3,305 research outputs found
Plume mapping and isotopic characterisation of anthropogenic methane sources
Methane stable isotope analysis, coupled with mole fraction measurement, has been used to link isotopic signature to methane emissions from landfill sites, coal mines and gas leaks in the United Kingdom. A mobile Picarro G2301 CRDS (Cavity Ring-Down Spectroscopy) analyser was installed on a vehicle, together with an anemometer and GPS receiver, to measure atmospheric methane mole fractions and their relative location while driving at speeds up to 80 kph. In targeted areas, when the methane plume was intercepted, air samples were collected in Tedlar bags, for delta C-13-CH4 isotopic analysis by CF-GC-IRMS (Continuous Flow Gas Chromatography-Isotope Ratio Mass Spectrometry). This method provides high precision isotopic values, determining delta C-13-CH4 to +/- 0.05 per mil. The bulk signature of the methane plume into the atmosphere from the whole source area was obtained by Keeling plot analysis, and a delta C-13 -CH4 signature, with the relative uncertainty, allocated to each methane source investigated. Both landfill and natural gas emissions in SE England have tightly constrained isotopic signatures. The averaged delta C-13-CH4 for landfill sites is -58 +/- 3%o. The delta C-13-CH4 signature for gas leaks is also fairly constant around -36 +/- 2 parts per thousand, a value characteristic of homogenised North Sea supply. In contrast, signatures for coal mines in N. England and Wales fall in a range of -51.2 +/- 0.3 parts per thousand to 30.9 +/- 1.4 parts per thousand, but can be tightly constrained by region. The study demonstrates that CRDS-based mobile methane measurement coupled with off-line high precision isotopic analysis of plume samples is an efficient way of characterising methane sources. It shows that iiotopic measurements allow type identification, and possible location of previously unknown methane sources. In modelling studies this measurement provides an independent constraint to determine the contributions of different sources to the regional methane budget and in the verification of inventory source distribution. (C) 2015 Elsevier Ltd. All rights reserved
Quantum calculations of Coulomb reorientation for sub-barrier fusion
Classical mechanics and Time Dependent Hartree-Fock (TDHF) calculations of
heavy ions collisions are performed to study the rotation of a deformed nucleus
in the Coulomb field of its partner. This reorientation is shown to be
independent on charges and relative energy of the partners. It only depends
upon the deformations and inertias. TDHF calculations predict an increase by
30% of the induced rotation due to quantum effects while the nuclear
contribution seems negligible. This reorientation modifies strongly the fusion
cross-section around the barrier for light deformed nuclei on heavy collision
partners. For such nuclei a hindrance of the sub-barrier fusion is predicted.Comment: accepted for publication in Physical Review Lette
Contextual factors among indiscriminate or larger attacks on food or water supplies, 1946-2015
This research updates previous inventories of malicious attacks on food and water to include data from 1946 through mid-2015. A systematic search of news reports, databases and previous inventories of poisoning events was undertaken. Incidents that threatened or were intended to achieve direct harm to humans, and that were either relatively large (number of victims > 4 or indiscriminate in intent or realisation were included. Agents could be chemical, biological or radio-nuclear. Reports of candidate incidents were subjected to systematic inclusion and exclusion criteria as well as validity analysis (not always clearly undertaken in previous inventories of such attacks). We summarise contextual aspects of the attacks that may be important for scenario prioritisation, modelling and defensive preparedness. Opportunity is key to most realised attacks, particularly access to dangerous agents. The most common motives and relative success rate in causing harm were very different between food and water attacks. The likelihood that people were made ill or died also varied by food/water mode, and according to motive and opportunity for delivery of the hazardous agent. Deaths and illness associated with attacks during food manufacture and prior to sale have been fewer than those in some other contexts. Valuable opportunities for food defence improvements are identified in other contexts, especially food prepared in private or community settings
Influence of steps on the tilting and adsorption dynamics of ordered Pn films on vicinal Ag(111) surfaces
Here we present a structural study of pentacene (Pn) thin films on vicinal
Ag(111) surfaces by He atom diffraction measurements and density functional
theory (DFT) calculations supplemented with van der Waals (vdW) interactions.
Our He atom diffraction results suggest initial adsorption at the step edges
evidenced by initial slow specular reflection intensity decay rate as a
function of Pn deposition time. In parallel with the experimental findings, our
DFT+vdW calculations predict the step edges as the most stable adsorption site
on the surface. An isolated molecule adsorbs as tilted on the step edge with a
binding energy of 1.4 eV. In addition, a complete monolayer (ML) with
pentacenes flat on the terraces and tilted only at the step edges is found to
be more stable than one with all lying flat or tilted molecules, which in turn
influences multilayers. Hence our results suggest that step edges can trap Pn
molecules and act as nucleation sites for the growth of ordered thin films with
a crystal structure similar to that of bulk Pn.Comment: 4 pages, 4 figures, 1 tabl
Rocket and FUSE Observations of IC 405: Differential Extinction and Fluorescent Molecular Hydrogen
We present far-ultraviolet spectroscopy of the emission/reflection nebula IC
405 obtained by a rocket-borne long-slit spectrograph and the Far Ultraviolet
Spectroscopic Explorer. Both data sets show a rise in the ratio of the nebular
surface brightness to stellar flux (S/F_*) of approximately two orders of
magnitude towards the blue end of the far-UV bandpass. Scattering models using
simple dust geometries fail to reproduce the observed S/F_* for realistic grain
properties. The high spectral resolution of the FUSE data reveals a rich
fluorescent molecular hydrogen spectrum ~1000" north of the star that is
clearly distinguished from the steady blue continuum. The S/F_* remains roughly
constant at all nebular pointings, showing that fluorescent molecular hydrogen
is not the dominant cause for the blue rise. We discuss three possible
mechanisms for the ``Blue Dust'': differential extinction of the dominant star
(HD 34078), unusual dust grain properties, and emission from nebular dust. We
conclude that uncertainties in the nebular geometry and the degree of dust
clumping are most likely responsible for the blue rise. As an interesting
consequence of this result, we consider how IC 405 would appear in a spatially
unresolved observation. If IC 405 was observed with a spatial resolution of
less than 0.4 pc, for example, an observer would infer a far-UV flux that was
2.5 times the true value, giving the appearance of a stellar continuum that was
less extinguished than radiation from the surrounding nebula, an effect that is
reminiscent of the observed ultraviolet properties of starburst galaxies.Comment: 8 pages, 9 figures, using emulateapj, ApJ - accepte
Fluorescent Molecular Hydrogen Emission in IC 63: FUSE, HUT, and Rocket Observations
We present far-ultraviolet observations of IC 63, an emission/reflection
nebula illuminated by the B0.5IV star gamma Cassiopeia, located 1.3 pc from the
nebula. Molecular hydrogen fluorescence was detected first in IC 63 by IUE and
later at shorter wavelengths by ORFEUS. Here we present Far Ultraviolet
Spectroscopic Explorer (FUSE) observations towards three locations in the
nebula, complemented by Hopkins Ultraviolet Telescope (HUT) data on the central
nebular position. In addition, we present a sounding rocket calibration of a
FUSE spectrum of gamma Cas. Molecular hydrogen fluorescence is detected in all
three FUSE pointings. The intensity of this emission as well as the
contributions from other species are seen to vary with position. The absolute
flux calibration of the sounding rocket data allows us to reliably predict the
radiation field incident on IC 63. We use these data to test models of the
fluorescent process. Our modeling resolves the perceived discrepancy between
the existing ultraviolet observations and achieves a satisfactory agreement
with the H_2 rotational structure observed with FUSE.Comment: 7 pages, 6 figures, using emulateapj. Accepted by Ap
Methane Mitigation:Methods to Reduce Emissions, on the Path to the Paris Agreement
The atmospheric methane burden is increasing rapidly, contrary to pathways compatible with the goals of the 2015 United Nations Framework Convention on Climate Change Paris Agreement. Urgent action is required to bring methane back to a pathway more in line with the Paris goals. Emission reduction from “tractable” (easier to mitigate) anthropogenic sources such as the fossil fuel industries and landfills is being much facilitated by technical advances in the past decade, which have radically improved our ability to locate, identify, quantify, and reduce emissions. Measures to reduce emissions from “intractable” (harder to mitigate) anthropogenic sources such as agriculture and biomass burning have received less attention and are also becoming more feasible, including removal from elevated-methane ambient air near to sources. The wider effort to use microbiological and dietary intervention to reduce emissions from cattle (and humans) is not addressed in detail in this essentially geophysical review. Though they cannot replace the need to reach “net-zero” emissions of CO2, significant reductions in the methane burden will ease the timescales needed to reach required CO2 reduction targets for any particular future temperature limit. There is no single magic bullet, but implementation of a wide array of mitigation and emission reduction strategies could substantially cut the global methane burden, at a cost that is relatively low compared to the parallel and necessary measures to reduce CO2, and thereby reduce the atmospheric methane burden back toward pathways consistent with the goals of the Paris Agreement
Lifetime measurements in Co and Co
Lifetimes of the and states in Co and the
state in Co were measured using the recoil distance Doppler
shift and the differential decay curve methods. The nuclei were populated by
multi-nucleon transfer reactions in inverse kinematics. Gamma rays were
measured with the EXOGAM Ge array and the recoiling fragments were fully
identified using the large-acceptance VAMOS spectrometer. The E2 transition
probabilities from the and states to the ground
state could be extracted in Co as well as an upper limit for the
(E2) value in Co. The experimental
results were compared to large-scale shell-model calculations in the and
model spaces, allowing to draw conclusions on the single-particle
or collective nature of the various states.Comment: 8 pages, 8 figures, 1 table, accepted for publication in Physical
Review
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