649 research outputs found
Platinum/ceria/alumina catalysts on microstructures for carbon monoxide conversion
Platinum/ceria/alumina catalysts have been prepared by a sol–gel method and coated in the microchannels of stainless steel platelets. These catalysts are very active for the water-gas shift reaction between 300 and 400°C. Moreover, they are non-pyrophoric and thus well suited for the purification of hydrogen for PEM fuel cells. The obtained coatings show good adherence and catalytic activity. The influence of the amount of platinum and ceria as well as the effect of a binder on the catalytic performance has been investigated. The samples have been characterized before reaction by XRD, SEM and by N2 adsorption measurements. The kinetics, free from internal diffusion limitations, over these thin films have been described by a power law rate equation. An activation energy of 86 kJ/mol has been found and at 260 °C the TOF corresponds to 0.6 ± 0.1 s−1 for all investigated samples. The superior activity of the platelets compared to the powder samples is attributed to the diffusion limitations inside the powder pellets. Thus catalysts deposited on microstructured platelets lead to a better platinum utilization
Properties of simulated Milky Way-mass galaxies in loose group and field environments
We test the validity of comparing simulated field disk galaxies with the
empirical properties of systems situated within environments more comparable to
loose groups, including the Milky Way's Local Group. Cosmological simulations
of Milky Way-mass galaxies have been realised in two different environment
samples: in the field and in environments with similar properties to the Local
Group. Apart from the environments of the galaxies, the samples are kept as
homogeneous as possible with equivalent ranges in last major merger time, halo
mass and halo spin. Comparison of these two samples allow for systematic
differences in the simulations to be identified. Metallicity gradients, disk
scale lengths, colours, magnitudes and age-velocity dispersion relations are
studied for each galaxy in the suite and the strength of the link between these
and environment of the galaxies is studied. The bulge-to-disk ratio of the
galaxies show that these galaxies are less spheroid dominated than many other
simulated galaxies in literature with the majority of both samples being disk
dominated. We find that secular evolution and mergers dominate the spread of
morphologies and metallicity gradients with no visible differences between the
two environment samples. In contrast with this consistency in the two samples
there is tentative evidence for a systematic difference in the velocity
dispersion-age relations of galaxies in the different environments. Loose group
galaxies appear to have more discrete steps in their velocity dispersion-age
relations. We conclude that at the current resolution of cosmological galaxy
simulations field environment galaxies are sufficiently similar to those in
loose groups to be acceptable proxies for comparison with the Milky Way
provided that a similar assembly history is considered.Comment: 16 pages, 11 figures, abstract abridged for arXiv. Accepted for
publication in Astronomy & Astrophysic
Commissioning of the CMS Cryogenic System After Final Installation in the Underground Cavern
After having served for the surface tests of the Compact Muon Solenoid (CMS) magnet, the cold box and ancillaries of the CMS helium refrigerator have been dismantled, moved and re-installed in the USC55 cavern in 2007. The full re-commissioning in the cavern has been followed by several tests of the refrigerator to confirm its nominal performance before it was used for the magnet and detector tests in 2008. During these tests the safety modes of the refrigeration system have been tested and improved. After a nine-year project both, the magnet and the refrigeration system are now ready for the CMS operation
Star formation efficiency and host galaxies of Gamma-Ray Bursts
Gamma-ray bursts are likely to be associated with regions of active star formation and may therefore be useful as cosmological tracers of galaxy formation. Using hydrodynamical/N-body simulations the cosmological properties of host galaxies are investigated. Assuming the hosts to be efficient star-forming objects, i.e. with high specific star formation rates, the majority of the candidate
hosts are found to below mass, young galaxies with a moderate star formation rate. This picture, consistent with most observations of GRB host galaxies, corroborates the idea that gamma-ray bursts do not follow the cosmic star formation rate. More importantly the hosts should contribute to unveil the faint end of the galaxy luminosity function
Quantum fluctuations for drag free geodesic motion
The drag free technique is used to force a proof mass to follow a geodesic
motion. The mass is protected from perturbations by a cage, and the motion of
the latter is actively controlled to follow the motion of the proof mass. We
present a theoretical analysis of the effects of quantum fluctuations for this
technique. We show that a perfect drag free operation is in principle possible
at the quantum level, in spite of the back action exerted on the mass by the
position sensor.Comment: 4 pages, 1 figure, RevTeX, minor change
Chirality transfer and stereo-selectivity of imprinted cholesteric networks
Imprinting of cholesteric textures in a polymer network is a method of
preserving a macroscopically chiral phase in a system with no molecular
chirality. By modifying the elastics properties of the network, the resulting
stored helical twist can be manipulated within a wide range since the
imprinting efficiency depends on the balance between the elastics constants and
twisting power at network formation. One spectacular property of phase
chirality imprinting is the created ability of the network to adsorb
preferentially one stereo-component from a racemic mixture. In this paper we
explore this property of chirality transfer from a macroscopic to the molecular
scale. In particular, we focus on the competition between the phase chirality
and the local nematic order. We demonstrate that it is possible to control the
subsequent release of chiral solvent component from the imprinting network and
the reversibility of the stereo-selective swelling by racemic solvents
Beating quantum limits in interferometers with quantum locking of mirrors
The sensitivity in interferometric measurements such as gravitational-wave
detectors is ultimately limited by quantum noise of light. We discuss the use
of feedback mechanisms to reduce the quantum effects of radiation pressure.
Recent experiments have shown that it is possible to reduce the thermal motion
of a mirror by cold damping. The mirror motion is measured with an
optomechanical sensor based on a high-finesse cavity, and reduced by a feedback
loop. We show that this technique can be extended to lock the mirror at the
quantum level. In gravitational-waves interferometers with Fabry-Perot cavities
in each arms, it is even possible to use a single feedback mechanism to lock
one cavity mirror on the other. This quantum locking greatly improves the
sensitivity of the interferometric measurement. It is furthermore insensitive
to imperfections such as losses in the interferometer
Stereo-selective swelling of imprinted cholesteric networks
Molecular chirality, and the chiral symmetry breaking of resulting
macroscopic phases, can be topologically imprinted and manipulated by
crosslinking and swelling of polymer networks. We present a new experimental
approach to stereo-specific separation of chiral isomers by using a cholesteric
elastomer in which a helical director distribution has been topological
imprinted by crosslinking. This makes the material unusual in that is has a
strong phase chirality, but no molecular chirality at all; we study the nature
and parameters controlling the twist-untwist transition. Adding a racemic
mixture to the imprinted network results in selective swelling by only the
component of ``correct'' handedness. We investigate the capacity of demixing in
a racemic environment, which depends on network parameters and the underlying
nematic order
Pioneer 10 data analysis: Investigation on periodic anomalies
International audienceThe Pioneer Anomaly refers to the difference between the expected theoretical tra jectory of the Pioneer 10 and 11 spacecrafts and the observed tra jectory through Doppler measurements. It has been interpreted by the Jet Propulsion Laboratory (JPL) as a constant anomalous acceleration (Anderson et al. 2002). For this analysis, the Groupe Anomalie Pioneer (GAP) composed of several french laboratories has developped a specific tra jectography software, ODYSSEY, which enables to test different anomaly models. The paper will present, after a brief description of the software and the implemented models, the last results obtained: in addition to the constant anomaly, time dependent signatures of the anomaly have been noticed which can be described geometrically. The fit of the Pioneer 10 data with these new models yields a reduction of the standard deviation of the residual by a factor 2 with respect to the simple constant anomaly
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