Black Carbon and Organic Components in the Atmosphere of Southern Italy: Comparing Emissions from Different Sources and Production Processes of Carbonaceous Particles

Initial measurements of black carbon (BC) content at both 880 and 370 nm, obtained in two sites in southern Italy by an aethalometer, have been analyzed. The sites are located in the same region (Basilicata), but are affected by different emission sources. In one case the main source of BC is related to vehicular traffic from a nearby freeway. Data were collected, although not continuously, during 2008, 2009 and 2010. In the second case, a fresh crude-oil pre-treatment plant continuously burns petroleum-derived products, thus contributing to emissions of both carbonaceous matter and its organic component. The corresponding data-set was collected in the period January–April 2011. At the first site, two daily peaks were found for the BC content, typical of vehicles emissions, with maximum values ranging from 2000 ng/m3 to 4700 ng/m3 found during weekdays. This behavior disappears at the weekend or when polluted air-masses from north-east Europe are transported over the measurement site. At the second site, two daily peaks were never found, suggesting that crude oil chemical processes were the main source of the emissions. In this case, the maximum BC values ranged between 1000–8000 ng/m3, depending on the processes occurring at the fresh crude-oil pre-treatment plant. Moreover, the estimated level of BC at 370 nm was higher than that of BC at 880 nm in all months, expect for April, indicating a clear organic component in atmospheric aerosols. Finally, based on a best-fit procedure applied to the seven wavelengths’ absorption coefficients, aerosols with different spectroscopic properties have been detected at these two sites

Physical and optical properties of atmospheric aerosols by in-situ and radiometric measurements

Physical and optical properties of atmospheric aerosols collected by using a high resolution (1.5 nm) spectroradiometer (spectral range 400–800 nm), a 13-stage Dekati Low Pressure Impactor (size range 30 nm–10 μm), and an AE31 Aethalometer (7 wavelenghts from 370 nm to 950 nm), have been examined in a semi-rural site in Southwest Italy (Tito Scalo, 40°35' N, 15°41' E, 750 m a.s.l.). In particular, daily averaged values of AOD and Ångström turbidity parameters from radiometric data together with mass-size distributions from impactor data and Black Carbon (BC) concentrations have been analyzed from May to October 2008. Furthermore, by inverting direct solar radiances, aerosol columnar number and volume size distributions have been obtained for the same period. The comparison of different observation methods, allowed to verify if, and in what conditions, changes in aerosol properties measured at ground are representative of columnar properties variations. Agreement between columnar and in-situ measurements has been obtained in case of anthropogenic aerosol loading, while in case of Saharan dust intrusions some discrepancies have been found when dust particles were located at high layers in the atmosphere (4–8 km) thus affecting columnar properties more than surface ones. For anthropogenic aerosols, a good correlation has been confirmed through the comparison of fine aerosol fraction contribution as measured by radiometer, impactor and aethalometer, suggesting that, in this case, the particles are more homogeneously distributed over the lower layers of atmosphere and columnar aerosol optical properties are dominated by surface measured component

A state-space partitioned time integration algorithm for real-time hybrid simulation with nonlinear numerical subdomains

This paper describes a state-space partitioned algorithm for real-time hybrid simulation. The state-space modeling is proposed to represent nonlinear numerical substructures. The effectiveness of the proposed method is demonstrated for a virtual bridge case study equipped with seismic isolation devices

A new algorithm for brown and black carbon identification and organic carbon detection in fine atmospheric aerosols by a multi-wavelength Aethalometer

A novel approach for the analysis of aerosol absorption coefficient measurements is presented. A 7-wavelenghts aethalometer has been employed to identify brown carbon (BrC) and black carbon (BC) and to detect organic carbon (OC) in fine atmospheric aerosols (PM2.5). The Magee Aethalometer estimates the BC content in atmospheric particulate by measuring the light attenuation in the aerosols accumulated on a quartz filter, at the standard wavelength λ = 0.88 μm. The known Magee algorithm is based on the hypothesis of a mass absorption coefficient inversely proportional to the wavelength. The new algorithm has been developed and applied to the whole spectral range; it verifies the spectral absorption behavior and, thus, it distinguishes between black and brown carbon. Moreover, it allows also to correct the absorption estimation at the UV wavelength commonly used to qualitatively detect the presence of mixed hydrocarbons. The algorithm has been applied to data collected in Agri Valley, located in Southern Italy, where torched crude oil undergoes a pre-treatment process. The Magee Aethalometer has been set to measure Aerosol absorption coefficients τaer (λ, t) every 5 min. Wavelength dependence of τaer (λ, t) has been analyzed by a best-fit technique and, excluding UV-wavelengths, both the absorption Angstrom coefficient α and the BC (or BrC) concentration have been determined. Finally, daily histograms of α provide information on optical properties of carbonaceous aerosol, while the extrapolation at UV-wavelengths gives information on the presence of semivolatile organic carbon (OC) particles

ORBIT CODES FROM FORMS ON VECTOR SPACES OVER A FINITE FIELD

In this paper we construct different families of orbit codes in the vector spaces of the symmetric bilinear forms, quadratic forms and Hermitian forms on an n-dimensional vector space over the finite field Fq. All these codes admit the general linear group GL(n, q) as a transitive automorphism group

Vapor etching to avoid micro-masking by gas-bubbles in wet release of MEMS

We report on the formation of gas bubbles during the release of MEMS devices using buffered oxide etch. Several approaches to mitigate the problem are proposed and tested together with a qualitative study of the phenomenon. The chemical reaction behind such phenomenon and the influence of defects and topography is discussed. Finally, a comparison with the HF-vapor release technique is shown

Locus coeruleus modulates neuroinflammation in parkinsonism and dementia

Locus Coeruleus (LC) is the main noradrenergic nucleus of the central nervous system, and its neurons widely innervate the whole brain. LC is severely degenerated both in Alzheimer’s disease (AD) and in Parkinson’s disease (PD), years before the onset of clinical symptoms, through mechanisms that differ among the two disorders. Several experimental studies have shown that noradrenaline modulates neuroinflammation, mainly by acting on microglia/astrocytes function. In the present review, after a brief introduction on the anatomy and physiology of LC, we provide an overview of experimental data supporting a pathogenetic role of LC degeneration in AD and PD. Then, we describe in detail experimental data, obtained in vitro and in vivo in animal models, which support a potential role of neuroinflammation in such a link, and the specific molecules (i.e., released cytokines, glial receptors, including pattern recognition receptors and others) whose expression is altered by LC degeneration and might play a key role in AD/PD pathogenesis. New imaging and biochemical tools have recently been developed in humans to estimate in vivo the integrity of LC, the degree of neuroinflammation, and pathology AD/PD biomarkers; it is auspicable that these will allow in the near future to test the existence of a link between LC-neuroinflammation and neurodegeneration directly in patients

The degeneration of locus coeruleus occurring during Alzheimer’s disease clinical progression: a neuroimaging follow-up investigation

\ua9 The Author(s) 2024.The noradrenergic nucleus Locus Coeruleus (LC) is precociously involved in Alzheimer’s Disease (AD) pathology, and its degeneration progresses during the course of the disease. Using Magnetic Resonance Imaging (MRI), researchers showed also in vivo in patients the disruption of LC, which can be observed both in Mild Cognitively Impaired individuals and AD demented patients. In this study, we report the results of a follow-up neuroradiological assessment, in which we evaluated the LC degeneration overtime in a group of cognitively impaired patients, submitted to MRI both at baseline and at the end of a 2.5-year follow-up. We found that a progressive LC disruption can be observed also in vivo, involving the entire nucleus and associated with clinical diagnosis. Our findings parallel neuropathological ones, which showed a continuous increase of neuronal death and volumetric atrophy within the LC with the progression of Braak’s stages for neurofibrillary pathology. This supports the reliability of MRI as a tool for exploring the integrity of the central noradrenergic system in neurodegenerative disorders