316 research outputs found
Thermodynamic large fluctuations from uniformized dynamics
Large fluctuations have received considerable attention as they encode
information on the fine-scale dynamics. Large deviation relations known as
fluctuation theorems also capture crucial nonequilibrium thermodynamical
properties. Here we report that, using the technique of uniformization, the
thermodynamic large deviation functions of continuous-time Markov processes can
be obtained from Markov chains evolving in discrete time. This formulation
offers new theoretical and numerical approaches to explore large deviation
properties. In particular, the time evolution of autonomous and non-autonomous
processes can be expressed in terms of a single Poisson rate. In this way the
uniformization procedure leads to a simple and efficient way to simulate
stochastic trajectories that reproduce the exact fluxes statistics. We
illustrate the formalism for the current fluctuations in a stochastic pump
model
Estimating the spectrum of a density operator
Given N quantum systems prepared according to the same density operator \rho,
we propose a measurement on the N-fold system which approximately yields the
spectrum of \rho. The projections of the proposed observable decompose the
Hilbert space according to the irreducible representations of the permutations
on N points, and are labeled by Young frames, whose relative row lengths
estimate the eigenvalues of \rho in decreasing order. We show convergence of
these estimates in the limit N\to\infty, and that the probability for errors
decreases exponentially with a rate we compute explicitly.Comment: 4 Pages, RevTeX, one figur
The Measure-theoretic Identity Underlying Transient Fluctuation Theorems
We prove a measure-theoretic identity that underlies all transient
fluctuation theorems (TFTs) for entropy production and dissipated work in
inhomogeneous deterministic and stochastic processes, including those of Evans
and Searles, Crooks, and Seifert. The identity is used to deduce a tautological
physical interpretation of TFTs in terms of the arrow of time, and its
generality reveals that the self-inverse nature of the various trajectory and
process transformations historically relied upon to prove TFTs, while necessary
for these theorems from a physical standpoint, is not necessary from a
mathematical one. The moment generating functions of thermodynamic variables
appearing in the identity are shown to converge in general only in a vertical
strip in the complex plane, with the consequence that a TFT that holds over
arbitrary timescales may fail to give rise to an asymptotic fluctuation theorem
for any possible speed of the corresponding large deviation principle. The case
of strongly biased birth-death chains is presented to illustrate this
phenomenon. We also discuss insights obtained from our measure-theoretic
formalism into the results of Saha et. al. on the breakdown of TFTs for driven
Brownian particles
Large Deviations for Stochastic Evolution Equations with Small Multiplicative Noise
The Freidlin-Wentzell large deviation principle is established for the
distributions of stochastic evolution equations with general monotone drift and
small multiplicative noise. As examples, the main results are applied to derive
the large deviation principle for different types of SPDE such as stochastic
reaction-diffusion equations, stochastic porous media equations and fast
diffusion equations, and the stochastic p-Laplace equation in Hilbert space.
The weak convergence approach is employed in the proof to establish the Laplace
principle, which is equivalent to the large deviation principle in our
framework.Comment: 31 pages, published in Appl. Math. Opti
Dynamic simplification and visualization of large maps
In this paper, we present an algorithm that performs simplification of large geographical maps through a novel use of graphics hardware. Given a map as a collection of non-intersecting chains and a tolerance parameter for each chain, we produce a simplified map that resembles the original map, satisfying the condition that the distance between each point on the simplified chain and the original chain is within the given tolerance parameter, and that no two chains intersect. In conjunction with this, we also present an out-of-core system for interactive visualization of these maps. We represent the maps hierarchically and employ different pruning strategies to accelerate the rendering. Our algorithm uses a parallel approach to do rendering as well as fetching data from the disk in a synchronous manner. We have applied our algorithm to a gigabyte sized map dataset. The memory overhead of our algorithm (the amount of main memory it requires) is output sensitive and is typically tens of megabytes, much smaller than the actual data size
The Continuum Directed Random Polymer
Motivated by discrete directed polymers in one space and one time dimension,
we construct a continuum directed random polymer that is modeled by a
continuous path interacting with a space-time white noise. The strength of the
interaction is determined by an inverse temperature parameter beta, and for a
given beta and realization of the noise the path evolves in a Markovian way.
The transition probabilities are determined by solutions to the one-dimensional
stochastic heat equation. We show that for all beta > 0 and for almost all
realizations of the white noise the path measure has the same Holder continuity
and quadratic variation properties as Brownian motion, but that it is actually
singular with respect to the standard Wiener measure on C([0,1]).Comment: 21 page
Nonconventional Large Deviations Theorems
We obtain large deviations theorems for nonconventional sums with underlying
process being a Markov process satisfying the Doeblin condition or a dynamical
system such as subshift of finite type or hyperbolic or expanding
transformation
Rational Design of Photoelectrodes for the Fully Integrated Polymer Electrode Membrane–Photoelectrochemical Water-Splitting System: A Case Study of Bismuth Vanadate
Photoelectrochemical (PEC) reactors based on polymer electrolyte membrane (PEM) electrolyzers are an attractive alternative to improve scalability compared to conventional monolithic devices. To introduce narrow band gap photoabsorbers such as BiVO4 in PEM-PEC system requires cost-effective and scalable deposition techniques beyond those previously demonstrated on monolithic FTO-coated glass substrates, followed by the preparation of membrane electrode assemblies. Herein, we address the significant challenges in coating narrow band gap metal-oxides on porous substrates as suitable photoelectrodes for the PEM-PEC configuration. In particular, we demonstrate the deposition and integration of W-doped BiVO4 on porous conductive substrates by a simple, cost-effective, and scalable deposition based on the SILAR (successive ionic layer adsorption and reaction) technique. The resultant W-doped BiVO4 photoanode exhibits a photocurrent density of 2.1 mA·cm–2, @1.23V vs RHE, the highest reported so far for the BiVO4 on any porous substrates. Furthermore, we integrated the BiVO4 on the PEM-PEC reactor to demonstrate the solar hydrogen production from ambient air with humidity as the only water source, retaining 1.55 mA·cm–2, @1.23V vs RHE. The concept provides insights into the features necessary for the successful development of materials suitable for the PEM-PEC tandem configuration reactors and the gas-phase operation of the reactor, which is a promising approach for low-cost, large-scale solar hydrogen production.</p
Lattice gas model in random medium and open boundaries: hydrodynamic and relaxation to the steady state
We consider a lattice gas interacting by the exclusion rule in the presence
of a random field given by i.i.d. bounded random variables in a bounded domain
in contact with particles reservoir at different densities. We show, in
dimensions , that the rescaled empirical density field almost surely,
with respect to the random field, converges to the unique weak solution of a
non linear parabolic equation having the diffusion matrix determined by the
statistical properties of the external random field and boundary conditions
determined by the density of the reservoir. Further we show that the rescaled
empirical density field, in the stationary regime, almost surely with respect
to the random field, converges to the solution of the associated stationary
transport equation
Transfer matrices for the totally asymmetric exclusion process
We consider the totally asymmetric simple exclusion process (TASEP) on a
finite lattice with open boundaries. We show, using the recursive structure of
the Markov matrix that encodes the dynamics, that there exist two transfer
matrices and that intertwine the Markov
matrices of consecutive system sizes:
. This semi-conjugation property of
the dynamics provides an algebraic counterpart for the matrix-product
representation of the steady state of the process.Comment: 7 page
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