Trans-Cis Isomerization And The Blue Phases

A new class of photoactive chiral liquid crystals based on a photoactive nematic host material and a photoinactive chiral dopant was utilized to investigate the behavior of the blues phases when trans-cis isomerization is induced. While the general behavior follows what has been observed in the cholesteric phase, the sensitivity of the blue phases to external parameters causes different behavior when these systems are exposed to UV radiation. The results for four different mixtures are reported and include (1) modulation of the blue phase selective reflection wavelength with low levels of UV and visible light, (2) conversion of one blue phase to another upon exposure to UV light, and (3) induction of blue phases due to UV irradiation when no blue phases are stable beforehand. It is also noted that the supercooled blue phase behaves differently from the other blue phases. All of these results can be understood qualitatively from the ratio of non-nematogenic cis isomers to nematogenic trans isomers and chiral molecules

Wide band gap materials as a new tuning strategy for dye doped cholesteric liquid crystals laser

A new tuning strategy for mirror-less liquid crystals laser is presented. A three layer cell is prepared with two cholesteric layers sandwiching a layer containing an isotropic mixture of a photoluminescent dye. One of the chiral layers contains a wide band gap material while the second layer consists of a series of small band gap materials. Through the combination of these two layers, a set of mirrors that can selectively reflect different wavelengths is obtained. A different laser wavelength is emitted from different regions of the cell under the pumping beam irradiation. (C) 2009 Optical Society of Americ

The Sphaleron Barrier in the Presence of Fermions

We calculate the minimal energy path over the sphaleron barrier in the pre\-sen\-ce of fermions, assuming that the fermions of a doublet are degenerate in mass. This allows for spherically symmetric ans\"atze for the fields, when the mixing angle dependence is neglected. While light fermions have little influence on the barrier, the presence of heavy fermions ($M_F \sim$ TeV) strongly deforms the barrier, giving rise to additional sphalerons for very heavy fermions ($M_F \sim$ 10 TeV). Heavy fermions form non-topological solitons in the vacuum sector.Comment: 19 pages, latex, 18 figures in 3 seperate uuencoded postscript files THU-93/1

The transient process of flexographic printing with parallelink supply

The problem of modeling and transient analysis of flexographic printer’s ink system with parallel ink feeding into the form is enlightened. Printing material has been singled out

Direct measurements of structural forces and twist transitions in cholesteric liquid crystal films with a surface force apparatus

Using a surface force apparatus, a cholesteric liquid crystal was confined between two crossed cylindrical surfaces that induced strong planar anchoring and normal alignment of the chiral helix. The film thickness and total twist angle of the chiral molecular structure were simultaneously measured using multiple-beam optical interference. As the film thickness was increased and the chiral structure deformed, the twist angle remained almost unchanged until discontinuous changes occurred at critical distances that were equally spaced by one cholesteric half-pitch length. Structural deformations generated oscillatory elastic forces with periodically spaced maxima corresponding to twist transitions. These findings were reproduced using an equilibrium model of cholesteric confinement and force generation. The analysis indicates that the strength of the azimuthal surface anchoring on mica is high, exceeding 0.2 mJ m-2

Trans-Cis Isomerization Of An Azoxybenzene Liquid Crystal

Trans-cis isomerization was investigated in a room temperature liquid crystal mixture of two azoxybenzene compounds. Experiments were performed on isolated molecules in dilute solutions and on the liquid crystal phase composed of the pure compounds. The absorption spectra of the trans and cis isomers were found to be similar to those of azobenzene compounds, as were the birefringence and order parameter of the nematic liquid crystal phase. The photo-optic properties were also similar in that irradiation by ultraviolet light caused the conversion from trans to cis isomers, while short wavelength visible light incident on these compounds resulted in the conversion from cis to trans isomers. The activation energy for thermal relaxation from the cis to trans isomer in the liquid crystal phase was determined to be ( 66 +/- 7) kJ/mole, which is less than for azobenzene in solution. While a photostationary state in a dilute solution with approximately equal numbers of trans and cis isomers was achieved, the nematic-isotropic transition of the mixture of the pure compounds decreased from 70 degrees C to room temperature with a cis concentration of only about 12%. One unusual finding was that the photostationary concentration of trans and cis isomers due to irradiation with light of a specific visible wavelength depended on the starting concentrations of the two isomers, indicating that there may be a molecular conformation that is not photo-responsive and relaxes only thermally

Direct measurements of structural forces and twist transitions in cholesteric liquid crystal films with a surface force apparatus

Using a surface force apparatus, a cholesteric liquid crystal was confined between two crossed cylindrical surfaces that induced strong planar anchoring and normal alignment of the chiral helix. The film thickness and total twist angle of the chiral molecular structure were simultaneously measured using multiple-beam optical interference. As the film thickness was increased and the chiral structure deformed, the twist angle remained almost unchanged until discontinuous changes occurred at critical distances that were equally spaced by one cholesteric half-pitch length. Structural deformations generated oscillatory elastic forces with periodically spaced maxima corresponding to twist transitions. These findings were reproduced using an equilibrium model of cholesteric confinement and force generation. The analysis indicates that the strength of the azimuthal surface anchoring on mica is high, exceeding 0.2 mJ m-2