990 research outputs found
Orbital Ordering and Spin-Ladder Formation in La2RuO5
The semiconductor-semiconductor transition of La2RuO5 is studied by means of
augmented spherical wave (ASW) electronic structure calculations as based on
density functional theory and the local density approximation. This transition
has lately been reported to lead to orbital ordering and a quenching of the
local spin magnetic moment. Our results hint towards an orbital ordering
scenario which, markedly different from the previously proposed scheme,
preserves the local S = 1 moment at the Ru sites in the low-temperature phase.
The unusual magnetic behaviour is interpreted by the formation of spin-ladders,
which result from the structural changes occurring at the transition and are
characterized by antiferromagnetic coupling along the rungs.Comment: 5 pages, 4 figures, for more information see
http://www.physik.uni-augsburg.de/~eyert
Non-intrinsic origin of the Colossal Dielectric Constants in CaCu3Ti4O12
The dielectric properties of CaCu3Ti4O12, a material showing colossal values
of the dielectric constant, were investigated in a broad temperature and
frequency range extending up to 1.3 GHz. A detailed equivalent circuit analysis
of the results and two crucial experiments, employing different types of
contacts and varying sample thickness, provide clear evidence that the
apparently high values of the dielectric constant in CaCu3Ti4O12 are
non-intrinsic and due to electrode polarization effects. The intrinsic
properties of CaCu3Ti4O12 are characterized by charge transport via hopping of
localized charge carriers and a relatively high dielectric constant of the
order of 100.Comment: 4 pages, 4 figure
Broadband dielectric response of CaCu3Ti4O12: From dc to the electronic transition regime
We report on phonon properties and electronic transitions in CaCu3Ti4O12, a
material which reveals a colossal dielectric constant at room temperature
without any ferroelectric transition. The results of far- and mid-infrared
measurements are compared to those obtained by broadband dielectric and
millimeter-wave spectroscopy on the same single crystal. The unusual
temperature dependence of phonon eigenfrequencies, dampings and ionic plasma
frequencies of low lying phonon modes are analyzed and discussed in detail.
Electronic excitations below 4 eV are identified as transitions between full
and empty hybridized oxygen-copper bands and between oxygen-copper and
unoccupied Ti 3d bands. The unusually small band gap determined from the
dc-conductivity (~200 meV) compares well with the optical results.Comment: 7 pages, 8 figure
Dielectric behavior of Copper Tantalum Oxide
A thorough investigation of the dielectric properties of Cu2Ta4O12, a
material crystallizing in a pseudo-cubic, perovskite-derived structure is
presented. We measured the dielectric constant and conductivity of single
crystals in an exceptionally broad frequency range up to GHz frequencies and at
temperatures from 25 - 500 K. The detected dielectric constant is unusually
high (reaching values up to 105) and almost constant in a broad frequency and
temperature range. Cu2Ta4O12 possesses a crystal structure similar to
CaCu3Ti4O12, the compound for which such an unusually high dielectric constant
was first observed. An analysis of the results using a simple equivalent
circuit and measurements with different types of contact revealed that
extrinsic interfacial polarization effects, derived from surface barrier
capacitors are the origin of the observed giant dielectric constants. The
intrinsic properties of Cu2Ta4O12 are characterized by a (still relatively
high) dielectric constant in the order of 100 and by charge transport via
hopping conduction of Anderson-localized charge carriers.Comment: 18 pages, 6 figures, submitted to Jouranl of Physical Chemestr
Broadband dielectric spectroscopy on single-crystalline and ceramic CaCu3Ti4O12
We present dielectric measurements of the colossal dielectric constant
material CaCu3Ti4O12 extending up to 1.3 GHz also covering so far only rarely
investigated single crystalline samples. Special emphasis is put on the second
relaxation reported in several works on polycrystals, which we detect also in
single crystals. For polycrystalline samples we provide a recipe to achieve
values of the dielectric constant as high as in single crystals.Comment: 3 pages, 3 figure
Metal-to-insulator transition and magnetic ordering in CaRu_{1-x}Cu_xO_3
CaRuO_3 is perovskite with an orthorhombic distortion and is believed to be
close to magnetic ordering. Magnetic studies of single crystal and
polycrystalline CaRu_{1-x}Cu_xO_3 (0\le x \le 15 at.%Cu) reveal that
spin-glass-like transition develops for x\le 7 at.%Cu and obtained value for
effective magnetic moment p_{eff}=3.55 mu_B for x=5 at.% Cu, single crystal,
indicates presence of Ru^{5+}. At higher Cu concentrations more complex
magnetic behaviors are observed. Electrical resistivity measured on
polycrystalline samples shows metal-to-insulator transition (MIT) at 51 K for
only 2 at.% Cu. Charge compensation, which is assumed to be present upon
Cu^{2+/3+} substitution, induces appearance of Ru^{5+} and/or creation of
oxygen vacancies in crystal structure. Since the observed changes in physical
properties are completely attributable to the charge compensation, they cannot
be related to behaviors of pure compound where no such mechanism is present.
This study provides the criterion for "good" chemical probes for studying
Ru-based perovskites.Comment: 12 pages, 7 figure
CaCu3Ti4O12 single crystals: insights on growth and nanoscopic investigation
The combination of scanning impedance microscopy and conductive atomic force microscopy was
applied to single crystals of the perovskite-type oxide CaCu3Ti4O12 (CCTO) in order to provide a local
dielectric characterization on ingot sections. Both techniques clearly showed dielectric heterogeneities
due to the presence of inclusions within crystals grown in different laboratories. Despite macroscopic
characterizations, such as Laue diffraction, gave no indications for the presence of inclusions within the
crystals, the discovery of dielectric heterogeneities prompted a careful structural analysis, which
revealed the presence of crystalline CaTiO3 (CTO) precipitates. Thus, the scanning probe investigation
provided the evidence for the electrical homogeneity within the CCTO crystal and the presence of
internal barriers due to the CCTO/CTO interfaces
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