Estimating European volatile organic compound emissions using satellite observations of formaldehyde from the Ozone Monitoring Instrument

Emission of non-methane Volatile Organic Compounds (VOCs) to the atmosphere stems from biogenic and human activities, and their estimation is difficult because of the many and not fully understood processes involved. In order to narrow down the uncertainty related to VOC emissions, which negatively reflects on our ability to simulate the atmospheric composition, we exploit satellite observations of formaldehyde (HCHO), an ubiquitous oxidation product of most VOCs, focusing on Europe. HCHO column observations from the Ozone Monitoring Instrument (OMI) reveal a marked seasonal cycle with a summer maximum and winter minimum. In summer, the oxidation of methane and other long-lived VOCs supply a slowly varying background HCHO column, while HCHO variability is dominated by most reactive VOC, primarily biogenic isoprene followed in importance by biogenic terpenes and anthropogenic VOCs. The chemistry-transport model CHIMERE qualitatively reproduces the temporal and spatial features of the observed HCHO column, but display regional biases which are attributed mainly to incorrect biogenic VOC emissions, calculated with the Model of Emissions of Gases and Aerosol from Nature (MEGAN) algorithm. These "bottom-up" or a-priori emissions are corrected through a Bayesian inversion of the OMI HCHO observations. Resulting "top-down" or a-posteriori isoprene emissions are lower than "bottom-up" by 40% over the Balkans and by 20% over Southern Germany, and higher by 20% over Iberian Peninsula, Greece and Italy. We conclude that OMI satellite observations of HCHO can provide a quantitative "top-down" constraint on the European "bottom-up" VOC inventories

Development and testing of porous ionizer materials, part I Summary report, Feb. 1965 - May 1966

Development and testing of porous tungsten ionizer materials for cesium contact engine

Structural Analysis of Gelsolin Using Synchrotron Protein Footprinting

Protein footprinting provides detailed structural information on protein structure in solution by directly identifying accessible and hydroxyl radical-reactive side chain residues. Radiolytic generation of hydroxyl radicals using millisecond pulses of a synchrotron white beam results in the formation of stable side chain oxidation products, which can be digested with proteases for mass spectrometry (MS) analysis. Liquid chromatography-coupled MS and tandem MS methods allow for the quantitation of the ratio of modified and unmodified peptides and identify the specific side chain probes that are oxidized, respectively. The ability to monitor the changes in accessibility of multiple side chain probes by monitoring increases or decreases in their oxidation rates as a function of ligand binding provides an efficient and powerful tool for analyzing protein structure and dynamics. In this study, we probe the detailed structural features of gelsolin in its inactive and Ca2+-activated state. Oxidation rate data for 81 peptides derived from the trypsin digestion of gelsolin are presented; 60 of these peptides were observed not to be oxidized, and 21 had detectable oxidation rates. We also report the Ca2+-dependent changes in oxidation for all 81 peptides. Fifty-nine remained unoxidized, five increased their oxidation rate, and two experienced protections. Tandem mass spectrometry was used to identify the specific side chain probes responsible for the Ca2+-insensitive and Ca2+-dependent responses. These data are consistent with crystallographic data for the inactive form of gelsolin in terms of the surface accessibility of reactive residues within the protein. The results demonstrate that radiolytic protein footprinting can provide detailed structural information on the conformational dynamics of ligand-induced structural changes, and the data provide a detailed model for gelsolin activation

Incorporation Of Broadband Access Technology In A Telecommunications Engineering Technology Program

The so-called “last mile” of the telecommunications network, which links residences and business locations to the network, has traditionally been the last bastion of old technology. Residential voice service is still mostly provided via an analog signal over a pair of copper wires that connects the telephone to a switching system in a central office. The high-speed digital technology employed by modern switching systems and inter-office transmission systems does not extend to most residences. The local access network is a landscape of copper wires bound into large cables, splices, cross-boxes and other equipment that has provided voice-grade service over the years. However, the landscape is changing dramatically as both residential and business customers demand more and more bandwidth for a growing number of services including high-speed Internet access and video as well as voice. Telcos such as AT&T and Verizon as well as Multi-Service Operators (MSOs) are both vying to provide the “triple play” (voice, data and video) to these customers. In order to provide the triple play, service providers are introducing digital transmission and optical fiber, which have revolutionized long-haul communication, to the local access network. The Telecommunication Engineering Technology program at RIT is responding to this trend by providing courses and laboratory facilities to introduce students to the associated technology. Our Telecommunication Systems Laboratory now features both passive optical network (PON) and hybrid fiber/coax (HFC) technology. These are two leading approaches to provide broadband access to support the triple play. In addition, we are developing new courses to cover topics such as video transmission and broadband network engineering. This paper presents the current status of our laboratory and course development along with our plans for future enhancements

Tactile signatures and hand motion intent recognition for wearable assistive devices

Within the field of robotics and autonomous systems where there is a human in the loop, intent recognition plays an important role. This is especially true for wearable assistive devices used for rehabilitation, particularly post-stroke recovery. This paper reports results on the use of tactile patterns to detect weak muscle contractions in the forearm while at the same time associating these patterns with the muscle synergies during different grips. To investigate this concept, a series of experiments with healthy participants were carried out using a tactile arm brace (TAB) on the forearm while performing four different types of grip. The expected force patterns were established by analysing the muscle synergies of the four grip types and the forearm physiology. The results showed that the tactile signatures of the forearm recorded on the TAB align with the anticipated force patterns. Furthermore, a linear separability of the data across all four grip types was identified. Using the TAB data, machine learning algorithms achieved a 99% classification accuracy. The TAB results were highly comparable to a similar commercial intent recognition system based on a surface electromyography (sEMG) sensing

Molecular transport junctions: Current from electronic excitations in the leads

Using a model comprising a 2-level bridge connecting free electron reservoirs we show that coupling of a molecular bridge to electron-hole excitations in the leads can markedly effect the source-drain current through a molecular junction.In some cases, e.g. molecules that exhibit strong charge transfer transitions, the contribution from electron-hole excitations can exceed the Landauer elastic current and dominate the observed conduction.Comment: 4 pages, 2 figures, submitted to PR

Tunable far infrared studies of molecular parameters in support of stratospheric measurements

Lab studies were made in support of far infrared spectroscopy of the stratosphere using the Tunable Far InfraRed (TuFIR) method of ultrahigh resolution spectroscopy and, more recently, spectroscopic and retrieval calculations performed in support of satellite-based atmospheric measurement programs: the Global Ozone Monitoring Experiment (GOME), and the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY)

Optical microscopy via spectral modifications of a nano-antenna

The existing optical microscopes form an image by collecting photons emitted from an object. Here we report on the experimental realization of microscopy without the need for direct optical communication with the sample. To achieve this, we have scanned a single gold nanoparticle acting as a nano-antenna in the near field of a sample and have studied the modification of its intrinsic radiative properties by monitoring its plasmon spectrum.Comment: 6 pages, 4 figures (color