools, Access
Paper type Case stud
Investigation of extractable organic compounds in deep-sea hydrothermal vent fluids along the Mid-Atlantic Ridge
Author Posting. © The Author(s), 2015. This is the author's version of the work. It is posted here by permission of Elsevier for personal use, not for redistribution. The definitive version was published in Geochimica et Cosmochimica Acta 156 (2015): 122-144, doi:10.1016/j.gca.2015.02.022.The possibility that deep-sea hydrothermal vents may contain organic compounds produced by abiotic synthesis or by microbial communities living deep beneath the surface has led to numerous studies of the organic composition of vent fluids. Most of these studies have focused on methane and other light hydrocarbons, while the possible occurrence of more complex organic compounds in the fluids has remained largely unstudied. To address this issue, the presence of higher molecular weight organic compounds in deep-sea hydrothermal fluids was assessed at three sites along the Mid-Atlantic Ridge that span a range of temperatures (51 to >360 °C), fluid compositions, and host-rock lithologies (mafic to ultramafic). Sample were obtained at several sites within the Lucky Strike, Rainbow, and Lost City hydrothermal fields. Three methods were employed to extract organic compounds for analysis, including liquid:liquid extraction, cold trapping on the walls of a coil of titanium tubing, and pumping fluids through cartridges filled with solid phase extraction (SPE) sorbents. The only samples to consistently yield high amounts of extractable organic compounds were the warm (51-91 °C), highly alkaline fluids from Lost City, which contained elevated concentrations of C8, C10, and C12 n-alkanoic acids and, in some cases, trithiolane, hexadecanol, squalene, and cholesterol. Collectively, the C8-C12 acids can account for about 15% of the total dissolved organic carbon in the Lost City fluids. The even-carbon-number predominance of the alkanoic acids indicates a biological origin, but it is unclear whether these compounds are derived from microbial activity occurring within the hydrothermal chimney proximal to the site of fluid discharge or are transported from deeper within the system. Hydrothermal fluids from the Lucky Strike and Rainbow fields were characterized by an overall scarcity of extractable dissolved organic compounds. Trace amounts of aromatic hydrocarbons including phenanthrenes and benzothiophene were the only compounds that could be identified as indigenous components of these fluids. Although hydrocarbons and fatty acids were observed in some samples, those compounds were likely derived from particulate matter or biomass entrained during fluid collection. In addition, extracts of some fluid samples from the Rainbow field were found to contain an unresolved complex mixture (UCM) of organic compounds. This UCM shared some characteristics with organic matter extracted from bottom seawater, suggesting that the organic matter observed in these samples might represent seawater-derived compounds that had persisted, albeit with partial alteration, during circulation through the hydrothermal system. While there is considerable evidence that Rainbow and Lost City vent fluids contain methane and other light hydrocarbons produced through abiotic reduction of inorganic carbon, we found no evidence for more complex organic compounds with an abiotic origin in the same fluids.This research was supported by the NSF Ocean Sciences directorate through grants MGG-OCE 0550800 to T.M.M. and MGG-OCE 0549829 to J.S.S. and C.R.G
Quality of life as the basis for achieving social welfare of the population
The paper discusses the concept and features of life quality as a socio-economic category. The main signs of quality of life of the population are shown. The analysis of different methodologies to measure indicators of life quality is given. It is shown that the most authoritative measure of the quality of life in the world is the “Human Development Index” (HDI). The main task of authorities at different levels to improve the quality of life of the population is described
Discrimination problems of retirement age employees
It is shown that there is an increasing number of people of retirement age; however, they fac
Radio-frequency dressed lattices for ultracold alkali atoms
Ultracold atomic gases in periodic potentials are powerful platforms for exploring quantum physics in regimes dominated by many-body effects as well as for developing applications that benefit from quantum mechanical effects. Further advances face a range of challenges including the realization of potentials with lattice constants smaller than optical wavelengths as well as creating schemes for effective addressing and manipulation of single sites. In this paper we propose a dressed-based scheme for creating periodic potential landscapes for ultracold alkali atoms with the capability of overcoming such difficulties. The dressed approach has the advantage of operating in a low-frequency regime where decoherence and heating effects due to spontaneous emission do not take place. These results highlight the possibilities of atom-chip technology in the future development of quantum simulations and quantum technologies, and provide a realistic scheme for starting such an exploration
Addition of a dairy fraction rich in milk fat globule membrane to a high-saturated fat meal reduces the postprandial insulinaemic and inflammatory response in overweight and obese adults.
Meals high in SFA, particularly palmitate, are associated with postprandial inflammation and insulin resistance. Milk fat globule membrane (MFGM) has anti-inflammatory properties that may attenuate the negative effects of SFA-rich meals. Our objective was to examine the postprandial metabolic and inflammatory response to a high-fat meal composed of palm oil (PO) compared with PO with an added dairy fraction rich in MFGM (PO+MFGM) in overweight and obese men and women (n 36) in a randomised, double-blinded, cross-over trial. Participants consumed two isoenergetic high-fat meals composed of a smoothie enriched with PO with v. without a cream-derived complex milk lipid fraction ( dairy fraction rich in MFGM) separated by a washout of 1-2 weeks. Serum cytokines, adhesion molecules, cortisol and markers of inflammation were measured at fasting, and at 1, 3 and 6 h postprandially. Glucose, insulin and lipid profiles were analysed in plasma. Consumption of the PO + MFGM v. PO meal resulted in lower total cholesterol (P = 0·021), LDL-cholesterol (P = 0·046), soluble intracellular adhesion molecule (P = 0·005) and insulin (P = 0·005) incremental AUC, and increased IL-10 (P = 0·013). Individuals with high baseline C-reactive protein (CRP) concentrations (≥3 mg/l, n 17) had higher (P = 0·030) insulin at 1 h after the PO meal than individuals with CRP concentrations <3 mg/l (n 19). The addition of MFGM attenuated this difference between CRP groups. The addition of a dairy fraction rich in MFGM attenuated the negative effects of a high-SFA meal by reducing postprandial cholesterol, inflammatory markers and insulin response in overweight and obese individuals, particularly in those with elevated CRP
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