Electrophoresis of a polyelectrolyte through a nanopore

A hydrodynamic model for determining the electrophoretic speed of a polyelectrolyte through a nanopore is presented. It is assumed that the speed is determined by a balance of electrical and viscous forces arising from within the pore and that classical continuum electrostatics and hydrodynamics may be considered applicable. An explicit formula for the translocation speed as a function of the pore geometry and other physical parameters is obtained and is shown to be consistent with experimental measurements on DNA translocation through nanopores in silicon membranes. Experiments also show a weak dependence of the translocation speed on polymer length that is not accounted for by the present model. It is hypothesized that this is due to secondary effects that are neglected here.Comment: 5 pages, 2 column, 2 figure

Strongly nonlinear waves in capillary electrophoresis

In capillary electrophoresis, sample ions migrate along a micro-capillary filled with a background electrolyte under the influence of an applied electric field. If the sample concentration is sufficiently high, the electrical conductivity in the sample zone could differ significantly from the background.Under such conditions, the local migration velocity of sample ions becomes concentration dependent resulting in a nonlinear wave that exhibits shock like features. If the nonlinearity is weak, the sample concentration profile, under certain simplifying assumptions, can be shown to obey Burgers' equation (S. Ghosal and Z. Chen Bull. Math. Biol. 2010, 72(8), pg. 2047) which has an exact analytical solution for arbitrary initial condition.In this paper, we use a numerical method to study the problem in the more general case where the sample concentration is not small in comparison to the concentration of background ions. In the case of low concentrations, the numerical results agree with the weakly nonlinear theory presented earlier, but at high concentrations, the wave evolves in a way that is qualitatively different.Comment: 7 pages, 5 figures, 1 Appendix, 2 videos (supplementary material

Robustness of d-Density Wave Order to Nonmagnetic Impurities

Effect of finite density of nonmagnetic impurities on a coexisting phase of d-density wave (DDW) order and d-wave superconducting (DSC) order is studied using Bogoliubov-de Gennes (BdG) method. The spatial variation of the inhomogeneous DDW order due to impurities has a strong correlation with that of density, which is very different from that of DSC order. The length scale associated with DDW is found to be of the order of a lattice spacing. The nontrivial inhomogeneities are shown to make DDW order much more robust to the impurities, while DSC order becomes very sensitive to them. The effect of disorder on the density of states is also discussed.Comment: 4 pages, 3 PostScript figure

Theory and simulation of surface plasmon excitation using resonant metal nanoparticle arrays

We discuss a plasmonic coupling device consisting of a periodic array of ellipsoidal silver nanoparticles embedded in SiO(2) and placed near a silver surface. By tuning the shape of the particles in the array, the nanoparticle plasmon resonance is tuned. The resulting resonantly enhanced fields near the nanoparticles, in turn, excite surface plasmons on the metal film. We have performed finite integration technique simulations of such a plasmon coupler, optimized for operation near a wavelength of 676 nm. Analysis of the frequency dependent electric field at different locations in the simulation volume reveals the separate contributions of the particle and surface resonance to the excitation mechanism. A coupled oscillator model describing the nanoparticle and the metal film as individual resonators is introduced and is shown to reproduce the trends observed in the simulations. Implications of our analysis on the resonantly enhanced excitation of surface plasmons are discussed

Atomic Cournotian Traders May Be Walrasian

In a bilateral oligopoly, with large traders, represented as atoms, and small traders, represented by an atomless part, when is there a nonempty intersection between the sets of Walras and Cournot–Nash allocations? Using a two-commodity version of the Shapley window model, we show that a necessary and sufficient condition for a Cournot–Nash allocation to be a Walras allocation is that all atoms demand a null amount of one of the two commodities. We provide four examples which show that this characterization holds non-vacuously. When our condition fails to hold, we also confirm, through some examples, the result obtained by Okuno et al. (1980): small traders always have a negligible influence on prices, while the large traders keep their strategic power even when their behavior turns out to be Walrasian in the cooperative framework considered by Gabszewicz and Mertens (1971) and Shitovitz (1973)

On the foundation of monopoly in bilateral exchange

We address the problem of monopoly in general equilibrium in a mixed version of a monopolistic two-commodity exchange economy where the monopolist, represented as an atom, is endowed with one commodity and “small traders,” represented by an atomless part, are endowed only with the other. First we provide an economic theoretical foundation of the monopoly solution in this bilateral framework through a formalization of an explicit trading process inspired by Pareto (Cours d’économie politique. F. Rouge Editeur, Lausanne, 1896) for an exchange economy with a finite number of commodities, and we give the conditions under which our monopoly solution has the geometric characterization proposed by Schydlowsky and Siamwalla (Q J Econ 80:147–153, 1966). Then, we provide a game theoretical foundation of our monopoly solution through a two-stage reformulation of our model. This allows us to prove that the set of the allocations corresponding to a monopoly equilibrium and the set of the allocations corresponding to a subgame perfect equilibrium of the two-stage game coincide. Finally, we compare our model of monopoly with a bilateral exchange version of a pioneering model proposed by Forchheimer (Jahrbuch für Gesetzgebung, Verwaltung und Volkswirschafts im Deutschen Reich 32:1–12, 1908), known as a model of “partial monopoly” since there a monopolist shares a market with a“competitive fringe.” Journal of Economic Literature Classification Numbers: D42, D51

Antiferromagnetism and charged vortices in high-Tc superconductors

The effect of the long-range Coulomb interaction on charge accumulation in antiferromagnetic vortices in high-Tc superconductors is studied within a Bogoliubov-de Gennes mean-field model of competing antiferromagnetic and d-wave superconducting orders. Antiferromagnetism is found to be associated with an accumulation of charge in the vortex core, even in the presence of the long-range Coulomb interaction. The manifestation of Pi-triplet pairing in the presence of coexisting dSC and AFM order, and the intriguing appearance of one-dimensional stripe-like ordering are discussed. The local density of states (LDOS) in the vortex core is calculated and is found to be in excellent qualitative agreement with experimental data.Comment: 14 pages, 8 figures, 2 column RevTex4 PRB forma

Phase diagram and upper critical field of homogenously disordered epitaxial 3-dimensional NbN films

We report the evolution of superconducting properties with disorder, in 3-dimensional homogeneously disordered epitaxial NbN thin films. The effective disorder in NbN is controlled from moderately clean limit down to Anderson metal-insulator transition by changing the deposition conditions. We propose a phase diagram for NbN in temperature-disorder plane. With increasing disorder we observe that as kFl-->1 the superconducting transition temperature (Tc) and minimum conductivity (sigma_0) go to zero. The phase diagram shows that in homogeneously disordered 3-D NbN films, the metal-insulator transition and the superconductor-insulator transition occur at a single quantum critical point at kFl~1.Comment: To appear in Journal of Superconductivity and Novel Magnetism (ICSM2010 proceedings

Pairbreaking Without Magnetic Impurities in Disordered Superconductors

We study analytically the effects of inhomogeneous pairing interactions in short coherence length superconductors, using a spatially varying Bogoliubov-deGennes model. Within the Born approximation, it reproduces all of the standard Abrikosov-Gor'kov pairbreaking and gaplessness effects, even in the absence of actual magnetic impurities. For pairing disorder on a single site, the T-matrix gives rise to bound states within the BCS gap. Our results are compared with recent scanning tunneling microscopy measurements on Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ with Zn or Ni impurities.Comment: 4 pages, 2 figures, submitted to PR