Geospatial simulations of airborne ice-penetrating radar surveying reveal elevation under-measurement bias for ice-sheet bed topography

© The Author(s), 2020. Published by Cambridge University Press. This is an Open Access article, distributed under the terms of the Creative Commons Attribution licence (http://creativecommons.org/licenses/by/4.0/).Airborne radio-echo sounding (RES) surveys are widely used to measure ice-sheet bed topography. Measuring bed topography as accurately and widely as possible is of critical importance to modelling ice dynamics and hence to constraining better future ice response to climate change. Measurement accuracy of RES surveys is influenced both by the geometry of bed topography and the survey design. Here we develop a novel approach for simulating RES surveys over glaciated terrain, to quantify the sensitivity of derived bed elevation to topographic geometry. Furthermore, we investigate how measurement errors influence the quantification of glacial valley geometry. We find a negative bias across RES measurements, where off-nadir return measurement error is typically -1.8 ± 11.6 m. Topographic highlands are under-measured an order of magnitude more than lowlands. Consequently, valley depth and cross-sectional area are largely under-estimated. While overall estimates of ice thickness are likely too high, we find large glacier valley cross-sectional area to be under-estimated by -2.8 ± 18.1%. Therefore, estimates of ice flux through large outlet glaciers are likely too low when this effect is not taken into account. Additionally, bed mismeasurements potentially impact our appreciation of outlet-glacier stability.Peer reviewedFinal Published versio

Microscopic theory of atom-molecule oscillations in a Bose-Einstein condensate

In a recent experiment at JILA [E.A. Donley et al., Nature (London) 417, 529 (2002)] an initially pure condensate of Rb-85 atoms was exposed to a specially designed time dependent magnetic field pulse in the vicinity of a Feshbach resonance. The production of new components of the gas as well as their oscillatory behavior have been reported. We apply a microscopic theory of the gas to identify these components and determine their physical properties. Our time dependent studies allow us to explain the observed dynamic evolution of all fractions, and to identify the physical relevance of the pulse shape. Based on ab initio predictions, our theory strongly supports the view that the experiments have produced a molecular condensate.Comment: 18 pages, 20 figure

Carbon uptake and distribution in Spark Plasma Sintering (SPS) processed Sm(Co, Fe, Cu, Zr)z

Spark Plasma Sintering (SPS) rapidly consolidates high-melting point powders between carbon dies, but carbon can pose a risk for many materials. Carbon uptake in SPS and conventional, pressure-less sintered (CS) Sm(Co, Fe, Cu, Zr)z has been analysed using Electron Probe Micro-Analysis (EPMA) to produce high-detail elemental distribution maps. Field's metal was used as mounting material to avoid introducing carbon into the samples. The distribution maps show high surface carbon levels in the SPS-processed Sm(Co, Fe, Cu, Zr)z to a depth of 10 μm. Much less carbon was observed in CS Sm(Co, Fe, Cu, Zr)z. Furthermore, elemental carbon analysis (LECO-C) confirmed carbon was most abundant at the surface in SPS-processed Sm(Co, Fe, Cu, Zr)z but also at higher levels internally, when compared to the CS sample. It is inferred that the carbon contamination is due to the contact between the powder and the graphite die/paper at elevated temperatures during SPS process. The measured levels of carbon in the SPS-processed sample are not expected to significantly impact the magnetic properties of Sm(Co, Fe, Cu, Zr)z. These results may have implications for other powder materials processed by SPS with properties sensitive to carbon

Comparison of Physical-chemical and Mechanical Properties of Chlorapatite and Hydroxyapatite Plasma Sprayed Coatings

Chlorapatite can be considered a potential biomaterial for orthopaedic applications. Its use as plasma-sprayed coating could be of interest considering its thermal properties and particularly its ability to melt without decomposition unlike hydroxyapatite. Chlorapatite (ClA) was synthesized by a high-temperature ion exchange reaction starting from commercial stoichiometric hydroxyapatites (HA). The ClA powder showed similar characteristics as the original industrial HA powder, and was obtained in the monoclinic form. The HA and ClA powders were plasma-sprayed using a low-energy plasma spraying system with identical processing parameters. The coatings were characterized by physical-chemical methods, i.e. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy, including distribution mapping of the main phases detected such as amorphous calcium phosphate (ACP), oxyapatite (OA), and HA or ClA. The unexpected formation of oxyapatite in ClA coatings was assigned to a side reaction with contaminating oxygenated species (O2, H2O). ClA coatings exhibited characteristics different from HA, showing a lower content of oxyapatite and amorphous phase. Although their adhesion strength was found to be lower than that of HA coatings, their application could be an interesting alternative, offering, in particular, a larger range of spraying conditions without formation of massive impurities.This study was carried out under a MNT ERA-Net Project named NANOMED. The authors gratefully thank the Midi-Pyrénées region (MNT ERA Net Midi-Pyrénées Région, NANOMED2 project) and the Institute National Polytechnique de Toulouse (BQR INPT 2011, BIOREVE project) for supporting this research work, especially the financial support for research carried out in the CIRIMAT and the LGP laboratories (France), and the Basque government and Tratamientos Superficiales Iontech, S.A. for their financial and technical support under the IG-2007/0000381 grant for the development of the LEPS device and deposition of the coatings carried out in Inasmet-Tecnalia. The French industrial collaborators (TEKNIMED SA and 2PS SA) were financed by the OSEO programs