Light charged Higgs boson production at the Large Hadron electron Collider

We study the production of a light charged Higgs boson at the future Large Hadron electron Collider (LHeC), through the process $e^- p \to \nu_e H^- q$ considering both decay channels $H^- \to b \bar c$ and $H^- \to \tau \bar \nu_\tau$ in the final state. We analyse these processes in the context of the 2-Higgs Doublet Model Type III (2HDM-III) and assess the LHeC sensitivity to such $H^-$ signals against a variety of both reducible and irreducible backgrounds. We confirm that prospects for $H^-$ detection in the 2HDM-III are excellent assuming standard collider energy and luminosity conditions.Comment: 12 pages, 12 figures. Accepted in Physical Review

Submillimeter H2O masers in water-fountain nebulae

We report the first detection of submillimeter water maser emission toward water-fountain nebulae, which are post-AGB stars that exhibit high-velocity water masers. Using APEX we found emission in the ortho-H2O (10_29-9_36) transition at 321.226 GHz toward three sources: IRAS 15445-5449, IRAS 18043-2116 and IRAS 18286-0959. Similarly to the 22 GHz masers, the submillimeter water masers are expanding with a velocity larger than that of the OH masers, suggesting that these masers also originate in fast bipolar outflows. In IRAS 18043-2116 and IRAS 18286-0959, which figure among the sources with the fastest water masers, the velocity range of the 321 GHz masers coincides with that of the 22 GHz masers, indicating that they likely coexist. Towards IRAS 15445-5449 the submillimeter masers appear in a different velocity range, indicating that they are tracing different regions. The intensity of the submillimeter masers is comparable to that of the 22 GHz masers, implying that the kinetic temperature of the region where the masers originate should be Tk > 1000 K. We propose that the passage of two shocks through the same gas can create the conditions necessary to explain the presence of strong high-velocity 321 GHz masers coexisting with the 22 GHz masers in the same region.Comment: 4 pages, 1 figure. Accepted for publication in A&A Letter

Chemical abundances of stars with brown-dwarf companions

It is well-known that stars with giant planets are on average more metal-rich than stars without giant planets, whereas stars with detected low-mass planets do not need to be metal-rich. With the aim of studying the weak boundary that separates giant planets and brown dwarfs (BDs) and their formation mechanism, we analyze the spectra of a sample of stars with already confirmed BD companions both by radial velocity and astrometry. We employ standard and automatic tools to perform an EW-based analysis and to derive chemical abundances from CORALIE spectra of stars with BD companions. We compare these abundances with those of stars without detected planets and with low-mass and giant-mass planets. We find that stars with BDs do not have metallicities and chemical abundances similar to those of giant-planet hosts but they resemble the composition of stars with low-mass planets. The distribution of mean abundances of $\alpha$-elements and iron peak elements of stars with BDs exhibit a peak at about solar abundance whereas for stars with low-mass and high-mass planets the [X$_\alpha$/H] and [X$_{\rm Fe}$/H] peak abundances remain at $\sim -0.1$~dex and $\sim +0.15$~dex, respectively. We display these element abundances for stars with low-mass and high-mass planets, and BDs versus the minimum mass, $m_C \sin i$, of the most-massive substellar companion in each system, and we find a maximum in $\alpha$-element as well as Fe-peak abundances at $m_C \sin i \sim 1.35\pm 0.20$ jupiter masses. We discuss the implication of these results in the context of the formation scenario of BDs in comparison with that of giant planets.Comment: Accepted for publication in Astronomy & Astrophysic

Participación ciudadana en el Ramo 33

Los recursos transferidos a las entidades federativas y municipios a través de los fondos del Ramo 33 representan una fuente primordial de ingresos de los diferentes niveles de gobierno. Sin embargo, ni el Gobierno Federal, ni los gobiernos de los Estados se han puesto de acuerdo en la tarea de elaborar una normatividad completa y precisa para la correcta y adecuada operación del Fondo para la Infraestructura Social Municipal, lo que evidentemente provoca graves problemas en la ejecución de las obras y propicia divergencias entre Gobiernos Estatales y Municipales en la interpretación de la Ley; pero, sobre todo, dificulta el cumplimiento de los objetivos para los cuales fueron creados los fondos, disminuyendo el impacto que se busca en el abatimiento de la pobreza extrema y desalentando incluso, la realización de proyectos y obras de escala regional sustantiva para el desarrollo integral del país. En consecuencia, no se trata solamente de un asunto de finanzas públicas estatales o municipales, sino de un aspecto eminentemente social y político donde la participación ciudadana adquiere y se convierte en una necesidad primordial. Una normatividad completa y precisa en las 32 entidades federativas y de aplicación en la totalidad de los municipios de México, permitiría elevar la calidad de vida de los ciudadanos desde la perspectiva del mejoramiento de las condiciones de la infraestructura social en cada uno de los barrios, colonias y comunidades a lo largo y ancho del territorio nacional

Screening of pesticides and polycyclic aromatic hydrocarbons in feeds and fish tissues by gas chromatography coupled to high-resolution mass spectrometry using atmospheric pressure chemical ionization

This paper reports a wide-scope screening for detection and identification of pesticides and polycyclic aromatic hydrocarbons (PAHs) in feeds and fish tissues. QuEChERS sample treatment was applied, using freezing as an additional cleanup. Analysis was carried out by gas chromatography coupled to hybrid quadrupole time-of-flight mass spectrometry with atmospheric pressure chemical ionization (GC-(APCI) QTOF MS). The qualitative validation was performed for over 133 representative pesticides and 24 PAHs at 0.01 and 0.05 mg/kg. Subsequent application of the screening method to aquaculture samples made it possible to detect several compounds from the target list, such as chlorpyrifos-methyl, pirimiphos-methyl, and ethoxyquin, among others. Light PAHs (≤4 rings) were found in both animal and vegetable samples. The reliable identification of the compounds was supported by accurate mass measurements and the presence of at least two representative m/z ions in the spectrum together with the retention time of the peak, in agreement with the reference standard. Additionally, the search was widened to include other pesticides for which standards were not available, thanks to the expected presence of the protonated molecule and/or molecular ion in the APCI spectra. This could allow the detection and tentative identification of other pesticides different from those included in the validated target list. © 2014 American Chemical Society.This work has been (partly) funded under the EU Seventh Framework Programme by ARRAINA Project 288925: Advanced Research Initiatives for Nutrition and Aquaculture. The views expressed in this work are the sole responsibility of the authors and do not necessarily reflect the views of the European Commission. This work has been developed within the framework of the Research Unit of Marine Ecotoxicology (IATS (CSIC)-IUPA (UJI)). We also acknowledge the financial support of Generalitat Valenciana (research group of excellence PROMETEO/2009/054; ISIC 2012/016).Peer Reviewe

Gibbs Energy Minimization Using Simulated Annealing for Two-phase Equilibrium Calculations in Reactive Systems

Phase equilibrium calculations in systems subject to chemical reactions are involved in the design, synthesis and optimization of reactive separation processes. Until now, several methods have been developed to perform simultaneously physical and chemical equilibrium calculations. However, published methods may face numerical difficulties such as variable initialization dependence, divergence and convergence to trivial solutions or unstable equilibrium states. Besides, these methods generally use conventional composition variables and reactions extents as unknowns which directly affect the numerical implementation, reliability and efficiency of solving strategies. The objective of this work is to introduce and test an alternative approach to perform Gibbs energy minimization in phase equilibrium problems for reactive systems. Specifically, we have employed the transformed composition variables of Ung and Doherty and the stochastic optimization method Simulated Annealing for two-phase equilibrium calculations in reacting systems. Performance of this strategy has been tested using several benchmark problems and results show that proposed approach is generally suitable for the global minimization of transformed Gibbs energy in reactive systems with two-phase equilibrium