Oxidation of sulphur dioxide in water droplets in the presence of ammonia

SO2 oxidation by oxygen in monodisperse water droplets was studied in a cylindrical chamber, without and in the presence of ammonia. The range of SO2 concentration was from about 1022 to 5 ppmv, while the NH3 input concentration was kept constant at about 4.731022 ppmv. The contact time between gases and droplets was 210 s. The experimental results were compared with the theoretical values predicted by the kinetics of Larson et al. (Atmos. Environ., 12 (1978) 1597) and McKay (Atmos. Environ., 5 (1971) 7). Much higher sulphate concentrations were obtained in experiments run in the presence of NH3, as opposed to those without NH3. The experimental results agree with the values predicted by McKay’s kinetics and are higher than Larson’s

SO2 oxidation in supercooled droplets in the presence of O2

Sulphur dioxide oxidation in supercooled monodisperse droplets at T4213 7C was studied in the presence of oxygen. The SO2 concentration was found to range from 0.08 to 7.1 ppmv and the contact time between gases and droplets was 210 s. The experimental results showed that sulphate concentration due to SO2 oxidation is independent of temperature, i.e. the increase of SO2 solubility in the liquid phase balances the rate constant decrease of the oxidation reaction. Following McKay’s kinetics (Atmos. Environ., 5 (1971) 7), we calculated the rate constant at T4213 7C and the activation energy. A comparison was made between experimental S(VI) oxidation concentrations due to oxygen and theoretical oxidation values due to O3, H2O2 and oxygen in the presence of catalyzers (Fe31, Mn21)

Infinite Randomness Phases and Entanglement Entropy of the Disordered Golden Chain

Topological insulators supporting non-abelian anyonic excitations are at the center of attention as candidates for topological quantum computation. In this paper, we analyze the ground-state properties of disordered non-abelian anyonic chains. The resemblance of fusion rules of non-abelian anyons and real space decimation strongly suggests that disordered chains of such anyons generically exhibit infinite-randomness phases. Concentrating on the disordered golden chain model with nearest-neighbor coupling, we show that Fibonacci anyons with the fusion rule $\tau\otimes\tau={\bf 1}\oplus \tau$ exhibit two infinite-randomness phases: a random-singlet phase when all bonds prefer the trivial fusion channel, and a mixed phase which occurs whenever a finite density of bonds prefers the $\tau$ fusion channel. Real space RG analysis shows that the random-singlet fixed point is unstable to the mixed fixed point. By analyzing the entanglement entropy of the mixed phase, we find its effective central charge, and find that it increases along the RG flow from the random singlet point, thus ruling out a c-theorem for the effective central charge.Comment: 16 page

Entanglement between particle partitions in itinerant many-particle states

We review `particle partitioning entanglement' for itinerant many-particle systems. This is defined as the entanglement between two subsets of particles making up the system. We identify generic features and mechanisms of particle entanglement that are valid over whole classes of itinerant quantum systems. We formulate the general structure of particle entanglement in many-fermion ground states, analogous to the `area law' for the more usually studied entanglement between spatial regions. Basic properties of particle entanglement are first elucidated by considering relatively simple itinerant models. We then review particle-partitioning entanglement in quantum states with more intricate physics, such as anyonic models and quantum Hall states.Comment: review, about 20 pages. Version 2 has minor revisions

Correlation amplitude and entanglement entropy in random spin chains

Using strong-disorder renormalization group, numerical exact diagonalization, and quantum Monte Carlo methods, we revisit the random antiferromagnetic XXZ spin-1/2 chain focusing on the long-length and ground-state behavior of the average time-independent spin-spin correlation function C(l)=\upsilon l^{-\eta}. In addition to the well-known universal (disorder-independent) power-law exponent \eta=2, we find interesting universal features displayed by the prefactor \upsilon=\upsilon_o/3, if l is odd, and \upsilon=\upsilon_e/3, otherwise. Although \upsilon_o and \upsilon_e are nonuniversal (disorder dependent) and distinct in magnitude, the combination \upsilon_o + \upsilon_e = -1/4 is universal if C is computed along the symmetric (longitudinal) axis. The origin of the nonuniversalities of the prefactors is discussed in the renormalization-group framework where a solvable toy model is considered. Moreover, we relate the average correlation function with the average entanglement entropy, whose amplitude has been recently shown to be universal. The nonuniversalities of the prefactors are shown to contribute only to surface terms of the entropy. Finally, we discuss the experimental relevance of our results by computing the structure factor whose scaling properties, interestingly, depend on the correlation prefactors.Comment: v1: 16 pages, 15 figures; v2: 17 pages, improved discussions and statistics, references added, published versio

Fractional Laplacian in Bounded Domains

The fractional Laplacian operator, $-(-\triangle)^{\frac{\alpha}{2}}$, appears in a wide class of physical systems, including L\'evy flights and stochastic interfaces. In this paper, we provide a discretized version of this operator which is well suited to deal with boundary conditions on a finite interval. The implementation of boundary conditions is justified by appealing to two physical models, namely hopping particles and elastic springs. The eigenvalues and eigenfunctions in a bounded domain are then obtained numerically for different boundary conditions. Some analytical results concerning the structure of the eigenvalues spectrum are also obtained.Comment: 11 pages, 11 figure

One-Dimensional Impenetrable Anyons in Thermal Equilibrium. II. Determinant Representation for the Dynamic Correlation Functions

We have obtained a determinant representation for the time- and temperature-dependent field-field correlation function of the impenetrable Lieb-Liniger gas of anyons through direct summation of the form factors. In the static case, the obtained results are shown to be equivalent to those that follow from the anyonic generalization of Lenard's formula.Comment: 16 pages, RevTeX

Entanglement Entropy in the Calogero-Sutherland Model

We investigate the entanglement entropy between two subsets of particles in the ground state of the Calogero-Sutherland model. By using the duality relations of the Jack symmetric polynomials, we obtain exact expressions for both the reduced density matrix and the entanglement entropy in the limit of an infinite number of particles traced out. From these results, we obtain an upper bound value of the entanglement entropy. This upper bound has a clear interpretation in terms of fractional exclusion statistics.Comment: 14 pages, 3figures, references adde

One-dimensional anyons with competing δ\delta-function and derivative δ\delta-function potentials

We propose an exactly solvable model of one-dimensional anyons with competing $\delta$-function and derivative $\delta$-function interaction potentials. The Bethe ansatz equations are derived in terms of the $N$-particle sector for the quantum anyonic field model of the generalized derivative nonlinear Schr\"{o}dinger equation. This more general anyon model exhibits richer physics than that of the recently studied one-dimensional model of $\delta$-function interacting anyons. We show that the anyonic signature is inextricably related to the velocities of the colliding particles and the pairwise dynamical interaction between particles.Comment: 9 pages, 2 figures, minor changes, references update

Supersymmetric Model of Spin-1/2 Fermions on a Chain

In recent work, N=2 supersymmetry has been proposed as a tool for the analysis of itinerant, correlated fermions on a lattice. In this paper we extend these considerations to the case of lattice fermions with spin 1/2 . We introduce a model for correlated spin-1/2 fermions with a manifest N=4 supersymmetry, and analyze its properties. The supersymmetric ground states that we find represent holes in an anti-ferromagnetic background.Comment: 15 pages, 10 eps figure