P2-type Na2/3Ni1/3Mn2/3O2 Cathode Material with Excellent Rate and Cycling Performance for Sodium-Ion Batteries

P2-type Na2/3Ni1/3Mn2/3O2 is an air-stable cathode material for sodium-ion batteries. However, it suffers irreversible P2-O2 phase transition in 4.2-V plateau and shows poor cycling stability and rate capability within this plateau. To evaluate the practicability of this material in 2.3–4.1 V voltage range, single-crystal micro-sized P2-type Na2/3Ni1/3Mn2/3O2 with high rate capability and cycling stability is synthesized via polyvinylpyrrolidone (PVP)-combustion method. The electrochemical performance is evaluated by galvanostatic charge-discharge tests. The kinetics of Na+ intercalation/deintercalation is studied detailly with potential intermittent titration technique (PITT), galvanostatic intermittent titration technique (GITT) and cyclic voltammetry (CV). The discharge capacity at 0.1 C in 2.3–4.1 V is 87.6 mAh g−1. It can deliver 91.5% capacity at 40 C rate and keep 89% after 650 cycles at 5C. The calculated theoretical energy density of full cell with hard carbon anode is 210 Wh kg−1. The moderate energy density associated with high power density and long cycle life is acceptable for load adjustment of new-energy power, showing the prospect of practical application

The X-ray light curve of Gamma-ray bursts: clues to the central engine

We present the analysis of a large sample of gamma-ray burst (GRB) X-ray light curves in the rest frame to characterise their intrinsic properties in the context of different theoretical scenarios. We determine the morphology, time scales, and energetics of 64 long GRBs observed by \emph{Swift}/XRT \emph{without} flaring activity. We furthermore provide a one-to-one comparison to the properties of GRBs \emph{with} X-ray flares. We find that the steep decay morphology and its connection with X-ray flares favour a scenario in which a central engine origin. We show that this scenario can also account for the shallow decay phase, provided that the GRB progenitor star has a self-similar structure with a constant envelope-to-core mass ratio $\sim 0.02-0.03$. However, difficulties arise for very long duration ($t_p\gtrsim10^4$ s) shallow phases. Alternatively, a spinning-down magnetar whose emitted power refreshes the forward shock can quantitatively account for the shallow decay properties. In particular we demonstrate that this model can account for the plateau luminosity vs. end time anticorrelation.Comment: 12 pages, 8 figures, accepted for publication in A&

Mercury deposition in southern New Hampshire, 2006–2009

The atmospheric deposition of mercury (Hg) occurs via several mechanisms including wet, dry, and occult processes. In an effort to understand the atmospheric cycling and seasonal depositional characteristics of Hg, event-based wet deposition samples and reactive gaseous Hg (RGM) measurements were collected for approximately 3 years at Thompson Farm (TF), a near-coastal rural site in Durham, NH, part of the University of New Hampshire AIRMAP Observing Network. Total aqueous mercury exhibited seasonal patterns in Hg wet deposition at TF. The lowest Hg wet deposition was measured in the winter with an average total seasonal deposition of 1.56 μg m−2compared to the summer average of 4.71 μg m−2. Inter-annual differences in total wet deposition are generally linked with precipitation volume, with the greatest deposition occurring in the wettest year. Relationships between surface level RGM and Hg wet deposition were also investigated based on continuous RGM measurements at TF from November 2006 to September 2009. No correlations were observed between RGM mixing ratios and Hg wet deposition, however the ineffective scavenging of RGM during winter precipitation events was evidenced by the less frequent depletion of RGM below the detection level. Seasonal dry deposition of reactive gaseous Hg (RGM) was estimated using an order-of-magnitude approach. RGM mixing ratios and dry deposition estimates were greatest during the winter and spring. The seasonal ratios of Hg wet deposition to RGM dry deposition vary by up to a factor of 80

Energy Spectra of Anti-nucleons in Finite Nuclei

The quantum vacuum in a many-body system of finite nuclei has been investigated within the relativistic Hartree approach which describes the bound states of nucleons and anti-nucleons consistently. The contributions of the Dirac sea to the source terms of the meson-field equations are taken into account up to the one-nucleon loop and one-meson loop. The tensor couplings for the $\omega$- and $\rho$-meson are included in the model. The overall nucleon spectra of shell-model states are in agreement with the data. The calculated anti-nucleon spectra in the vacuum differ about 20 -- 30 MeV with and without the tensor-coupling effects.Comment: 4 pages, to appear in the Proceedings of MENU 2004 (Beijing, Aug. 29 -- Sept. 4, 2004

Imprinted Networks as Chiral Pumps

We investigate the interaction between a chirally imprinted network and a solvent of chiral molecules. We find, a liquid crystalline polymer network is preferentially swollen by one component of a racemic solvent. This ability to separate is linked to the chiral order parameter of the network, and can be reversibly controlled via temperature or a mechanical deformation. It is maximal near the point at which the network loses its imprinted structure. One possible practical application of this effect would be a mechanical device for sorting mixed chiral molecules.Comment: 4 pages, 5 figure

Crystal lattice properties fully determine short-range interaction parameters for alkali and halide ions

Accurate models of alkali and halide ions in aqueous solution are necessary for computer simulations of a broad variety of systems. Previous efforts to develop ion force fields have generally focused on reproducing experimental measurements of aqueous solution properties such as hydration free energies and ion-water distribution functions. This dependency limits transferability of the resulting parameters because of the variety and known limitations of water models. We present a solvent-independent approach to calibrating ion parameters based exclusively on crystal lattice properties. Our procedure relies on minimization of lattice sums to calculate lattice energies and interionic distances instead of equilibrium ensemble simulations of dense fluids. The gain in computational efficiency enables simultaneous optimization of all parameters for Li+, Na+, K+, Rb+, Cs+, F-, Cl-, Br-, and I- subject to constraints that enforce consistency with periodic table trends. We demonstrate the method by presenting lattice-derived parameters for the primitive model and the Lennard-Jones model with Lorentz-Berthelot mixing rules. The resulting parameters successfully reproduce the lattice properties used to derive them and are free from the influence of any water model. To assess the transferability of the Lennard-Jones parameters to aqueous systems, we used them to estimate hydration free energies and found that the results were in quantitative agreement with experimentally measured values. These lattice-derived parameters are applicable in simulations where coupling of ion parameters to a particular solvent model is undesirable. The simplicity and low computational demands of the calibration procedure make it suitable for parametrization of crystallizable ions in a variety of force fields.Comment: 9 pages, 5 table

Luminous Infrared Galaxies in the Local Universe

We study the morphology and star formation properties of 159 local luminous infrared galaxy (LIRG) using multi-color images from Data Release 2 (DR2) of the Sloan Digital Sky Survey (SDSS). The LIRGs are selected from a cross-correlation analysis between the IRAS survey and SDSS. They are all brighter than 15.9 mag in the r-band and below redshift ~ 0.1, and so can be reliably classified morphologically. We find that the fractions of interacting/merging and spiral galaxies are ~ 48% and ~ 40% respectively. Our results complement and confirm the decline (increase) in the fraction of spiral (interacting/merging) galaxies from z ~1 to z ~ 0.1, as found by Melbourne, Koo & Le Floc'h (2005). About 75% of spiral galaxies in the local LIRGs are barred, indicating that bars may play an important role in triggering star formation rates > 20 M_{sun}/yr in the local universe. Compared with high redshift LIRGs, local LIRGs have lower specific star formation rates, smaller cold gas fractions and a narrower range of stellar masses. Local LIRGs appear to be either merging galaxies forming intermediate mass ellipticals or spiral galaxies undergoing high star formation activities regulated by bars.Comment: 22 pages, 5 figures, accepted for publication in ApJ, title changed, typos corrected,major revisions following referee's comments,updated reference