Validation of fluorescence transition probability calculations

A systematic and quantitative validation of the K and L shell X-ray transition probability calculations according to different theoretical methods has been performed against experimental data. This study is relevant to the optimization of data libraries used by software systems, namely Monte Carlo codes, dealing with X-ray fluorescence. The results support the adoption of transition probabilities calculated according to the Hartree-Fock approach, which manifest better agreement with experimental measurements than calculations based on the Hartree-Slater method.Comment: 8 pages, 21 figures and images, 3 tables, to appear in proceedings of the Nuclear Science Symposium and Medical Imaging Conference 2009, Orland

Morphology and properties evolution upon ring-opening polymerization during extrusion of cyclic butylene terephthalate and graphene-related-materials into thermally conductive nanocomposites

In this work, the study of thermal conductivity before and after in-situ ring-opening polymerization of cyclic butylene terephthalate into poly (butylene terephthalate) in presence of graphene-related materials (GRM) is addressed, to gain insight in the modification of nanocomposites morphology upon polymerization. Five types of GRM were used: one type of graphite nanoplatelets, two different grades of reduced graphene oxide (rGO) and the same rGO grades after thermal annealing for 1 hour at 1700{\deg}C under vacuum to reduce their defectiveness. Polymerization of CBT into pCBT, morphology and nanoparticle organization were investigated by means of differential scanning calorimetry, electron microscopy and rheology. Electrical and thermal properties were investigated by means of volumetric resistivity and bulk thermal conductivity measurement. In particular, the reduction of nanoflake aspect ratio during ring-opening polymerization was found to have a detrimental effect on both electrical and thermal conductivities in nanocomposites

Tracing the Mass-Assembly History of Galaxies with Deep Surveys

We use the optical and near-infrared galaxy samples from the Munich Near-Infrared Cluster Survey (MUNICS), the FORS Deep Field (FDF) and GOODS-S to probe the stellar mass assembly history of field galaxies out to z ~ 5. Combining information on the galaxies' stellar mass with their star-formation rate and the age of the stellar population, we can draw important conclusions on the assembly of the most massive galaxies in the universe: These objects contain the oldest stellar populations at all redshifts probed. Furthermore, we show that with increasing redshift the contribution of star-formation to the mass assembly for massive galaxies increases dramatically, reaching the era of their formation at z ~ 2 and beyond. These findings can be interpreted as evidence for an early epoch of star formation in the most massive galaxies in the universe.Comment: 3 pages, 2 figures; published in B. Aschenbach, V. Burwitz, G. Hasinger, B. Leibundgut (eds.): "Relativistic Astrophysics and Cosmology - Einstein's Legacy. Proceedings of the Conference held in Munich, 2006", ESO Astrophysics Symposia, Springer Verlag, 2007, p. 310. Replaced to match final published versio

Effect of processing conditions on the thermal and electrical conductivity of poly (butylene terephthalate) nanocomposites prepared via ring-opening polymerization

Successful preparation of polymer nanocomposites, exploiting graphene-related materials, via melt mixing technology requires precise design, optimization and control of processing. In the present work, the effect of different processing parameters during the preparation of poly (butylene terephthalate) nanocomposites, through ring-opening polymerization of cyclic butylene terephthalate in presence of graphite nanoplatelets (GNP), was thoroughly addressed. Processing temperature (240{\deg}C or 260{\deg}C), extrusion time (5 or 10 minutes) and shear rate (50 or 100 rpm) were varied by means of a full factorial design of experiment approach, leading to the preparation of polybutylene terephthalate/GNP nanocomposite in 8 different processing conditions. Morphology and quality of GNP were investigated by means of electron microscopy, X-ray photoelectron spectroscopy, thermogravimetry and Raman spectroscopy. Molecular weight of the polymer matrix in nanocomposites and nanoflake dispersion were experimentally determined as a function of the different processing conditions. The effect of transformation parameters on electrical and thermal properties was studied by means of electrical and thermal conductivity measurement. Heat and charge transport performance evidenced a clear correlation with the dispersion and fragmentation of the GNP nanoflakes; in particular, gentle processing conditions (low shear rate, short mixing time) turned out to be the most favourable condition to obtain high conductivity values

Effect of morphology and defectiveness of graphene-related materials on the electrical and thermal conductivity of their polymer nanocomposites

In this work, electrically and thermally conductive poly (butylene terephthalate) nanocomposites were prepared by in-situ ring-opening polymerization of cyclic butylene terephthalate (CBT) in presence of a tin-based catalyst. One type of graphite nanoplatelets (GNP) and two different grades of reduced graphene oxide (rGO) were used. Furthermore, high temperature annealing treatment under vacuum at 1700{\deg}C was carried out on both RGO to reduce their defectiveness and study the correlation between the electrical/thermal properties of the nanocomposites and the nanoflakes structure/defectiveness. The morphology and quality of the nanomaterials were investigated by means of electron microscopy, x-ray photoelectron spectroscopy, thermogravimetry and Raman spectroscopy. Thermal, mechanical and electrical properties of the nanocomposites were investigated by means of rheology, dynamic mechanical thermal analysis, volumetric resistivity and thermal conductivity measurements. Physical properties of nanocomposites were correlated with the structure and defectiveness of nanoflakes, evidencing a strong dependence of properties on nanoflakes structure and defectiveness. In particular, a significant enhancement of both thermal and electrical conductivities was demonstrated upon the reduction of nanoflakes defectiveness

IR Colors and Sizes of Faint Galaxies

We present J and Ks band galaxy counts down to J=24 and Ks=22.5 obtained with the new infrared imager/spectrometer, SOFI, at the ESO New Technology Telescope. The co-addition of short, dithered, images led to a total exposure time of 256 and 624 minutes respectively, over an area of $\sim20$ arcmin$^2$ centered on the NTT Deep Field. The total number of sources with S/N$>5$ is 1569 in the J sample and 1025 in the Ks-selected sample. These are the largest samples currently available at these depths. A d$logN$/d$m$ relation with slope of $\sim0.36$ in J and $\sim0.38$ in Ks is found with no evident sign of a decline at the magnitude limit. The observed surface density of ``small'' sources is much lower than ``large'' ones at bright magnitudes and rises more steeply than the large sources to fainter magnitudes. Fainter than $J\sim22.5$ and Ks$\sim21.5$, small sources dominate the number counts. Galaxies get redder in J-K down to J$\sim20$ and Ks$\sim19$. At fainter magnitudes, the median color becomes bluer with an accompanying increase in the compactness of the galaxies. We show that the blue, small sources which dominate the faint IR counts are not compatible with a high redshift ($z>1$) population. On the contrary, the observed color and compactness trends, together with the absence of a turnover at faint magnitudes and the dominance of small sources, can be naturally explained by an increasing contribution of sub-$L^*$ galaxies when going to fainter apparent magnitudes. Such evidence strongly supports the existence of a steeply rising ($\alpha\ll-1$) faint end of the local infrared luminosity function of galaxies - at least for luminosities $L<0.01L^*$.Comment: Accepted for publication on A&A; 15 pages, 13 figure

Non-linear Matter Spectra in Coupled Quintessence

We consider cosmologies in which a dark-energy scalar field interacts with cold dark matter. The growth of perturbations is followed beyond the linear level by means of the time-renormalization-group method, which is extended to describe a multi-component matter sector. Even in the absence of the extra interaction, a scale-dependent bias is generated as a consequence of the different initial conditions for baryons and dark matter after decoupling. The effect is enhanced significantly by the extra coupling and can be at the 2-3 percent level in the range of scales of baryonic acoustic oscillations. We compare our results with N-body simulations, finding very good agreement.Comment: 20 pages, 6 figures, typo correcte