Air/methane mixture ignition with Multi-Walled Carbon Nanotubes (MWCNTs) and comparison with spark ignition

The possibility to ignite the single wall carbon nanotubes (SWCNTs) containing impurities of iron in atmosphere once exposed to the radiation of a flash camera was observed for the first time in 2002. Afterwards, it was proposed to exploit this property in order to use nanostructured materials as ignition agents for fuel mixtures. Finally, in 2011 it was shown that SWCNTs can be effectively used as ignition source for an air/ethylene mixture filling a constant volume combustion chamber; the observed combustion presented the characteristics of a homogeneous-like combustion. In this paper a system for the ignition of an air/methane mixture is proposed, based on the exposition of multi wall carbon nanotubes (MWCNTs) to a low consumption flash camera. Namely, several experiments have been run in which 20 mg of MWCNTs, containing 75% in weight of ferrocene, have been added to an air/methane fuel mixture inside a constant volume combustion chamber. The mixture has been heated up to 373 K and the onset pressure was set equal to 3 bar. The experiments have been run varying the equivalence ratio in the range 1–2. The combustion process so realized has been compared to that obtained igniting the mixture with a traditional spark as in spark ignition engines. The comparison has been based on chamber pressure measurement as well as combustion process images, both sampled at a frequency equal to 2,5 kHz for an overall duration of 1.8 s. Results confirm that the ignition triggered with MWCNTs leads to a homogeneous-like combustion, without observing a well-defined flame front propagation. The contrary is observed, as expected, with the spark assisted ignition. Moreover, dynamic pressure measurements show that, compared to spark assisted ignition, the MWCNTs photo-ignition determines a more rapid pressure gradient and a higher peak pressure which corresponds to a higher energy release rate

Analysis and performance assessment of the use of ammonia-based nano additive for lean combustion

In recent years, considerable progress has been made in exploring new applications of fuel additives to reduce emissions. Reduction of total nitrogen oxide (NOx) emissions can be achieved by decreasing the flame temperature by using fuel emulsified with water and/or using ammonia-based nano additives such as urea. The use of water as part of the hydrocarbon fuel is also one of the prospective directions in the development of new types of fuel systems. For the preparation of emulsified fuel, it is desirable to achieve greater stability of the emulsified fuel with minimum expenditure of chemicals and energy, so that the emulsified fuel can be used for a longer period. The paper analyzed the influence of nano-dispersed urea particles, water, and surfactant (Span 80/ Tween 80) on the combustion stability and emission characteristics of aviation fuel. The experimental campaign was conducted on a test stand (a 300kW liquid vortex combustor of 300 kW) consisting of a cylindrical combustion chamber with four optical windows and equipped with high-precision pressure sensors, thermocouples, and an exhaust gas analyzer for acquiring emissions. The experimental campaign was conducted at a constant fuel/air ratio (Φ). One of the main focus is related to the stability of the emulsion. Chemiluminescence imaging was performed to characterize the effects of the additive on flame emissions. In addition, a statistical and spectral analysis was performed using the pressure sensor for instability analysis. Exhaust gas analysis was performed both with the additive described above and without additive for a constant Φ condition. The analysis was performed for NOx, carbon monoxide (CO) and carbon dioxide (CO2) and oxygen (O 2)

Microwave-Assisted Treatment of Waste Wood Biomass with Deep Eutectic Solvents

Abstract. The increasing depletion of fossil feeds and the environmental concerns linked to the use of traditional energy sources have stimulated both academic and industrial worlds in exploiting new sustainable and renewable suppliers of raw materials [1]. In this framework, lignocellulosic biomass can play an important role, acting as the starting material of a biorefinery leading to biofuels, chemicals, and other value-added products, commonly obtained from petroleum. Recently, numerous protocols for processing lignocellulosic biomass of selected plants have been reported. However, developing an environment-friendly method is still a big goal. This challenge becomes more interesting if lignocellulosic biomass coming from wood wastes could be efficiently treated. Deep eutectic solvents (DESs) are new sustainable and cheap reaction media, combining the features of ionic liquids and organic solvents. They are made by association of hydrogen-bond donors and hydrogen-bond acceptors, and they can promote the hydrolysis of lignocellulosic bonds [2]. Herein, we report on the microwave-assisted treatment of waste wood flours with DESs formed by choline chloride and oxalic acid to get a cellulosic residue separated from lignin degradation products, identified by NMR spectroscopy. The insoluble deposit was characterized by SEM, TGA, DSC, FTIR-ATR and 13C CP/MAS NMR techniques and could be available for further uses such as nanocellulose production. [1] Haldar D., Purkait M.K. Chemosphere 2021, 128523. [2] Liu S., Zhang Q., Gou S., Zhang L., Wang Z. Carbohydr. Polym. 2021, 251, 11701

CaCO3 as an environmentally friendly renewable material for drug delivery systems: Uptake of HSA-CaCO3 nanocrystals conjugates in cancer cell lines

Chemical and biochemical functionalization of nanoparticles (NPs) can lead to an active cellular uptake enhancing their efficacy thanks to the targeted localization in tumors. In the present study calcium carbonate nano-crystals (CCNs), stabilized by an alcohol dehydration method, were successfully modified by grafting human serum albumin (HSA) on the surface to obtain a pure protein corona. Two types of CCNs were used: naked CaCO3 and the (3-aminopropyl)triethoxysilane (APTES) modified CaCO3-NH2. The HSA conjugation with naked CCN and amino-functionalized CCN (CCN-NH2) was established through the investigation of modification in size, zeta potential, and morphology by Transmission Electron Microscopy (TEM). The amount of HSA coating on the CCNs surface was assessed by spectrophotometry. Thermogravimetric analysis (TGA) and Differential scanning calorimetry (DSC) confirmed the grafting of APTES to the surface and successive adsorption of HSA. Furthermore, to evaluate the effect of protein complexation of CCNs on cellular behavior, bioavailability, and biological responses, three human model cancer cell lines, breast cancer (MCF7), cervical cancer (HeLa), and colon carcinoma (Caco-2) were selected to characterize the internalization kinetics, localization, and bio-interaction of the protein-enclosed CCNs. To monitor internalization of the various conjugates, chemical modification with fluorescein-isothiocyanate (FITC) was performed, and their stability over time was measured. Confocal microscopy was used to probe the uptake and confirm localization in the perinuclear region of the cancer cells. Flow cytometry assays confirmed that the bio-functionalization influence cellular uptake and the CCNs behavior depends on both cell line and surface features

HPLC-HRMS Global Metabolomics Approach for the Diagnosis of “Olive Quick Decline Syndrome” Markers in Olive Trees Leaves

Olive quick decline syndrome (OQDS) is a multifactorial disease affecting olive plants. The onset of this economically devastating disease has been associated with a Gram-negative plant pathogen called Xylella fastidiosa (Xf). Liquid chromatography separation coupled to high-resolution mass spectrometry detection is one the most widely applied technologies in metabolomics, as it provides a blend of rapid, sensitive, and selective qualitative and quantitative analyses with the ability to identify metabolites. The purpose of this work is the development of a global metabolomics mass spectrometry assay able to identify OQDS molecular markers that could discriminate between healthy (HP) and infected (OP) olive tree leaves. Results obtained via multivariate analysis through an HPLC-ESI HRMS platform (LTQ-Orbitrap from Thermo Scientific) show a clear separation between HP and OP samples. Among the differentially expressed metabolites, 18 different organic compounds highly expressed in the OP group were annotated; results obtained by this metabolomic approach could be used as a fast and reliable method for the biochemical characterization of OQDS and to develop targeted MS approaches for OQDS detection by foliage analysis

Uranium and thorium in lamprophyres of the Altai-Sayan folded region

The work is devoted to the study of lamprophyres of the Altai-Sayan region. According to X-ray phase analysis, these rocks have a complex mineral composition. According to the TAS diagram, the petrochemical composition varies from alkaline picrites to trachytes. As the INAA shows, the studied samples are significantly enriched with thorium and uranium. Combining the method of electron microscopy and fission radiography (f-radiography), the occurrence forms of thorium and uranium were studied, therefore concentrating minerals were identified

Biology-inspired photocatalysis: Recent advances in biomimetic photocatalytic nanosystems synthesis and applications

Nature offers interesting structures and chemicals for photochemistry and photocatalysis. Therefore, highly performing photocatalysts have been derived with improved morphology, photoadsorption, energy transfer, and photostability. Different green synthesis methods have been developed employing phytochemicals, biotemplates, and bioreactors. Smart natural hierarchical structures and enzyme-like materials have been faithfully reproduced providing unique physico-chemical proprieties and constructing artificial photosynthesis. Hybridization with natural pigments and polymers has been investigated, obtaining a new class of heterogenous nano-photocatalysts with improved dispersibility and efficacy. A biology-inspired approach has expanded the spectrum of photocatalysis applications carrying out increasingly biocompatible and effective systems for bioremediation, active food packaging, and nanomedicine

The Augmented State System Approach to the Discretization of Continuous Dynamic Systems

We present the continuous-discrete dynamic system approximation (often referred to as discretization) criterion based on the Augmented State System (ASS) approach [1,2], and show its effectiveness in designing digital filters [4] and digital model reference adaptive controllers (DMRAC) [3,5,6,7,8,9,10,11]. We also comment how our method performs better than the ones widely found in literature

Derivati di 1-(alfa-amminobenzil) -2 -naftolo o base di betti procedimento per la loro preparazione e per la loro risoluzione ottica

A detailed protocol for the resolution of the Betti base [i.e. 1-(-aminobenzyl)-2-naphthol] was investigated and the absolute configuration of the two isomers was established by means of an X-ray diffractometric study. A series of optically active derivatives was also prepared. The list includes the N-benzyl- and the N,N,O-trimethyl derivatives. The N,N-dimethyl derivative was prepared in racemic form by means of the Betti reaction and was resolved into the two enantiomers with an extremely easy and efficient procedure. The O-methyl derivative was prepared in a racemic form and subjected to resolution